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Copper Imidazolin-imine Coordination Compounds as Precursors for a Cu/Al Complex. [PDF]
Antsiburov I +4 more
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A Mixed-Valent and High-Spin Vanadium Phosphide. [PDF]
Chandran A +7 more
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Pentamethylcyclopentadienyl Ir(III) metallacycles: recent developments in catalysis
Vincent Rysak +3 more
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Pentamethylcyclopentadienyl diruthenium chemistry
Journal of the Chemical Society, Chemical Communications, 1984The Chemistry of the diruthenium centre, when stabilised by η-C5Me5 ligands, provides examples of new organic transformations (e.g. isomerisation of ethylene to ethylidene, addition of ethylene to vinylidene) and new species {e.g.[Ru2(CO)2(µ-H)2(η-C5Me5)2]}.
Nigel J. Forrow, Selby A. R. Knox
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Journal of Organometallic Chemistry, 1985
Abstract Reaction of dichloro- or dibromo-(pentamethylcyclopentadienyl)phosphane with Group I or Group II metals gives pentamethylcyclopentadienyl substituted diphosphene, bicyclo[1.1.0]tetraphosphane, cyclotetraphosphane and cyclotriphosphanes, which have been unambiguously characterised from their NMR data.
Jutzi, Peter, WIPPERMANN, T
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Abstract Reaction of dichloro- or dibromo-(pentamethylcyclopentadienyl)phosphane with Group I or Group II metals gives pentamethylcyclopentadienyl substituted diphosphene, bicyclo[1.1.0]tetraphosphane, cyclotetraphosphane and cyclotriphosphanes, which have been unambiguously characterised from their NMR data.
Jutzi, Peter, WIPPERMANN, T
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Amidobis(pentamethylcyclopentadienyl)titanium(III)
Acta Crystallographica Section C Crystal Structure Communications, 1995The title compound, [Ti(NH 2 )(Me 5 C 5 ) 2 ] (I), is a bent metallocene with the NH 2 group oriented so as to maximize the π interaction between the N and Ti atoms.
E. Brady +3 more
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Pentamethylcyclopentadienyl-übergangsmetall-π- komplexe
Journal of Organometallic Chemistry, 1985Abstract The complex [Cp′Co(μ-Cl)] 2 , (Cp′ = η 5 -C 5 Me 5 ), 2a , is cleaved by pyridine to yield the mononuclear, paramagnetic cobalt(II) halfsandwich compound Cp′CoCl(C 5 H 5 N), 3a . Single crystal structure determination of 3a confirms its monomeric structure in the solid state and reveals CoC bond lengths (206–209 pm) comparable to those ...
E. Raabe, U. Koelle
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Organometallics, 1990
By treatment of the alkoxo complex (Cp{sup *}Ru(OMe)){sub 2} with acid or trimethylsilyl trifluoromethanesulfonate in the presence of a polycyclic arene, the monocations Cp{sup *}Ru(arene){sup +} (arene = naphthalene ((1){sup +}), phenanthrene ((2){sup +}), pyrene ((3){sup +}), anthracene ((4){sup +})) and dications (Cp{sup *}Ru){sub 2}(arene){sup 2+} (
Ulrich Koelle, Maja Hong Wang
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By treatment of the alkoxo complex (Cp{sup *}Ru(OMe)){sub 2} with acid or trimethylsilyl trifluoromethanesulfonate in the presence of a polycyclic arene, the monocations Cp{sup *}Ru(arene){sup +} (arene = naphthalene ((1){sup +}), phenanthrene ((2){sup +}), pyrene ((3){sup +}), anthracene ((4){sup +})) and dications (Cp{sup *}Ru){sub 2}(arene){sup 2+} (
Ulrich Koelle, Maja Hong Wang
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ChemInform, 1987
AbstractThe title chloride (I) undergoes replacement of chlorine by various nucleophiles such as silyl‐substituted cyclopentadienides (II), Li amides LiR4R5, or LiCH(SiMe3)2 to give the unsym. germanocenes (III), the unsym. substituted new germylenes (V), or (VI).
P. JUTZI +3 more
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AbstractThe title chloride (I) undergoes replacement of chlorine by various nucleophiles such as silyl‐substituted cyclopentadienides (II), Li amides LiR4R5, or LiCH(SiMe3)2 to give the unsym. germanocenes (III), the unsym. substituted new germylenes (V), or (VI).
P. JUTZI +3 more
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