The Asymmetric Self‐Replicative Alkylation of N‐Arylaldimines Using Organolithium Reagents
Chemistry – A European Journal, EarlyView.Here, we report a new asymmetric autoinductive reaction; the addition of nBuLi to N‐arylaldimines to form chiral lithium amides. The reaction proceeds with full conversion and complete transfer of chirality, representing the first example of an asymmetric autoinductive reaction with organolithium reagents.
Anka Hagelschuer +2 more
wiley +1 more source
Chemistry – A European Journal, EarlyView.Open halogen‐bonded networks have been prepared from building blocks that incorporate both iodoalkyne halogen bond donors and a pyridine‐N‐oxide halogen bond acceptor. An initially‐formed 3D network containing dioxane in its channels undergoes an unprecedented transition to a 2D material when crystals are exposed to diethyl ether.
Jordan N. Smith +4 more
wiley +1 more source
Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Chemistry – A European Journal, EarlyView.Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Joint modeling of teleseismic and tsunami wave observations to constrain the 16 September 2015 Illapel, Chile, M_w 8.3 earthquake rupture process [PDF]
, 2016 The 16 September 2015 Illapel, Chile, M_w 8.3 earthquake ruptured ~170 km along the plate boundary megathrust fault from 30.0°S to 31.6°S. A patch of offshore slip of up to 10 m extended to near the trench, and a patch of ~3 m slip occurred downdip below
Cheung, Kwok Fai +3 more
core
High‐Temperature Heat Pump Test Bench with n‐Butane (R‐600) Generating Steam
Chemie Ingenieur Technik, EarlyView.This work involves building a test bench for a high‐temperature heat pump (HTHP) and analyzing the measurements. The focus is on steam generation using an HTHP to decarbonize process steam demand. The findings indicate that stable steam generation is possible, providing a higher heat transfer coefficient in the heat pump's condenser.
Sebastian Benkert +7 more
wiley +1 more source
The Filament Extension Atomization Process for Powder Production of Elastic Fluids
Chemie Ingenieur Technik, EarlyView.Filament extension atomization is a promising technique for spraying a wide range of materials, enabling narrow droplet size distributions. This study examines the behavior of various fluids and suspensions to define application limits and identify optimal operating conditions.
Moritz Neukötter +4 more
wiley +1 more source
Liquid phase products and solid deposit formation from thermally stressed model jet fuels [PDF]
The relationship between solid deposit formation and liquid degradation product concentration was studied for the high temperature (400 C) stressing of three hydrocarbon model fuels.
Bittker, D. A., Kim, W. S.
core +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Synthetic jet fuel containing non‐petroleum‐derived kerosene can be produced from synthetic kerosene obtained through processes that include a hydroprocessing step. The potential use of non‐sulphided (reduced) nickel supported on alumina (Ni/Al2O3) was evaluated as an alternative to sulphided catalysts to saturate alkenes in sulphur‐free ...
Garima Chauhan +3 more
wiley +1 more source
Geophysical Monograph Series, Page 329-339., 2020 This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.
Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Vladimir Kutcherov +3 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Abstract Acid catalyzed conversion of durene by isomerization, disproportionation, and transalkylation is of interest to the development of a methanol‐to‐jet process to reduce the amount of durene in the kerosene. It was of interest to determine whether durene conversion could be performed at a temperature lower than 350°C.
Aida G. Velasco Ortiz +2 more
wiley +1 more source