Results 21 to 30 of about 563 (145)

Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum

open access: yesDalton Transactions, 2004
The divergent behavior of palladium(0) and platinum(0) is revealed in the reactivity of [M(PR3)2] (M = Pd or Pt; R = Cy or iPr) toward pentafluoropyridine and 2,3,5,6-tetrafluoropyridine.
Neumann, B.   +7 more
core   +5 more sources

Tetrahydropyrido[3,4-b]pyrazine Scaffolds from Pentafluoropyridine

open access: yes, 2016
Representative polyfunctional tetrahydropyrido[3,4-b]pyrazine scaffolds have been synthesized very readily by a one-pot annelation reaction of pentafluoropyridine with appropriate diamines.
Dmitrii S. Yufit (2270068)   +4 more
core   +5 more sources

4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine

open access: yesMolbank, 2023
The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li   +4 more
doaj   +1 more source

4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)

open access: yesMolbank, 2023
The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS,
Katelyn D. Thompson   +3 more
doaj   +1 more source

Pentafluoropyridine

open access: yes, 2005
Graham Sandford
core   +2 more sources

The development of new applications for pentafluoropyridine in organic chemistry.

open access: yes, 2023
Esters are a class of organic compounds, that have uses in a wide variety of industries including, fragrances, lubrication, and medicine. One of the most common ways to approach ester synthesis is through a reactive acyl chloride moiety which is accessed
Beardmore, Liam Nicholas Declan
core   +5 more sources

Regioselective Transfer Hydrogenative Defluorination of Polyfluoroarenes Catalyzed by Bifunctional Azairidacycle

open access: yesOrganics, 2022
The catalytic hydrodefluorination (HDF) with a bifunctional azairidacycle using HCOOK was examined for cyano- and chloro-substituted fluoroarenes, including penta- and tetrafluorobenzonitriles, tetrafluoroterephthalonitrile, tetrafluorophthalonitrile, 3 ...
Asuka Matsunami   +2 more
doaj   +1 more source

Reaction of hydroxyl-quinoline with pentafluoropyridin. [PDF]

open access: yesSpringerplus, 2016
Reaction of pentafluoropyridine with 2 or 8-hydroxyl-quinoline under basic conditions in acetonitrile gives 4-oxy quinoline 2,3,5,6-tetrafluoropyridine derivatives in good yields. All the compounds were characterized using 1H, 13C, 19F-NMR and MS spectroscopy.
Beyki K, Maghsoodlou MT, Heydari R.
europepmc   +3 more sources

Reaction of hydroxylated naphtoquinones/antraquinones with pentafluoropyridine [PDF]

open access: yesSpringerPlus, 2016
In this study, the reaction of pentafluoropyridine with hydroxylated naphtoquinones and hydroxylated antraquinones was investigated under basic conditions in DMF. One or two hydroxyl group in naphtoquinones and antraquinones react with pentafluoropyridine to give mono and di-tetrafluoropyridyl naphtoquinones/antraquinones.
Beyki, Khalil   +2 more
openaire   +2 more sources

Real-time observation of multi-mode vibronic coherence in pentafluoropyridine [PDF]

open access: yesThe Journal of Chemical Physics, 2017
The ultrafast dynamics of pentafluoropyridine in the 1 1B2 (ππ*) electronic state excited at λpump = 255 nm is investigated by femtosecond time-resolved time-of-flight mass spectrometry and photoelectron imaging spectroscopy. A pronounced, long-lived, and complex periodic modulation of the transient ion yield signal with contributions by four distinct ...
J. A. Kus, O. Hüter, F. Temps
openaire   +2 more sources

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