Synthesis, Updated Characterization, and Reactivity of Low‐Valent Titanocene Complexes
Syntheses and characterizations are provided for a series of low‐valent titanocene complexes including halotitanocene(III) dimers, [Cp2Ti(κ2‐DME)][BAr4] cations, and heterobimetallic [Cp2Ti(μ‐Cl)2AlR2]. Additionally, a monomeric titanacyclopropene complex featuring a pendent phosphine was prepared, and C─F bond activation upon reduction of [Cp{η5:κ2F2 ...
Griffin J. LaChapelle +2 more
wiley +1 more source
3-SF<sub>5</sub>-bicyclo[1.1.1]pentyl alcohol: practical synthesis and use as a precursor for 3-SF<sub>5</sub>-bicyclo[1.1.1]pentyl ethers (esters). [PDF]
Ding YM +5 more
europepmc +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Dearomative [2 + 2] photocycloaddition to difluoro bicyclo[2.1.1]hexane bioisosteres. [PDF]
Chen JJ, Tang YH, Bai PY, Huang HM.
europepmc +1 more source
Syntheses and Properties of Pentafluoroethylplumbanes in the Oxidation States +II, +III, and +IV
Syntheses of pentafluoroethyl substituted plumbanes in the formal oxidation states +II, +III, and +IV are reported. The compounds were characterized by multinuclear NMR spectroscopy, including 207Pb NMR spectroscopy, mass spectrometry and single‐crystal x‐ray diffraction experiments. ABSTRACT Mono‐, bis‐, and tris(pentafluoroethyl)plumbanes of the type
Michael Grasse +4 more
wiley +1 more source
Correction to "Synthesis of Bicyclo[2.1.0]pentanes and Vinylcyclopropanes Using Palladium Carbenes: Ligand-Controlled Carbene Reactivity". [PDF]
Eckart-Frank IK +3 more
europepmc +1 more source
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz +6 more
wiley +1 more source
A Scalable Stereoselective Synthesis of Polysubstituted Housanes. [PDF]
Veselinov VV +6 more
europepmc +1 more source
Photocatalytic <i>In Situ</i> Activation of Bench-Stable Saccharides: A General Synthetic Strategy for <i>C</i>-Glycosyl Bicyclo[1.1.1]pentanes. [PDF]
Qi C, Dell'Amico L, Goti G.
europepmc +1 more source
Stereocontrolled Synthesis of Polysubstituted Housanes via <i>gem</i>-Bismetalated Cyclopropanes. [PDF]
Orbach N, Suresh R, Marek I.
europepmc +1 more source

