Results 251 to 260 of about 481,863 (320)

(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3

open access: yesChemistry – A European Journal, EarlyView.
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius   +5 more
wiley   +1 more source

Protonation‐Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes

open access: yesChemistry – A European Journal, EarlyView.
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann   +5 more
wiley   +1 more source

l‐Leucine‐Based Layered Coordination Polymer Supports for Immobilizing Basic Salts to Yield Solid CO2 Adsorbents Resistant to Moisture and Oxidation

open access: yesChemistry – A European Journal, EarlyView.
A layered amino acid–based coordination polymer, (Zn(Leu)2), acts as a support that immobilizes diverse basic salts. The resulting solid sorbents remain nondeliquescent under humid, DAC‐relevant feeds while enabling CO2 capture. The interlayer‐immobilized sorbents exhibit high oxidative stability after accelerated oxidative aging, unlike conventional ...
Yuki Kohno, Takuji Ikeda, Takashi Makino
wiley   +1 more source

Senescent Astrocytes: A New Player in Brain Aging and Cognitive Decline. [PDF]

open access: yesBrain Sci
Pessoa B   +5 more
europepmc   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Resolving a Nearly Two‐Centuries‐Old Mystery: On the Structural Chemistry and Physicochemical Properties of Compounds Associated With the Term Ammelide

open access: yesChemistry – A European Journal, EarlyView.
The crystal structure of ammelide, also known as melanuric acid, was solved almost 200 years after its discovery by Liebig. Moreover, three modifications of its 1:1 adduct with ammeline were structurally elucidated, consisting of layers with a honeycomb motif analogous to melamine cyanurate.
Thaddäus J. Koller   +8 more
wiley   +1 more source

Endogenous p21 levels protect genomic stability by suppressing both excess and restrained nascent DNA syntheses. [PDF]

open access: yesSci Adv
Calzetta NL   +8 more
europepmc   +1 more source

Combinatorial expression of glial transcription factors induces Schwann cell‐specific gene expression in mouse embryonic fibroblasts

open access: yesDevelopmental Dynamics, EarlyView.
Abstract Background Schwann cells provide peripheral nerve trophic support, myelinate axons, and assist in repair. However, Schwann cell repair capacity is limited by chronic injury, disease, and aging. Schwann cell reprogramming is a cellular conversion strategy that could provide a renewable cell supply to repair injured nerves.
Lauren Belfiore   +7 more
wiley   +1 more source

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