Results 71 to 80 of about 913 (183)

Ortho-Palladation of (Z)-2-Aryl-4-Arylidene-5(4H)-Oxazolones. Structure and Functionalization

open access: yes, 2012
Ortho-palladated complexes of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones have been prepared through oxidative addition. The reaction of (Z)-2-phenyl-4-(2-bromobenzylidene)-5(4H)-oxazolone (4) with Pd2(dba)3·CHCl3 gives the six-membered cyclopalladated ...
Cativiela, Carlos   +4 more
core   +1 more source

Synthesis and Antifungal Activity of Oxazolones

open access: yes, 1982
Department of Chemistry, Punjab Agricultural University, Ludhiana-141 004 Manuscript received 5 February 1981, revised 22 December 1981, accepted 11 March 1982.
M. R. MANRAO   +3 more
openaire   +1 more source

5(4H)-Oxazolones. Part X. Acid and base effects on the translactonization reaction of 4-(2-oxa-alkylidene)-5(4H)-oxazolones: New synthesis of 5-alkylidene-3-benzoylamino-2(5H)-furanones

open access: yes, 1997
4-(2-Oxa-alkylidene)-5(4H)-oxazolones (azlactones) 1 can be transformed in acidic conditions (anhydrous HBr/CHCl3) into 5-alkylidene-3-benzoylamino-2(5H)-furanones 2 which have Z configuration at the exocyclic double bond.
M.L. Gelmi, F. Clerici, A. Melis
core   +1 more source

Reactive intermediates in peptide synthesis: First crystal structures and ab initio calculations of 2-alkoxy-5(4H)-oxazolones from urethane-protected amino acids

open access: yes, 1997
The structures of the 2-alkoxy-5(4H)-oxazolones derived from 2,2,6,6-tetramethyl-4-[(benzyloxycarbonyl)amino]-1-oxypiperidine-4-carboxylic acid and 2,2,6,6-tetramethyl-4-[(9'-fluorenylmethycarbonyl)amino]-1-oxycarbonylpiperidine-4-carboxylic acid have ...
BAGNO, ALESSANDRO   +4 more
core   +1 more source

5(4H)-oxazolones. Part XI. Cycloaddition reaction of oxazolones and munchnones to triphenylvinylphosphonium salts as synthetic equivalents of alkynes

open access: yes, 1998
5(4H)-Oxazolones 1 and milnchnones 3 are reacted with triphenylvinylphosphonium bromide 2a to give, through a cycloaddition reaction, pyrrole derivatives 4a-d and 7a-c unsubstituted at C-3 and C-4.
M.L. Gelmi, P. Trimarco, F. Clerici
core   +1 more source

Stereoselective, Ruthenium-Photocatalyzed Synthesis of 1,2-Diaminotruxinic Bis-amino Acids from 4-Arylidene-5(4H)-oxazolones. [PDF]

open access: yesJ Org Chem, 2022
Sierra S   +9 more
europepmc   +1 more source

A Carbodiimide-Fueled Reaction Cycle That Forms Transient 5(4H)-Oxazolones. [PDF]

open access: yesJ Am Chem Soc, 2023
Chen X   +8 more
europepmc   +1 more source

Alkylation of oxazolones and related heterocycles through an SN1 reaction.

open access: yes
The alkylation of oxazolones through an SN1 reaction by using stabilized carbocations is reported. The reaction (catalyzed by Brønsted acids, such as TFA or thioureas) affords the final compounds in excellent yields.
Font Bardia, Ma. Mercedes   +4 more
core   +1 more source

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