Results 61 to 70 of about 20,876 (282)

Sequential Homo‐ and Hetero‐Coupling of Isocyanide and Carbon Monoxide Mediated by Acyclic Imino(silyl)Silylene

Angewandte Chemie, EarlyView.
We demonstrate the sequential reactions between an imino(hypersilyl)silylene and aryl isocyanide or carbon monoxide as a molecular‐level model of the Fischer–Tropsch process, providing systematic and detailed insight into C–C bond formation during the homologation of C1 building blocks.
Huaiyuan Zhu, Arseni Kostenko, Xufang Liu, Shigeyoshi Inoue   +3 more
wiley   +2 more sources

Synthesis of All‐Carbon Disubstituted Bicyclo[1.1.1]pentanes by Iron‐Catalyzed Kumada Cross‐Coupling

Angewandte Chemie, 2020
1,3‐Disubstituted bicyclo[1.1.1]pentanes (BCPs) are important motifs in drug design as surrogates for p‐substituted arenes and alkynes. Access to all‐carbon disubstituted BCPs via cross‐coupling has to date been limited to use of the BCP as the ...
Jeremy Nugent, Bethany R. Shire, D. Caputo, Helena D. Pickford, Frank Nightingale, Ian T. T. Houlsby, J. Mousseau, E. Anderson   +7 more
semanticscholar   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

Advanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard, Thulasinath Raman Venkatesan, Michael Bauer, Valentin Razvan Lupu, Philipp Scheidegger, Francesco Taddei, Frank A. Nüesch, Dorina M. Opris   +7 more
wiley   +1 more source

Machine Learning for Green Solvents: Assessment, Selection and Substitution

Advanced Science, EarlyView.
Environmental regulations have intensified demand for green solvents, but discovery is limited by Solvent Selection Guides (SSGs) that quantify solvent sustainability. Training a machine learning model on GlaxoSmithKline SSG, a database of sustainability metrics for 10,189 solvents, GreenSolventDB is developed. Integrated with Hansen solubility metrics,
Rohan Datta, Janhavi Nistane, Abhishek Sose, Harikrishna Sahu, Rampi Ramprasad   +4 more
wiley   +1 more source

An exergy-based analysis for the synthesis of aromatics from biomass

Next Sustainability
The chemical process industry has been facing rising energy costs, increasing competition due to rapid globalization, and more stringent government regulations amid growing public concern for the environment, health, and safety.
Mohammed Usman, Joseph Akintola, Gabriel Umoh, Joseph Akpan, Ekpotu Wilson, Queen Moses, Philemon Udom, Edose Osagie   +7 more
doaj   +1 more source

Engineering New‐to‐Nature Biological Pathways for β,γ‐Alkanediol Synthesis

Advanced Science, EarlyView.
β,γ‐Alkanediols are value‐added chemicals to be used as functional solvents, biofuels, and cosmetic components. This work demonstrates a carboligation‐mediated approach for synthesis of linear chain β,γ‐alkanediols in Escherichia coli, namely, hexane‐2,3‐diol (2,3‐HDO) and pentane‐2,3‐diol (2,3‐PDO). The engineered E. coli cells produce 152.2 mm (17.98
Haofeng Chen, Haidong Yu, Dongjiang Lin, Guojun Yang, Yuchen Xie, Yang Zhang, Jifeng Yuan   +6 more
wiley   +1 more source

C−F bond activation enables synthesis of aryl difluoromethyl bicyclopentanes as benzophenone-type bioisosteres

Nature Communications
Bioisosteric design has become an essential approach in the development of drug molecules. Recent advancements in synthetic methodologies have enabled the rapid adoption of this strategy into drug discovery programs.
Mingshuo Chen, Yuang Cui, Xiaoping Chen, Rui Shang, Xiaheng Zhang   +4 more
doaj   +1 more source

The Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP): Overview and description of models, simulations and climate diagnostics [PDF]

, 2013
The Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) consists of a series of time slice experiments targeting the long-term changes in atmospheric composition between 1850 and 2100, with the goal of documenting composition changes
Bergmann, D., Cameron-Smith, Philip, Cionni, I, Collins, William J., Dalsoren, Stig B, Doherty, R. M., Eyring, V., Faluvegi, G., Folberth, G., Ghan, S, Horowitz, L. W., Josse, B, Lamarque, J. F., Lee, Y, MacKenzie, Ian A., Nagashima, T, Naik, Vaishali, Plummer, David A, Righi, M, Rumbold, S, Schulz, Michael, Shindell, Drew T., Skeie, R, Stevenson, D. S., Strode, Sarah, Sudo, K., Szopa, Sophie, Voulgarakis, A., Young, Paul, Zeng, Guang   +29 more
core   +4 more sources

Controlled Optically Active Hierarchical Nanostructures of Side‐Chain Sequence‐Regulated Graphene Nanoribbons

Advanced Science, EarlyView.
The restrained side‐chain accessibility and versatility of GNRs extremely impede their multifunctionality, solution processability, and numerous solution‐based applications. We report herein a robust liquid‐phase bottom‐up synthesis approach for high‐efficiency preparation of side‐chain sequence‐regulated functional GNRs.
Baiyang Chen, Kaiyuan Song, Li Yu, Lujia You, Yiming Wang, Zhaoguo Zhang, Yongfeng Zhou, Xinyuan Zhu, Ruijiao Dong   +8 more
wiley   +1 more source

Endangered Hydrocarbons by Lesley Battler [PDF]

, 2016
A review of Lesley Battler\u27s Endangered ...
Sloane, Michael D
core   +1 more source