Results 51 to 60 of about 7,946 (266)

Reductive Cleavage of 1,2-Oxazines Promoted by Zinc and Ammonium Chloride; Mild One Pot Preparation of γ-Hydroxy Ketones

open access: yesE-Journal of Chemistry, 2012
A facile method for a mild single pot reductive cleavage of 1,2-oxazines to γ-hydroxy ketones was developed using zinc and aqueous ammonium chloride as the reagent in methanol.
P. Sunil Kumar, K. M. Lokanatha Rai
doaj   +1 more source

The Effect of Aldehyde and Carboxylic Acid Substitution on the Isomerization of Hemithioindigo Photoswitches

open access: yesChemistry – A European Journal, Accepted Article.
Hemithioindigo (HTI) photoswitches exhibit robust photoisomerization under visible light and relatively high thermal bistability. In this work, we report various modifications of the HTI core, namely the introduction of aldehydes and carboxylic acids at the para position of the stilbene fragment with different oxidation states of the sulfur center, and
Matías I. Quindt   +6 more
wiley   +1 more source

1,2,3-Triazole-4(5)-amines – Convenient Synthetic Blocks for the Construction of Triazolo-Annulated Heterocycles

open access: yesЖурнал органічної та фармацевтичної хімії, 2022
Aim. To analyze and summarize the synthetic potential of 1,2,3-triazole-4(5)-amines as efficient building blocks in the synthesis of triazolo-annulated pyridine, azine and azepine systems. Results and discussion.
Natalia O. Syrota   +3 more
doaj   +1 more source

Alkoxyallenes as building blocks for organic synthesis [PDF]

open access: yes, 2014
Alkoxyallenes are unusually versatile C3 building blocks in organic synthesis. Hence this tutorial review summarizes the most important transformations, including subsequent reactions and their applications in the synthesis of relevant compounds, e.g ...
Reissig, Hans-Ulrich, Zimmer, Reinhold
core   +1 more source

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts. [PDF]

open access: yes, 2015
A catalytic enantioselective and regiodivergent arylation of alkenes is described. Chiral copper(II)bisoxazoline complexes catalyze the addition of diaryliodonium salts to allylic amides in excellent ee.
Cahard, Elise   +3 more
core   +4 more sources

Cytotoxicity of 2-oxazines and poly(2-oxazine)s in mouse fibroblast

open access: yes, 2018
Poly(2-oxazoline)s are a polymer family that has received much attention in the last decade as biomaterials. In contrast, poly(2-oxazine)s, which can be viewed as their higher backbone homologue, have received much less attention. A first step towards the assessment as potential biomaterials is the evaluation of the cytotoxicity of the polymers ...
Zuzana Kroneková   +3 more
openaire   +2 more sources

Recent Developments for the Ring Opening of Pyrrolidines and Unstrained Cyclic Amines via C−N Bond Cleavage

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
This review highlights recent advancements in the deconstructive transformation of unstrained cyclic amines, with a particular focus on the C−N bond cleavage of pyrrolidines. Various methodologies, including von Braun‐type, oxidative, and reductive approaches, facilitate the synthesis of diverse amines and the expansion of chemical space.
Eisuke Ota, Junichiro Yamaguchi
wiley   +1 more source

A Systematic Review of Synthetic and Anticancer and Antimicrobial Activity of Quinazoline/Quinazolin‐4‐one Analogues

open access: yesChemistryOpen, EarlyView.
Quinazoline represents an important class of heterocycles with diverse medicinal and pharmacological significance. This review systematically examines scholarly efforts toward understanding different synthetic pathways emphasizing the role of metal and non‐metal catalysts including some miscellaneous reagents employed in the synthesis of quinazoline ...
Neha Manhas   +4 more
wiley   +1 more source

QSAR studies of antimicrobial activity of 1,3-disubstituted-1H-naphtho[1,2-e][1,3]oxazines using topological descriptors

open access: yesArabian Journal of Chemistry, 2017
The antimicrobial activity of 1,3-disubstituted-1H-naphtho[1,2-e][1,3]oxazines was correlated with their physicochemical parameters using Hansch analysis for first time. The QSAR models were developed by both linear and multiple linear regression and the
Vikas Verma   +3 more
doaj   +1 more source

Chemical constitutions in the Colour Index™: A century of colourant classification

open access: yesColoration Technology, EarlyView.
Abstract This article details how the Colour Index™ (CI) system categorises and unambiguously labels commercial dyes and pigments based upon their chemical constitutions. It outlines the current process by which colourants that are new to the market find a place within CI and acquire generic identifiers.
Andrew Towns
wiley   +1 more source

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