Results 211 to 220 of about 139,618 (290)

Three‐Layer‐Structured Garnet‐Dominant Composite Solid Electrolyte for Solid‐State Batteries

open access: yesCarbon Energy, EarlyView.
The three‐layer‐structured garnet‐dominant composite solid electrolyte (GD‐CSE) is designed for solid‐state batteries. The GD‐CSE is composed of over 80 wt. % contents of LGLZO. This three‐layer CSE has high ionic conductivity and high potential stability.
Wooyoung Lee   +13 more
wiley   +1 more source

KI‐Doped α‐Mo2C Stably Catalyze Near‐Equilibrium CO2 to CO Beyond 1000 Hours

open access: yesCarbon Energy, EarlyView.
Through iodine doping and effective stabilization of surface oxygen content, KI‐doped α‐Mo2C achieves a sustained equilibrium yield ratio of 0.95 over 1000 h at 400°C and 4 bar in reverse water–gas shift (RWGS) reaction. Furthermore, the catalyst has been successfully scaled up to the kilogram level, indicating considerable potential for industrial ...
Haipeng Wang   +6 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3

open access: yesChemistry – A European Journal, EarlyView.
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius   +5 more
wiley   +1 more source

Oxygen isotopes suggest elevated thermometabolism within multiple Permo-Triassic therapsid clades. [PDF]

open access: yesElife, 2017
Rey K   +12 more
europepmc   +1 more source

Copper(II), a Peculiar Metal Ion for Complexation with Monensin A Ionophore

open access: yesChemistry – A European Journal, EarlyView.
Copper(II) forms three chiral and EPR‐active complexes with monensinate A in methanol. Beside the bis [CuL2] and mono [CuL]+ species, the new dinuclear construct [Cu2L]3+ exhibits an [ML]+‐type and a metal salt‐type copper(II) centers weakly bound to each other through counter ion(s) and thus, being magnetically independent.
Máté Levente Kis   +7 more
wiley   +1 more source

Simple Access to a Series of Higher Substituted Pentafluoroorthotellurate‐Based Silanes

open access: yesChemistry – A European Journal, EarlyView.
The pentafluoroorthotellurate ligand was introduced to organo silanes. A variety of silanes with the formular RxSi(OTeF5)4–x were synthesized and characterized via spectroscopic techniques and sc‐XRD. The influence of the number of OTeF5 groups on structural properties as well as the fluoride ion affinities (FIA) has been studied and compared to other ...
Friederike Oesten   +7 more
wiley   +1 more source

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