Results 71 to 80 of about 7,847 (233)

Isodesmic Supramolecular Assembly of Phenylethynylene Bis‐Urea Macrocycles

Chemistry – A European Journal, EarlyView.
A soluble phenylethynylene bis‐urea macrocycle assembles in polar media via an isodesmic hydrogen bonded mechanism. Spectroscopic and morphological studies reveal nanoscale aggregates with short chain length, while guest additives modulate enthalpy and polymerization, demonstrating tunable supramolecular assembly.
Fahidat A. Gbadamosi, Kazi Md Zubaer, Vaibhavi A. Samant, Jillian Eubanks, Sophya Garashchuk, Linda S. Shimizu   +5 more
wiley   +1 more source

Enhancing light energy harvesting and storage properties of cellulose acetate/azobenzene films through perylene photosensitization

Carbohydrate Polymer Technologies and Applications
This study presents a straightforward approach to enhancing the light energy capture and storage properties of cellulose acetate/azobenzene (CA/Azb) films through photosensitization with a perylene derivative (Py). The films' photoisomerization (trans-to-
Pablo Castillo, Felipe Ramos, Constanza Kremer, Oscar Ramírez, Sebastian Bonardd, David Diaz Diaz, Angel Leiva, Cesar Saldias   +7 more
doaj   +1 more source

Mechanistic Insights Into Sustainable Catalytic Pyrolysis of Biomass‐Derived Ferulic Acid: The Role of Alumina Regeneration

Chemistry – A European Journal, EarlyView.
Surface‐bound ferulate phenolate complexes undergo styrene‐like polymerization on alumina, yielding a polymeric carbonaceous layer that progressively transforms into polyaromatic carbon domains with concomitant release of aromatic products, while parallel surface‐assisted decarboxylation produces 4‐vinylguaiacol. ABSTRACT A fundamental understanding of
Tetiana V. Kulik, Borys B. Palianytsia, Mykola M. Ilchenko, Nataliia S. Nastasiienko, David J. Morgan, Liudmila P. Storozhuk, David J. Willock, Greg Shaw, Duncan F. Wass, Rafael Luque, Philip R. Davies, Mykola T. Kartel   +11 more
wiley   +1 more source

Azuperylene: The Nonalternant Isomer of Perylene

Angewandte Chemie International Edition
Abstract The isoelectronic isomer of perylene, hereafter called as azuperylene, has been prepared. Electronic structure analysis reveals that the new isomer can be described as a union of two antiparallel azulenes in which the azulene‐type aromatic character of the starting azulene is partially retained.
Liu, Shengpei, Díaz-Fernández, Marcos, Zhang, Menglin, Huang, Fei, Chen, Yong, Yang, Yudong, Marín-Beloqui, José Manuel, Lan, Jingbo, You, Jingsong, Casado-Cordón, Juan, Zhang, Cheng   +10 more
openaire   +3 more sources

Cyclization of a 1,8‐Diphenylanthracene by Scholl Reactions to Form Five‐ and Seven‐Membered Ring Embedded Polycyclic Aromatic Hydrocarbons

Chemistry – A European Journal, EarlyView.
Reactions of 10‐mesityl‐1,8‐diphenylanthracene with DDQ/TfOH produced three products via sequential formation of a five‐ or seven‐membered ring. Unexpectedly, the triply cyclized product with a rubicene substructure was formed through cyclization involving 1,2‐methyl shift.
Tatsuhiro Sasaki, Eiji Tsurumaki, Shinji Toyota   +2 more
wiley   +1 more source

Proximal Steric Shielding Unlocks High Solid‐State Luminescence in Quinoxaline‐Fused Pyrene Heteroacenes

Chemistry – A European Journal, EarlyView.
Proximal steric tuning of quinoxaline‐fused pyrene heteroacenes enables soluble derivatives that exhibit solid‐state photoluminescence quantum yields (PLQYs) up to 82%, surpassing previous benchmarks. This work reveals key structure–property relationships for next‐generation, processable organic emitters in advanced optoelectronic applications ...
Rafiq Ahamed, Sonal Patil, Madhusudan Dutta, Godi Kiran Venkata Sai, Sergey Fisher, Anil Bhadke, Rama Krishna Gamidi, Susnata Pramanik, Tomáš Šolomek, Sudhakar Gaikwad   +9 more
wiley   +1 more source

Influences of Linker and Nucleoside for the Helical Self-Assembly of Perylene Along DNA Templates

Frontiers in Chemistry, 2019
Six different conjugates of perylene with 2′-deoxyuridine and with 2-amino-2′-deoxyadenosine were synthesized and applied for DNA-templated assembly in aqueous buffer solutions.
Yannic Fritz, Hans-Achim Wagenknecht
doaj   +1 more source

Co‐Catalyst/Semiconductor Interface Coupling Design for Efficient Solar‐Driven Photocatalysis

EcoEnergy, EarlyView.
Interfacial coupling strength is proposed as a unifying descriptor governing charge‐transfer behavior in co‐catalyst/semiconductor photocatalytic systems. This review establishes a coupling‐strength‐guided framework that correlates interface engineering strategies with charge transport pathways, electronic structure regulation, and photocatalytic ...
Fangxu Dai, Zhiyu Song, Meiyan Qiu, Zhen Zhang, Dan Zhang, Xiaobo Chen, Yun Hau Ng, Xin Li   +7 more
wiley   +1 more source

Carbon Anodes for Low‐Temperature Nonaqueous Alkali Metal‐Ion Batteries

EcoEnergy, EarlyView.
This review summarizes recent progress in carbon anodes for low‐temperature nonaqueous alkali‐metal ion batteries. Fundamental thermodynamic and kinetic limitations are examined, alongside a systematic discussion of graphite, hard carbon, and emerging carbon architectures.
Zhichun Miao, Dandan Yu, Guojie Liu, Yuyang Qin, Jingyun Mou, Wenlong Song, Lu Shi, Zengqin Xiao, Xin Yuan, Huayu Chen, Laishun Qin, Da Chen   +11 more
wiley   +1 more source

Low‐Dimensional Materials and Van Der Waals Heterostructures for Energy Application: A Comprehensive Review

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Low‐dimensional materials (0D, 1D, and 2D) exhibit unique electronic and physicochemical properties, enabling advanced nanoelectronic and optoelectronic devices. Mixed‐dimensional heterostructures combine these materials to enhance functionality.
Qaisar Alam, Sajjad Ali, Pir Muhammad Ismail, ABM Sharif Hossain   +3 more
wiley   +1 more source