Results 91 to 100 of about 17,709 (313)

Atroposelective Access to π‐Conjugated 1,2‐Azaborepines Enabled by Palladium‐Catalyzed Cyclization of N‐Heterobiaryls with Alkynylboronates

open access: yesAdvanced Science, EarlyView.
We report a palladium‐catalyzed atroposelective cyclization of N‐heterobiaryl triflates with alkynyl boronates to access seven‐membered 1,2‐BN‐bridged biaryls with high yields and excellent enantioselectivity via a cascade DyKAT, cis‐carbopalladation, and 1,2‐migration, which expands the toolbox for axially chiral π‐conjugated boron compounds and opens
Fengya He   +6 more
wiley   +1 more source

Comparative Insights and Overlooked Factors of Interphase Chemistry in Alkali Metal‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review presents a comparative analysis of Li‐, Na‐, and K‐ion batteries, focusing on the critical role of electrode–electrolyte interphases. It especially highlights overlooked aspects such as SEI/CEI misconceptions, binder effects, and self‐discharge relevance, emphasizing the limitations of current understanding and offering strategies for ...
Changhee Lee   +3 more
wiley   +1 more source

Wavelet-Aided OTFS: A 2-D Multicarrier Modulation Format for High-Mobility Communications

open access: yesIEEE Open Journal of the Communications Society
This article proposes a wavelet-aided orthogonal time-frequency space (W-OTFS) modulation as a novel approach for high-mobility vehicular communication.
Mahmudul Hasan Abid   +3 more
doaj   +1 more source

Performance Analysis of Multi-User OTFS, OTSM, and Single Carrier in Uplink

open access: yesIEEE Transactions on Communications
In this paper, we develop a multiple access (MA) mechanism where users transmit upsampled and circularly shifted orthogonal frequency division multiplexing (OFDM) signals in the uplink.
B. V. S. Reddy   +2 more
semanticscholar   +1 more source

Synchronization for Multiuser Uplink OTFS

open access: yes2025 IEEE Wireless Communications and Networking Conference (WCNC)
In this paper, we propose time and frequency synchronization techniques for the uplink of multiuser orthogonal time frequency space (MU-OTFS) in high-mobility scenarios. We introduce a spectrally efficient and practical pilot pattern where each user utilizes a pilot with a cyclic prefix (PCP) within a shared pilot region on the delay-Doppler plane.
Mohsen Bayat   +2 more
openaire   +2 more sources

Engineering Trace‐Amount Electrolyte Additives for Aqueous Zinc Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Large‐amount additives primarily modify the bulk electrolyte by coordinating with Zn2+ or reshaping the hydrogen‐bond network, thereby altering the overall solution chemistry. In contrast, trace‐amount additives mainly operate at the electrode–electrolyte interface, regulating Zn deposition through electric double‐layer modulation, interfacial ...
Zhaoxin Li   +9 more
wiley   +1 more source

3D Interconnected Zn‐Ion Pathways Through Anionic Nanochannels Surrounding Bacterial Cellulose Nanofibers by Repetitive Interfacial Assembly for Aqueous Zn‐Ion Battery Separators

open access: yesAdvanced Energy Materials, EarlyView.
A repetitive interfacial assembly method is introduced to prepare a nanofibrillar separator with interconnected 3D anionic nanochannels for aqueous zinc‐ion batteries. The carboxylate‐rich nanochannels promote enhancements of Zn2+ ion transport and charge transfer at the electrode surface, and the 3D nanostructured hydrogels contribute to homogeneous ...
Wonseok Choi   +6 more
wiley   +1 more source

New market conduct rules for financial intermediaries: Will complexity bring transparency? ECMI Policy Brief No. 24, May 2017 [PDF]

open access: yes, 2017
The financial crisis led to a raft of new or updated EU conduct rules to ensure the orderly functioning of markets and market operators. The core measure is known as MiFID II, which is a radical update of the 2004 Markets in Financial Instruments ...
Lannoo, Karel.
core  

Katalysatoraktivierung als Schlüsselfaktor in Kreuzkupplungen: Raumtemperatur‐Kupplungen schwacher Nukleophile ermöglicht durch [Pd(1‐MeNAP)TFA]2 Präkatalysatoren

open access: yesAngewandte Chemie, EarlyView.
Bei vielen Pd‐katalysierten Kreuzkupplungen hat sich gezeigt, dass die Katalysatorleistung durch dessen Aktivierung begrenzt wird. Methylnaphthyl (MeNAP)‐Palladiumtrifluoracetat‐Dimere werden als leicht zu lagernde und handhabende Präkatalysatoren vorgestellt, die sich unter Reaktionsbedingungen schnell aktivieren, selbst wenn nur schwach ...
Sourav Manna   +6 more
wiley   +1 more source

Schwefel‐gesteuerter Aufbau von Vinylcyclopropanen ausgehend von 1,3‐Dienen

open access: yesAngewandte Chemie, EarlyView.
Schwefel übernimmt die Kontrolle: Ein Thioether wirkt als molekularer Dirigent, der die Carbenaddition an 1,3‐Diene mit außergewöhnlicher Regio‐ und Diastereokontrolle lenkt. Dabei werden schwefelhaltige Vinylcyclopropane (S‐VCPs) erhalten, die mittels herkömmlicher Methoden nur schwer zugänglich sind.
Anna Keimer   +6 more
wiley   +1 more source

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