Results 81 to 90 of about 267,962 (256)

Interplay between oxygen redox and interfacial stability of Li-rich positive electrodes in sulfide-based all-solid-state batteries

Nature Communications
Understanding and manipulating the interplay between lattice oxygen redox and interfacial stability is critical for realizing the full potential of lithium-rich manganese-based oxide positive electrodes in all-solid-state lithium batteries.
Yuqi Wu, Fucheng Ren, Cheng Li, Chuanjing Xu, Huanran Wang, Jianrong Lin, Hanyan Wu, Qin Wang, Yiming Zou, Weidong Zhang, Guozhen Wei, Hongxin Lin, Ying Lin, Zhenyu Wang, Zhengliang Gong, Yong Yang   +15 more
doaj   +1 more source

Interaction‐Driven Assembly Pathways in Heterogeneous Active Microrobotic Systems

Advanced Functional Materials, EarlyView.
Peanut‐ and cube‐shaped light‐powered microrobots exhibit distinct magnetic and photocatalytic responses that determine their heterogeneous self‐assembly. In the dark, magnetic dipole interactions drive colloidal copolymerization with cubes acting as nucleation centers, whereas under light irradiation, phoretic interactions compete with magnetic ...
Domenico Calabrò, Roshan Velluvakandy, Martin Pumera, Francesco Priolo, Salvo Mirabella, Mario Urso   +5 more
wiley   +1 more source

Redox Processes Involving Oxygen: The Surprising Influence of Redox-Inactive Lewis Acids

JACS Au
Metalloenzymes with heteromultimetallic active sites perform chemical reactions that control several biogeochemical cycles. Transformations catalyzed by such enzymes include dioxygen generation and reduction, dinitrogen reduction, and carbon dioxide reduction-instrumental transformations for progress in the context of artificial photosynthesis and ...
Davide Lionetti, Sandy Suseno, Angela A. Shiau, Graham de Ruiter, Theodor Agapie   +4 more
openaire   +5 more sources

Atomically Dispersed Ni Site Catalysts Accelerating Sluggish Sulfur Redox Kinetics in Nonaqueous Zn‐S Batteries

Advanced Functional Materials, EarlyView.
An atomically dispersed Ni catalyst featuring Ni‐N4 coordination is developed as a sulfur host for nonaqueous Zn─S batteries. This configuration modulates the electronic structure to lower activation barriers during rate‐limiting steps and promotes a robust ZnF2‐rich cathode‐electrolyte interphase, thereby accelerating sulfur redox kinetics ...
Junhyuk Ji, Dongwoo Kim, Nuri Moon, Daehwan Kim, Keon Kim, Nahyung Kim, Young Yong Kim, Won Bae Kim   +7 more
wiley   +1 more source

Oxygen Redox in Battery Cathodes: A Brief Overview

The participation of oxygen or other anionic species in redox activities in cathode materials for lithium and sodium-ion battery systems is known to play a role in governing the useful capacity of these batteries. Directly probing anionic redox mechanisms is not possible, rather the computational analysis by density functional theory poses the main ...
Assadi, M. Hussein N., Hanaor, Dorian A. H.   +1 more
openaire   +2 more sources

Charge‐Tunable Coacervate Micelles for Separator Engineering in Lithium‐Sulfur Batteries

Advanced Functional Materials, EarlyView.
A separator engineering strategy based on charge‐tunable complex coacervate core micelles (C3Ms) is presented to form an ion‐selective layer regulating polysulfide transport in Li–S batteries. The micelles enable uniform adsorption onto commercial polypropylene separators and infiltration throughout the internal pore network, suppressing polysulfide ...
Yongsheng Zhang, J. R. Andrade Aguirre, Julien Es Sayed, Chongyang Jiang, Yuxuan Zhang, Xiaolong He, Yinyu Xiang, Yutao Pei, Xiangping Zhang, Petra Ruldolf, Marleen Kamperman, Giuseppe Portale   +11 more
wiley   +1 more source

Disentangling Bulk and Surface Contributions to Charge and Discharge Fading in High‐Voltage LiCoO2

Advanced Functional Materials, EarlyView.
High‐voltage operation of LiCoO2 accelerates capacity fading through bulk and surface degradation. By introducing a LiTaO3 coating to selectively suppress surface degradation, bulk and surface contributions to charge and discharge fading are decoupled.
Hyungjoon Moon, Sangbin Park, Jaewoo Jung, Seongeun Lee, Chanwoo Jung, Min‐Sik Park, Won‐Sub Yoon   +6 more
wiley   +1 more source

Enhanced CO2-splitting by reverse water-gas shift chemical looping over porous silica supported CoFe2O4 oxygen carriers

DeCarbon
Reverse water-gas shift chemical looping (RWGS-CL) process is a highly attractive thermochemical CO2 utilization technology, yet oxygen carriers often suffer from insufficient low-temperature oxygen mobility and deactivation by high-temperature sintering.
Kaiyuan Shi, Jie Gao, Jingyu Ran, Xin Huang, Yunlin Shao, Chuan Ma   +5 more
doaj   +1 more source

Network Topology Governs Photocatalytic Water Splitting in Organic Two‐Dimensional Crystals

Advanced Functional Materials, EarlyView.
Network topology in organic two‐dimensional crystals (O2DCs) dictates the photocatalytic water splitting performance. Kagome‐lattice O2DCs exhibit strong electron‐hole mass asymmetry, spatially separated carriers, and longer recombination lifetimes, exceeding rhombic isomers.
Preeti Bhauriyal, Thomas Heine
wiley   +1 more source

Confinement‐Engineered Thermally Programmed Ion‐Gating Separator for Decoupling Thermal–Electrochemical Feedback in High‐Energy Lithium‐Ion Batteries

Advanced Functional Materials, EarlyView.
A new phase‐change material encapsulated membrane offers more thermal resilience stability and safety than the conventional separators for batteries. ABSTRACT Thermal runaway in lithium‐ion batteries arises from the intrinsic coupling between heat generation and ion transport, yet conventional shutdown separators primarily rely on passive pore collapse
Sumedha Rajpoot, Wei‐Nien Su, Sheng‐Chiang Yang, Yu Chun Huang, Wahyu Fiqih Virdiansyah, Ashok Ranjan, Han‐Hsuan Hsieh, Chia‐Lung Hsieh, Yu‐Wei Li, Yosef Nikodimos, Zabish Bilew Muche, Yu Jen Liang, Chia‐Chi Wang, Chih‐Ching Liu, Gao‐Jhih Liang, Chun‐Chen Yang, She‐Huang Wu, Bing Joe Hwang   +17 more
wiley   +1 more source