Results 81 to 90 of about 896 (204)

Synthesis and Characterization of Novel Silylated Sm3+ and Eu3+ Complexes Incorporated Into Mesoporous Silica Nanoparticles

European Journal of Inorganic Chemistry, EarlyView.
The strategy of incorporating the Eu(tta‐Si)3(phen) and Sm(tta‐Si)3(phen)2 complexes prevented leaching of the complexes and preserved their intrinsic optical properties. Preliminary studies of silylated Ln3+ complexes and nanoparticles loaded with these complexes demonstrated cytotoxicity against cancer cells, with minimal cytotoxic effect on nontumor
Juliana Jorge, Jaqueline Rodrigues da Silva, Diego Boldo, Kristiane Fanti Del Pino Santos, Luana da Silva Oliveira, Adriana Pereira Duarte, Gustavo Rocha de Castro, Ariadna Lafourcade Prada, Jesús Rafael Rodríguez Amado, Marc Verelst, Vasilii Khripun, Marco Antonio Utrera Martines   +11 more
wiley   +1 more source

Correction to "Synthesis of Bicyclo[2.1.0]pentanes and Vinylcyclopropanes Using Palladium Carbenes: Ligand-Controlled Carbene Reactivity". [PDF]

J Am Chem Soc
Eckart-Frank IK, Arnold ES, Murphy LP, Wilkerson-Hill SM.   +3 more
europepmc   +1 more source

Artificial [FeFe]‐Hydrogenase Mimics From Ferrocenyl Thioketone‐Functionalized Triphenylamine and (Bi)thiophene Derivatives: Synthesis, Characterization, and Hydrogen Evolution Catalysis

European Journal of Inorganic Chemistry, EarlyView.
Synthesis of ferrocenyl thioketone‐functionalized triphenylamine and triphenylamine‐(bi)thiophene derivatives as proligands for the assembly of artificial [FeFe]‐hydrogenase active site models. Thiocarbonyl compounds, especially thioketones, have emerged as promising precursors for constructing [FeFe]‐hydrogenase mimics that can mediate hydrogen ...
Hassan Abul‐Futouh, Ibrahim Basma, Sara J. Abaalkhail, Ahmad Q. Daraosheh, Phil Köhler, Wolfgang Weigand   +5 more
wiley   +1 more source

Photocatalytic <i>In Situ</i> Activation of Bench-Stable Saccharides: A General Synthetic Strategy for <i>C</i>-Glycosyl Bicyclo[1.1.1]pentanes. [PDF]

Org Lett
Qi C, Dell'Amico L, Goti G.
europepmc   +1 more source

Main Group Metals in Redox Catalysis

European Journal of Inorganic Chemistry, EarlyView.
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki, Alba Martinez‐Bascuñana, Oriol Planas   +2 more
wiley   +1 more source

Stereocontrolled Synthesis of Polysubstituted Housanes via <i>gem</i>-Bismetalated Cyclopropanes. [PDF]

J Am Chem Soc
Orbach N, Suresh R, Marek I.
europepmc   +1 more source

Mixing Behavior of Natural Gas and Hydrogen in a High‐Efficiency Vane (HEV) Static Mixer

Energy Science &Engineering, EarlyView.
Static mixers play a crucial role in the safe transport of hydrogen‐blended natural gas. Computational fluid dynamics (CFD) was employed to investigate the effects of structural parameters of the HEV static mixer on the mixing behavior and homogeneity of natural gas and hydrogen. The modeling approach was well validated against experimental data.
Xiang Zhou, Jun Zheng, Weiqing Xu, Dewen Kong, Yan Shi, Maolin Cai   +5 more
wiley   +1 more source

Dibromocarbene addition to bicyclo[1.1.0]butanes: A facile route to substituted bicyclo[1.1.1]pentanes. [PDF]

Proc Natl Acad Sci U S A
Attard FC, Slobodianyk A, Bychek R, Panasiuk Y, Neigenfind P, Massaro L, Gardiner MG, Levterov VV, Baran PS, Mykhailiuk PK, Malins LR.   +10 more
europepmc   +1 more source

The Binding of Pentadiyl‐α,ω‐Bis(Dimethyldodecylammonium), a Cationic Gemini 12‐5‐12 Surfactant to Conjugated Carboxylates as Organic Counterions

Journal of Surfactants and Detergents, EarlyView.
ABSTRACT The critical micelle concentration (CMC) values of the cationic gemini surfactant pentadiyl‐α,ω‐bis(dimethyldodecylammonium) bromide depend on the hydrophobicity of added conjugated organic carboxylate anions. Nine conjugated counterions, present as sodium salts of organic acids, were studied to expand the correlation to the counterion ...
Alexia Rios, Jaslyn Salazar, Valentina Kornach, Mark D. Lingwood, Steven J. Bachofer   +4 more
wiley   +1 more source

Direct Synthesis of Bicyclo[1.1.1]pentanes by Sequential C═C, C-C Functionalization Reactions. [PDF]

J Am Chem Soc
Sailer JK, Ly D, Musaev DG, Davies HML.
europepmc   +1 more source