A New Family of Styrene/Diene Rubbers [PDF]
International audienceThe insertion of single styrene units into polyisoprene is demonstrated using borohydrido rare earth/dialkylmagnesium systems. This yields a new family of styrene/diene copolymers (SBR rubbers).
Mortreux, André +4 more
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The title complex, [Ru(C10H15)(C10H13NO2)](C24H20B)·C3H6O, is related to the analogous O-methyl complex. The average Ru—C distance to the pentamethylcyclopentadienyl (Cp*) group is 2.19 (3) Å, and 2.21&#
Bradley T. Loughrey +2 more
doaj +1 more source
Liquid Phase Electrochemistry at Ultralow Temperatures [PDF]
Fluid electrolyte solutions based on mixtures of butyronitrile (PrCN) and ethyl chloride (EtCl) with or as electrolyte freeze below −180°C and provide excellent media for cryogenic electrochemical experiments.
Ching, Stanton +3 more
core +2 more sources
Synthesis and reactivities of a new mononuclear hydroxidoiridium(III) complex with a pentamethylcyclopentadienyl (Cp*) ligand are reported. The hydroxido ligand was introduced into an iridium complex having a nonprotic amine chelate derived from N-mesyl ...
Shoko Kamezaki +3 more
doaj +1 more source
Experimental and Theoretical Study of the Polynuclear Bismuth Compounds : Dimers, Clusters, Molecular Self-Assemblies and Polyhedral Cage Molecules [PDF]
In the framework of this thesis, the polynuclear bismuth chemistry has been investigated from different perspectives with the main focus on four types of the chemical bonding.
Monakhov, Kirill
core +1 more source
Enantiopure Ferrocene-Based Planar-Chiral Iridacycles:Stereospecific Control of Iridium-Centred Chirality [PDF]
Reaction of [IrCp*Cl-2](2) with ferrocenylimines (Fc=NAr, Ar=Ph, p-MeOC6H4) results in ferrocene C-H activation and the diastereoselective synthesis of half-sandwich iridacycles of relative configuration S-p*,R-Ir*.
Albrecht +78 more
core +1 more source
The title compound, [Co(C10H15)2]2[CoCl4]·2CH2Cl2, was isolated as a dichloromethane solvate and was formed in the reaction between lithium pentamethylcyclopentadienide and anyhydrous cobalt(II) chloride in tetrahydrofuran.
Joseph S. Merola +2 more
doaj +1 more source
Erratum: “Atomic layer deposition of high purity Ga2O3 films using liquid pentamethylcyclopentadienyl gallium and combinations of H2O and O2 plasma” [J. Vac. Sci. Technol. A 38, 022412 (2020)] [PDF]
Fumikazu Mizutani +3 more
openalex +1 more source
Experimental and theoretical characterization of the Zn - Zn bond in [Zn2(η5-C5Me5)2] [PDF]
The existence and characterization of a bond between the Zn atoms in the recently synthesized complex [Zn2(5-C5Me5)2], as well as between Zn and ligand C atoms is firmly based on neutron diffraction and low-temperature X-ray synchrotron diffraction ...
Carmona Guzmán, Ernesto +9 more
core +1 more source
Synthese, Kristallstruktur und Eigenschaften von Tetraaminophosphonium-iodid P(NH2)4I [PDF]
The title compound has been prepared starting from phosphorothionic triamide SP(NH2)3 by methylation of the sulfur atom and subsequent ammonolysis reaction in dry acetonitrile and dichloromethane, respectively, both at room temperature.
Horstmann, Stefan, Schnick, Wolfgang
core +1 more source

