Results 51 to 60 of about 2,750 (239)

Parahydrogen-induced polarization in H2 activations and hydrogenations mediated by metal-free catalysts

open access: yes, 2023
The aim of this thesis is to study the metal-free activation of parahydrogen and the subsequent effects of parahydrogen-induced polarization (PHIP). PHIP is a nuclear spin hyperpolarization method that dramatically increases the sensitivity in NMR by ...
Zakharov, Danila O.
core   +1 more source

Parahydrogen Hyperpolarization Allows Direct NMR Detection of α‐Amino Acids in Complex (Bio)mixtures

open access: yesAngewandte Chemie, 2021
The scope of non‐hydrogenative parahydrogen hyperpolarization (nhPHIP) techniques has been expanding over the last years, with the continuous addition of important classes of substrates.
Lisanne Sellies   +4 more
semanticscholar   +1 more source

Parahydrogen-induced polarization with a metal-free P–P biradicaloid [PDF]

open access: yes, 2019
Metal-free H₂ activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques.
Igor V. Koptyug   +7 more
core   +3 more sources

Adsorption of parahydrogen on graphene [PDF]

open access: yesPhysical Review B, 2018
Replaced with published ...
Dusseault, Marisa, Boninsegni, Massimo
openaire   +2 more sources

Parahydrogen and Radiofrequency Amplification by Stimulated Emission of Radiation Induce Through-Space Multinuclear NMR Signal Enhancement

open access: yes, 2022
Hyperpolarized (i.e., polarized far beyond the thermal equilibrium) nuclear spins can result in radiofrequency amplification by stimulated emission of radiation (RASER) effect.
Oleg G., Salnikov   +6 more
core   +1 more source

Hyperpolarization of Nitrile Compounds Using Signal Amplification by Reversible Exchange

open access: yesMolecules, 2020
Signal Amplification by Reversible Exchange (SABRE), a hyperpolarization technique, has been harnessed as a powerful tool to achieve useful hyperpolarized materials by polarization transfer from parahydrogen.
Sarah Kim   +6 more
doaj   +1 more source

Clinical-Scale Production of Nearly Pure (>98.5%) Parahydrogen and Quantification by Benchtop NMR Spectroscopy

open access: yesAnalytical Chemistry, 2021
Due to the extensive chemical, physical and biomedical applications of parahydrogen, the need exists for the development of highly enriched parahydrogen in a robust and efficient manner.
Shiraz Nantogma   +3 more
semanticscholar   +1 more source

1, 3-Butadienen Hydrogenation on Supported Pd-Sn Bimetallic Catalysts Investigated by Parahydrogen-induced Polarization

open access: yesChinese Journal of Magnetic Resonance, 2022
The selective hydrogenation of 1, 3-butadiene over Pd-Sn/Al2O3 bimetallic catalysts was investigated by heterogeneous parahydrogen-induced polarization (PHIP). A series of Pd1-Snx/Al2O3 bimetallic catalysts with different Pd/Sn ratios were synthesized by
Han HU, Wei-yu WANG, Jun XU, Feng DENG
doaj   +1 more source

Symmetry Constraints on Spin Order Transfer in Parahydrogen-Induced Polarization (PHIP) [PDF]

open access: yesSymmetry, 2021
It is well known that the association of parahydrogen (pH2) with an unsaturated molecule or a transient metalorganic complex can enhance the intensity of NMR signals; the effect is known as parahydrogen-induced polarization (PHIP). During recent decades,
Andrey N. Pravdivtsev   +3 more
semanticscholar   +1 more source

Parahydrogen-Induced Magnetization of Jovian Planets?

open access: yes, 2020
A long-overdue hypothesis on the origin of the magnetic field of Jovian planets is presented. It is proposed that rapid parahydrogen ↔ orthohydrogen exchange catalyzed by aerosol clouds of parahydrogen-rich planetary layers renders a hyperpolarized ...
Eduard Y. Chekmenev (1290312)   +1 more
core   +1 more source

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