From Yield to Flavor: The Role of Lipid Coatings in Beef Aging
Journal of Food Science, Volume 91, Issue 7, July 2026.ABSTRACT Lipid‐coated aging has been proposed as an alternative to enhance flavor, particularly using butter as a coating material (butter‐aged beef). Thus, this study compared the wet‐aged and beef‐aged with different lipid‐based coatings: milk butter (butter‐aged), cocoa butter (cocoa‐aged), pork lard (lard‐aged), and beef tallow (tallow‐aged), all ...
Jonatã Henrique Rezende‐de‐Souza +10 more
wiley +1 more source
Nickel-catalyzed radical relay enabled chemoselective fluoroalkyl-borylation of [1.1.1]propellane under kinetic control. [PDF]
Sci AdvWu Y +6 more
europepmc +1 more source
Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides. [PDF]
J Am Chem SocEsteve Guasch J, Pal D, Suero MG.
europepmc +1 more source
Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n‐Pentene
Angewandte Chemie, Volume 138, Issue 25, 15 June 2026.Alkene cracking in medium‐pore zeolites is governed by a balance of enthalpic and entropic effects. Intrinsic barriers are quantified and shown to be lower than for alkanes due to stabilization of carbenium‐ion‐like transition states. Confinement and extra‐framework aluminum modulate reactivity by tuning transition‐state energetics, providing a ...
Ruixue Zhao +4 more
wiley +2 more sources
Regiodivergent Lewis acid catalysis of bicyclo[1.1.0]butanes with 2-naphthols. [PDF]
Chem SciFan L +6 more
europepmc +1 more source
From Phosphinimines to Four‐Membered SiCPN Cations: Insights Into N–Si Bonding and Ring Strain
European Journal of Inorganic Chemistry, Volume 29, Issue 18, 22 June 2026.Sterically tuned N‐silyl phosphinimines enable four‐membered SiCPN cations. Hydride abstraction yields cyclic cations for Me and iPr substituents at silicon, while tBu gives a protonated intermediate. Multinuclear NMR spectroscopy, X‐ray crystallography, thermochemical density functional theory investigations, and natural bond orbital analyses reveal ...
Alexander Falk, Jonathan O. Bauer
wiley +1 more source
Synthesis of Bicyclo[1.1.1]Pentane Z-Substituted Enamides, Enol Ethers, and Vinyl Sulfides Using Iodine (III) Reagents. [PDF]
Angew Chem Int Ed EnglLee N, Dechent J, Grinhagena E, Waser J.
europepmc +1 more source
Tracking the Reaction of Organoazides with Linear Chromium Silylamides
European Journal of Inorganic Chemistry, Volume 29, Issue 18, 22 June 2026.The multifaceted outcome of the interaction of linear chromium silylamides with organoazides is presented. It leads to terminal and bridging imido complexes, as well as azide adducts. With acylazide, a terminal chromium oxide is obtained. The reaction of organoazides with a linear chromium(I) silylamide leads to the observation of rare monomeric and ...
Andres Gonzalez +5 more
wiley +1 more source
Nucleophilic Substitution of 1,3-Diiodobicyclo[1.1.1]pentane: Synthesis of Bicyclo[1.1.1]pentylpyridinium, Quinolinium, Isoquinolinium, and Pyrazolium Salts. [PDF]
J Org ChemMonroe HJC +6 more
europepmc +1 more source
A Crystalline Ylide‐Stabilized Stibenium Cation
European Journal of Inorganic Chemistry, Volume 29, Issue 17, 17 June 2026.The isolation of a stibenium cation stabilized by two thiophosphinoyl‐tethered ylide groups is reported. The cation is accessible via salt metathesis of the metalated ylide with SbCl3 and features CSb single bonds, with lone pairs remaining localized at the ylidic carbon atoms.
Daniel Knyszek +4 more
wiley +1 more source