Results 61 to 70 of about 7,847 (233)

Structure-dependent optoelectronic properties of perylene, di-indenoperylene (DIP) isolated molecule and DIP molecular crystal

open access: yesChemistry Central Journal, 2017
Theoretical simulations were designed by first principles approach of density functional theory to investigate the structural and optoelectronic properties of different structural classes of perylene; isolated perylene, diindeno[1,2,3-cd:1′,2′,3′-lm ...
Mazmira Mohamad   +3 more
doaj   +1 more source

A Fluorine‐Free, Low Ion Pair Electrolyte for Transition Metal‐Free and Halogen‐Free Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Fluorine‐containing electrolytes dominate modern rechargeable batteries, yet the fundamental design principles for fluorine‐free systems remain largely unexplored. We demonstrate that fluorine‐free electrolyte chemistry can simultaneously achieve long cycle life, fast charging, and stable interphase formation in sodium‐ion batteries.
Dawei Xia   +7 more
wiley   +1 more source

Modified Titanium Dental Implants: The Current Progress of Soft‐Tissue Integration Methods

open access: yesAdvanced NanoBiomed Research, EarlyView.
Dental implants are an established solution for tooth loss, yet achieving soft tissue integration (STI) around the transmucosal region remains a challenge. The natural tooth–gingiva interface is poorly replicated on titanium implants. This review explores surface modification strategies, ranging from surface chemistry and topography to biological ...
Daniel De Maria   +5 more
wiley   +1 more source

Molecular Organization Induced Anisotropic Properties of Perylene – Silica Hybrid Nanoparticles

open access: yesScientific Reports, 2017
Optically active silica nanoparticles are interesting owing to high stability and easy accessibility. Unlike previous reports on dye loaded silica particles, here we address an important question on how optical properties are dependent on the aggregation-
Deepa Sriramulu   +3 more
doaj   +1 more source

A study of the elemental reactions involved in the initiation of the polymerization of tetrahydrofuran induced by the photosensitization of a triphenylsulphonium salt by perylene

open access: yesJournal of the Brazilian Chemical Society, 2003
The photopolymerization of THF was studied in the presence of a triphenylsulphonium salt and perylene. The mechanism involves an electron transfer from the excited singlet state of perylene to triphenylsulphonium ions, resulting in perylene cation ...
Neumann Miguel G., Rodrigues Maira R.
doaj  

Cycloazulenylen

open access: yesAngewandte Chemie, EarlyView.
Ein ausschließlich aus Azulen‐Untereinheiten aufgebauter gespannter Makrocyclus mit der Bezeichnung [6]Cycloparaazulenylen ([6]CPA) wird vorgestellt. Der Makrocyclus weist für ein Azulensystem eine bemerkenswert kleine HOMO–LUMO‐Energielücke, eine durch die Ringspannung hervorgerufene bathochrome Verschiebung der Absorption sowie ein ungewöhnliches ...
Clara Douglas   +8 more
wiley   +1 more source

(Perylene)3-(TCNQF1)2: Yet Another Member in the Series of Perylene–TCNQFx Polymorphic Charge Transfer Crystals

open access: yesCrystals, 2020
The 3:2 Charge Transfer (CT) co-crystal (Perylene)3(TCNQF1)2 is grown by the Physical Vapor Transport (PVT) method, and characterized structurally and spectroscopically.
Tommaso Salzillo   +7 more
doaj   +1 more source

Cycloazulenylene

open access: yesAngewandte Chemie International Edition, EarlyView.
A strained macrocycle consisting solely of azulene subunits, named [6]cycloparaazulenylene ([6]CPA), is presented. The macrocycle exhibits a notably narrow HOMO–LUMO gap for a pristine azulene species, strain‐induced red‐shifted absorption, and an unusual tubular packing motif elucidated via single‐crystal XRD.
Clara Douglas   +8 more
wiley   +1 more source

Liquid Crystalline Perylene Bisimide Derivatives Bearing Oligosiloxane Moieties

open access: yesChemistry
Perylene bisimide derivatives are typical n-type semiconductors as well as redox-active materials. However, it has been difficult to produce thin films by solution processes because of their low solubilities in organic solvents.
Masahiro Funahashi, Shinobu Uemura
doaj   +1 more source

A simple protocol for the synthesis of perylene bisimides from perylene tetracarboxylic dianhydride

open access: yesRSC Advances
PBIs were synthesized from the reaction of perylene bisanhydrides and primary amines in imidazole as solvent. Maleimide, anthraquinone or ferrocene were bonded to the side chain and the S-trityl group was replaced by imidazole in S-trityl cysteine.
Elina Marinho   +3 more
openaire   +3 more sources

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