Results 111 to 120 of about 34,037 (255)

Next Generation Hosts for Protein Recognition, Assembly and More

Chemistry – A European Journal, EarlyView.
The original design of synthetic receptors for proteins was based on macrocycles with a hydrophobic core and a polar/charged periphery. This design, geared towards protein recognition, facilitates receptor self‐assembly. Macrocycle oligomerization, in turn, contributes to protein assembly as evidenced in many cocrystal structures.
Peter B. Crowley
wiley   +1 more source

Efficient calculation of van der Waals dispersion coefficients with time-dependent density functional theory in real time: application to polycyclic aromatic hydrocarbons

, 2007
The van der Waals dispersion coefficients of a set of polycyclic aromatic hydrocarbons, ranging in size from the single-cycle benzene to circumovalene (C66H20), are calculated with a real-time propagation approach to time-dependent density functional ...
Alberto Castro, Flower D. R., Giacomo Mulas, Giuliano Malloci, London F., Mahanty J., Miguel A. L. Marques, Parsegian V. A., Siegel G. J., Silvana Botti   +9 more
core   +3 more sources

Twisted 1‐ and 2‐Azaperopyrenes: Synthesis, Structure, and Properties

Chemistry – A European Journal, EarlyView.
ABSTRACT A synthesis of hitherto unknown 1‐ and 2‐azaperopyrenes, twisted nitrogen‐doped peropyrenes, is reported. The synthesis is based on a Brønsted acid‐mediated benzannulation of alkynes. Key alkyne intermediates are synthesized via two complementary routes, including a Pd/C‐catalyzed, copper‐ and amine‐free Sonogashira‐type coupling of (hetero ...
Ricardo Molenda, Arpine Vardanyan, Alexander Villinger, Peter Ehlers, Peter Langer   +4 more
wiley   +1 more source

Bottlenecks‐Breaking in Zinc‐Iodine Batteries Toward Practical Implementation: A Review and Perspective

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Aqueous zinc–iodine batteries (Zn–I2Bs) offer promise for grid storage due to safety and cost advantages yet face critical bottlenecks: severe self‐discharge (polyiodide shuttling and HER), limited energy density, sluggish kinetics, and zinc anode instability.
Jia‐Lin Yang, Jun‐Ming Cao, Dai‐Huo Liu, Xing‐Long Wu   +3 more
wiley   +1 more source

Enhanced Thermal Durability and Efficiency of Organic Solar Cells via Selective Organic Electron Transport Layers

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
PDINN‐based organic solar cells exhibit strong thermal durability, maintaining high efficiency at 110°C, whereas PFN‐Br devices degrade rapidly. PDINN's stable interfacial interactions enhance charge transport and suppress recombination, emphasizing the key role of interfacial engineering in achieving thermally durable, high‐performance OSCs.
Hye Seon Shin, Dong Hwan Yun, Youngchae Cho, Mihyun Kim, Harin Kim, Seungmin Baek, Seyeong Song, Gi‐Hwan Kim   +7 more
wiley   +1 more source

Enhancing Stability in Next‐Generation Photoelectrodes Such as Organic Semiconductor and Halide Perovskite‐Based Photoelectrodes for Various Applications: Recent Advanced Passivation and Encapsulation Methods

Exploration, EarlyView.
This review explores advancements in passivation and encapsulation methods to enhance the stability of organic semiconductor and halide perovskite‐based photoelectrodes in photoelectrochemical systems. It highlights the potential of these materials for efficient solar energy conversion and environmental applications while emphasizing the need for ...
Yejoon Kim, Enok Lee, Sanghan Lee
wiley   +1 more source

The Rhodamine–Perylene Compact Electron Donor–Acceptor Dyad: Spin-Orbit Charge-Transfer Intersystem Crossing and the Energy Balance of the Triplet Excited States

Photochem
We prepared a rhodamine (RB)–perylene (Pery) compact electron donor/acceptor dyad (RB–Pery) to study the spin-orbit charge-transfer intersystem crossing (SOCT–ISC).
Muhammad Imran, Dongyi Liu, Kaiyue Ye, Xue Zhang, Jianzhang Zhao   +4 more
doaj   +1 more source

Fully crystalline perovskite-perylene hybrid photovoltaic cell capable of 1.2 V output with a minimized voltage loss

APL Materials, 2014
A fully crystalline heterojunction of organo-metal-halide perovskite, CH3NH3PbI3−xClx (X < 0.24), and perylene constitutes a planar photovoltaic cell that yields a photovoltage exceeding 1.2 V with a single junction cell absorbing up to 800 nm.
Ayumi Ishii, Ajay Kumar Jena, Tsutomu Miyasaka   +2 more
doaj   +1 more source

Recent Advances in Conjugated Microporous Polymers for Photocatalysis: Mechanism, Synthesis and Applications

Exploration, EarlyView.
Conjugated microporous polymers (CMPs) have attracted more and more attention as new photocatalysts due to their unique advantages such as high performance, long stability and strong light absorption. This review summarizes the application of CMPs as a photocatalyst in recent years and introduces the catalytic mechanism.
Dun Zhou, Kongqing Zhang, Xiaobai Li, Yongpeng Liu, Liang Yao, Hongwei Ma   +5 more
wiley   +1 more source

Detection of Radical Anions by Electrospray‐Ionization Mass Spectrometry

Helvetica Chimica Acta, EarlyView.
The present study investigates the ability of electrospray‐ionization mass spectrometry to detect radical anions. For neutral analytes with high electron affinities, radical anions are formed by cathodic reduction and can be easily observed. In contrast, analytes with lower electron affinities require the addition of a reducing agent for the generation
Niklas F. Eisele, Daniel Kösters, Konrad Koszinowski   +2 more
wiley   +1 more source