Results 71 to 80 of about 4,129 (201)

Continuous‐Wave (CW) Photo‐CIDNP NMR Spectroscopy: A Tutorial

open access: yesMagnetic Resonance in Chemistry, Volume 63, Issue 12, Page 1020-1034, December 2025.
ABSTRACT Photo‐chemically induced dynamic nuclear polarisation (photo‐CIDNP) is a nuclear spin‐selective magnetic resonance phenomenon that has traditionally been used to mechanistically study chemical reactions involving the (transient) formation of radical molecular species, extract EPR observables of short‐lived radicals, probe biomolecular ...
Lars T. Kuhn, Míriam Pérez‐Trujillo
wiley   +1 more source

13C MRI of hyperpolarized pyruvate at 120 µT

open access: yesScientific Reports
Nuclear spin hyperpolarization increases the sensitivity of magnetic resonance dramatically, enabling many new applications, including real-time metabolic imaging.
Nicolas Kempf   +8 more
doaj   +1 more source

Parahydrogen-Based Hyperpolarization for the Masses at Millitesla Fields

open access: yesMagnetochemistry
Hyperpolarization (HP) techniques, such as Parahydrogen-Induced Polarization (PHIP), Signal Amplification by Reversible Exchange (SABRE), and dissolution Dynamic Nuclear Polarization (d-DNP), significantly enhance the sensitivity of nuclear magnetic ...
Garrett L. Wibbels   +15 more
doaj   +1 more source

Optimal Variable Flip Angle Schemes for Hyperpolarized MR Kinetic Modeling Robust to RF Field Variations

open access: yesNMR in Biomedicine, Volume 38, Issue 11, November 2025.
Optimization of variable flip angle schemes that minimize the variances of conversion rate estimates derived from hyperpolarized magnetic resonance experiments. Simulations based on in vitro experiments validated the improved parameter estimation and robustness of the optimized variable flip angle schemes.
Marie Frederikke Garnæs   +5 more
wiley   +1 more source

Reversible Parahydrogen Induced Hyperpolarization of 15N in Unmodified Amino Acids Unraveled at High Magnetic Field

open access: yesAdvanced Science, 2023
Amino acids (AAs) and ammonia are metabolic markers essential for nitrogen metabolism and cell regulation in both plants and humans. NMR provides interesting opportunities to investigate these metabolic pathways, yet lacks sensitivity, especially in case
Ewoud Vaneeckhaute   +4 more
doaj   +1 more source

PHIP hyperpolarized [1-13C]pyruvate and [1-13C]acetate esters via PH-INEPT polarization transfer monitored by 13C NMR and MRI

open access: yesScientific Reports, 2021
Parahydrogen-induced polarization of 13C nuclei by side-arm hydrogenation (PHIP-SAH) for [1-13C]acetate and [1-13C]pyruvate esters with application of PH-INEPT-type pulse sequences for 1H to 13C polarization transfer is reported, and its efficiency is ...
Alexandra Svyatova   +8 more
doaj   +1 more source

Deep Learning for Hyperpolarized NMR of Intrinsically Disordered Proteins without Resolution Loss: Access to Short‐Lived Intermediates

open access: yesChemistry – A European Journal, Volume 31, Issue 59, October 22, 2025.
Abstract The inherently low sensitivity of solution‐state Nuclear Magnetic Resonance (NMR) has long limited its ability to characterize transient biomolecular states at atomic resolution. While dissolution dynamic nuclear polarization (dDNP) offers a compensating signal enhancement, its broader use has been hindered by rapid polarization decay, causing
Ertan Turhan   +5 more
wiley   +1 more source

Hyperpolarization of [13C]formate using parahydrogen

open access: yesJournal of Magnetic Resonance Open
Sodium [13C]formate was successfully hyperpolarized using parahydrogen-induced polarization by means of side-arm hydrogenation (PHIP-SAH). Allyl [13C]formate was hyperpolarized using homogeneous hydrogenation of the corresponding unsaturated precursor ...
Dudari B. Burueva   +7 more
doaj   +1 more source

Computer program for calculating thermodynamic and transport properties of fluids [PDF]

open access: yes, 1975
Computer code has been developed to provide thermodynamic and transport properties of liquid argon, carbon dioxide, carbon monoxide, fluorine, helium, methane, neon, nitrogen, oxygen, and parahydrogen.
Braon, A. K.   +2 more
core   +1 more source

Polarized nuclear target based on parahydrogen induced polarization

open access: yes, 2012
We discuss a novel concept of a polarized nuclear target for accelerator fixed-target scattering experiments, which is based on parahydrogen induced polarization (PHIP). One may be able to reach a 33% free-proton polarization in the ethane molecule.
Abbon   +42 more
core   +1 more source

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