Mechanistic Insights into the Regioselective (3 + 2) Cycloaddition of Unsymmetrical Cyclopropenones with Elemental Sulfur: Experimental and Computational Studies. [PDF]
Rivero P +8 more
europepmc +1 more source
Nucleation‐Controlled Reconstruction of CuOx for Selective CO2 Electroreduction
The ratio of oxygen vacancies (Ov) and exposed Cu2O (111)/(200) of CuOx precatalyst is modulated by nucleation control of Cu(OH)2 precursor. Low Ov ratio and high ratio of Cu2O (111)/(200) in slow‐nucleated CuOx reconstructs to high‐coordinated oxide‐derived copper (OD‐Cu) during electrochemical CO2 reduction reaction (CO2RR) and exhibits enhanced ...
Ying Ying Ch'ng +14 more
wiley +1 more source
One-Pot Assembly of 2‑Pyrones through Copper-Catalyzed Cyclization of Propargylamines with Malonates. [PDF]
Li J, Liu S, Huang L, Huang J, Feng H.
europepmc +1 more source
Ru single atoms and RuP nanoclusters are co‐anchored in N, P, and B co‐doped porous carbon nanospheres via in situ carbonization/phosphidation of a boronate polymer precursor. RuP activates water, while nearby Ru single atoms accelerate H2 formation through H* transfer. The catalyst delivers low overpotential and high durability in alkaline HER and AEM
Xiaohong Wang +13 more
wiley +1 more source
Material-Efficient Synthesis of Polymer Membrane-Immobilized Metal Oxides for Advanced Oxidation Processes: Catalytic Mechanism, Stability and Performance. [PDF]
Hesaraki SAH +5 more
europepmc +1 more source
This review evaluates strategies for electrochemical CO2 reduction to ethylene, focusing on copper‐based catalyst design and microenvironment modulation to achieve industrial‐grade performance. By leveraging operando synchrotron‐based characterizations, we provide a multiscale understanding of dynamic structural transformations and key reaction ...
Meng Zhang, Zuolong Chen, Yimin A. Wu
wiley +1 more source
Photoinduced Transformation in Glyoxal- and Methylglyoxal-Ammonium Solutions: Role of Photolysis and Photosensitization. [PDF]
Gu J +7 more
europepmc +1 more source
This study develops a novel atomic engineering strategy to fine‐tune the spin state of α‐Fe2O3 catalysts toward a medium‐spin state, thereby modulating peroxymonosulfate activation and selectively yielding surface‐bound radicals. Compared with free radicals, surface‐bound radicals exhibit moderated oxidation potential, extended lifespan, surface ...
Shuyu Wang +7 more
wiley +1 more source
Self-assembled magnesium peroxide supramolecular hydrogel for oxidants neutralization and chemical burn management. [PDF]
Zhang M +5 more
europepmc +1 more source
Bioprosthetic aortic valves have revolutionized the treatment of aortic stenosis, but their durability is limited by structural valve deterioration (SVD). This review focuses on the pericardial tissue at the heart of these valves, examining how its mechanical properties and calcification drive fatigue and failure.
Gabriele Greco +7 more
wiley +1 more source

