Results 21 to 30 of about 11,252 (184)

Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity‐Matched N‐Radical Cations

Angewandte Chemie, EarlyView.
Highly electrophilic N‐radical cations enable efficient and selective H‐atom transfer (HAT) of unprotected amines. In this exceedingly practical strategy, simple CuCl catalyzes an interrupted Hofmann–Löffler–Freytag (HLF) reaction to afford δ desaturated amines, aza‐heterocycles, and C─H aminated alkanes without protecting groups.
Pavitra Laohapaisan, Ross M. Dare, Meredith L. Rudich, Jacob J. A. Garwood, Siyuan Gong, R. Thomas Simons, David A. Nagib   +6 more
wiley   +2 more sources

Proteome‐Wide Target Identification Using Reactive Metallo‐Scaffolds (r‐mS): A Platform for Metallodrug Discovery

Angewandte Chemie, EarlyView.
Re‐envisioning the Ligandable Proteome: Reactive Metallo‐Scaffolds (r‐mS) combine non‐covalent protein engagement by a metallo‐scaffold with covalent cysteine capture through a tethered chloroacetamide warhead. Chemoproteomic profiling reveals unique enzyme engagement including ligases, kinases and methyltransferases, highlighting opportunities for ...
Jessica E. Waters, Harry Wilders, George S. Biggs, Mika Kintzel, Emma E. Cawood, Jonathan Bailey, Sarah Maslen, Yew Mun Yip, Mason Wakley, Ioannis G. Riziotis, Thomas W. Rees, Joanna Redmond, J. Mark Skehel, David House, Jacob Bush, Jeannine Hess   +15 more
wiley   +2 more sources

The Enantioselective Metabolism of p-Cymene in Rabbits.

Chemical and Pharmaceutical Bulletin, 1992
p-Cymene (1) was metabolized in rabbits and the following four optically active metabolites, 2-(p-tolyl)-1-propanol (3': R/S = 65:35), 2-(p-tolyl)propanoic acid (5': R/S = 0:100), p-(2-hydroxy-1-methylethyl)benzoic acid (6': R/S = 91:9) and p-(1-carboxyethyl)benzoic acid (8': R/S = 30:70), were isolated in addition to three optically inactive ...
MATSUMOTO, Takashi, ISHIDA, Takashi, YOSHIDA, Toshio, TERAO, Hiromitsu, TAKEDA, Yoshio, ASAKAWA, Yoshinori   +5 more
openaire   +3 more sources

Autoxidation of p-Cymen

The Journal of the Society of Chemical Industry, Japan, 1958
p-シメンの液相エマルジョン状酸素酸化において, 水層の初期pHを変え, 各pHにおけるp-シメンヒドロペルオキシドの生成限界濃度および反応率を求めた。また生成したペルオキシドを酢酸分解し,その生成物中に従来よく知られていたp-クレゾール, アセトン, クミン酸, p-メチルアセトフェノン, p-α-ジメチルスチレンの他にp-トリル酢酸を見出した。このことから, 今までに知られていたp-シメン-8-ヒドロペルオキシドおよび7-ヒドロペルナキシドの他に,9-ヒドロペルオキシドも少量ながら生成していることが推定される。
Junsaburo Yamamoto, Kunio Hata
openaire   +2 more sources

(η6-p-Cymene)bis(trichloridostannyl)(triethoxyphosphine-κP)ruthenium(II)

Acta Crystallographica Section E, 2009
In the title complex, [RuSn2(C10H14)Cl6(C6H15O3P)], the Ru—Sn bond lengths [2.5619 (3) and 2.5669 (3) Å] are about 0.3 Å shorter than the sum of the covalent Ru and Sn radii (1.46& ...
Sergey S. Shapovalov, Bruno Therrien
doaj   +1 more source

p-Cymene ruthenium thioether complexes [PDF]

Journal of Organometallic Chemistry, 2007
Abstract Thioethers PhC2H4SMe, PhC3H6SiPr and MeSAllyl form substitutionally labile monomeric adducts (p-cymene)RuCl2(SRR′) (2a–c) upon treatment with the {(p-cymene)RuCl2}2 dimer (p-cymene = η6-MeC6H4iPr-1,4). Pure adducts were obtained by crystallization from CH2Cl2/Et2O, and 2a,c as well as the bis(thioether) complex [ ( p -cymene ) RuCl
Winter, Rainer F., Cubrilo, Jadranka, Hartenbach, Ingo, Lissner, Falk, Schleid, Thomas, Niemeyer, Mark   +5 more
openaire   +2 more sources

Dichlorido(η6-p-cymene)[tris(2-cyanoethyl)phosphine]ruthenium(II)

Molbank, 2018
The tris(2-cyanoethyl)phosphine (tcep) complex [RuCl2{P(CH2CH2CN)3}(η6-p-cymene)] (p-cymene = p-CH3C6H4iPr) was synthesised by the bridge-splitting reaction of the chlorido-dimer [RuCl2(η6-p-cymene)]2 with tcep.
William Henderson, Ashwin Gopalan Nair, Nathan R. Halcovich, Edward R. T. Tiekink   +3 more
doaj   +1 more source

<em></em>p-Cymene Protects Mice Against Lipopolysaccharide-Induced Acute Lung Injury by Inhibiting Inflammatory Cell Activation

Molecules, 2012
The objective of this study was to test the hypothesis that <em>p</em>-cymene can attenuate acute lung injury induced by lipopolysaccharide (LPS)<em> in vivo</em>.
Haihua Feng, Hongyu Li, Qianchao Wu, Ying Xiong, Fang Liu, Lanan Wassy Soromou, Na Chen, Guanghong Xie, Guowen Liu   +8 more
doaj   +1 more source

Short-term effect of biochar on the improvement of calcareous soil biological properties and marjoram (Origanum majorana L.) growth under greenhouse conditions in a Mediterranean climate

Notulae Botanicae Horti Agrobotanici Cluj-Napoca, 2022
In the cultivation of medicinal and aromatic plants may be possible to improve the biological properties of the soil and to grow plants with properties close to those in the natural environment by using the valuable organic matter resources obtained by ...
Ismail Emrah TAVALI
doaj   +1 more source

A Synthesis of Thymol from p-Cymene. [PDF]

Journal of Industrial & Engineering Chemistry, 1920
n ...
Phillips, Max, Gibbs, H. D.
openaire   +2 more sources