Results 21 to 30 of about 448 (148)

Ultrasound promoted facile synthesis of some pentafluoropyridine derivatives at ambient conditions

open access: yesUltrasonics Sonochemistry, 2011
Some pentafluoropyridine derivatives have been synthesized by the reaction of pentafluoropyridine with appropriate mono and bidentate nucleophile under ultrasonic irradiation. This new methodology provides good to excellent yields in short reaction times (25-120 min) at room temperature.
Reza Ranjbar-Karimi, Ali Darehkordi
exaly   +3 more sources

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine

open access: yesDalton Transactions, 2010
The hydrido complexes trans-[Pd(H)(4-C(5)NF(4))(PiPr(3))(2)] (3) and trans-[Pd(H)(4-C(5)NF(4))(PCy(3))(2)] (5) can be prepared by reaction of trans-[Pd(F)(4-C(5)NF(4))(PiPr(3))(2)] (2) or trans-[Pd(F)(4-C(5)NF(4))(PCy(3))(2)] (4) with HBpin (HBpin = 4,4,5,5-tetramethyl-1,3,2-dioxaborolane, pinacolborane).
David, Breyer   +2 more
core   +5 more sources

Tetrahydropyrido[3,4-b]pyrazine Scaffolds from Pentafluoropyridine

open access: yes, 2016
Representative polyfunctional tetrahydropyrido[3,4-b]pyrazine scaffolds have been synthesized very readily by a one-pot annelation reaction of pentafluoropyridine with appropriate diamines.
Dmitrii S. Yufit (2270068)   +4 more
core   +5 more sources

4-(4-(2-Bromoethyl)phenoxy)-2,3,5,6-tetrafluoropyridine

open access: yesMolbank, 2023
The title compound was synthesized in near quantitative yields via initial nucleophilic aromatic substitution of pentafluoropyridine (PFP) with 4-(2-bromoethyl)phenol as a versatile precursor for ionic liquids (ILs).
Tiffany H. Li   +4 more
doaj   +1 more source

4,4′-(((Perfluoropropane-2,2-diyl)bis(4,1-phenylene))bis(oxy))-bis(2,3,5,6-tetrafluoropyridine)

open access: yesMolbank, 2023
The title compound was synthesized in near-quantitative yield using nucleophilic aromatic substitution of 4,4′-(hexafluoroisopropylidene)diphenol (BPAF) with perfluoropyridine (PFP). The purity and structure were determined by NMR (1H, 13C, 19F), GC–EIMS,
Katelyn D. Thompson   +3 more
doaj   +1 more source

Regioselective Transfer Hydrogenative Defluorination of Polyfluoroarenes Catalyzed by Bifunctional Azairidacycle

open access: yesOrganics, 2022
The catalytic hydrodefluorination (HDF) with a bifunctional azairidacycle using HCOOK was examined for cyano- and chloro-substituted fluoroarenes, including penta- and tetrafluorobenzonitriles, tetrafluoroterephthalonitrile, tetrafluorophthalonitrile, 3 ...
Asuka Matsunami   +2 more
doaj   +1 more source

Real-time observation of multi-mode vibronic coherence in pentafluoropyridine [PDF]

open access: yesThe Journal of Chemical Physics, 2017
The ultrafast dynamics of pentafluoropyridine in the 1 1B2 (ππ*) electronic state excited at λpump = 255 nm is investigated by femtosecond time-resolved time-of-flight mass spectrometry and photoelectron imaging spectroscopy. A pronounced, long-lived, and complex periodic modulation of the transient ion yield signal with contributions by four distinct ...
J. A. Kus, O. Hüter, F. Temps
openaire   +2 more sources

Computational study of the hydrodefluorination of fluoroarenes at [Ru(NHC)(PR3)2(CO)(H)2]: predicted scope and regioselectivities [PDF]

open access: yes, 2013
Density functional theory calculations have been employed to investigate the scope and selectivity of the hydrodefluorination (HDF) of fluoroarenes, C6F6-nHn (n = 0-5), at catalysts of the type [Ru(NHC)(PR3)(2)(CO)(H)(2)].
Panetier, Julien A.   +6 more
core   +1 more source

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