Oxygen-doped carbon-supported palladium nanoparticles boost the tandem hydrogenation-acetalization-hydrogenolysis of phenols and diphenyl ethers to cyclohexyl ethers. [PDF]
Nat CommunJiang L +9 more
europepmc +1 more source
Latex Serum‐Derived Supramolecular Networks Enable Toughening of Natural Rubber
Macromolecular Rapid Communications, EarlyView.Latex‐serum addition enhances strain‐induced crystallization (SIC) toughening in natural rubber, increasing tearing strength and extending the SIC activation window. Supramolecular networks form via bifurcated hydrogen bonding between polyol components (e.g., quebrachitol) and end‐functionalized polyisoprene chains, serving as effective crystallization
Katsuhiko Tsunoda +5 more
wiley +1 more source
Synthesis of Bicyclo[1.1.1]Pentane Z-Substituted Enamides, Enol Ethers, and Vinyl Sulfides Using Iodine (III) Reagents. [PDF]
Angew Chem Int Ed EnglLee N, Dechent J, Grinhagena E, Waser J.
europepmc +1 more source
Macromolecular Rapid Communications, EarlyView.Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj +4 more
wiley +1 more source
Macromolecular Rapid Communications, EarlyView.Arsonic acid containing diblock copolymers are developed to incorporate arsonic acid moieties for surface anchoring to IONPs, along with water soluble PEG blocks to impart colloidal stability in aqueous environments. The resulting polymer‐coated IONPs are evaluated for stability in physiological media and cytocompatibility.
Nhu Thao Huynh +10 more
wiley +1 more source
Advanced Catalysts for Olefin Synthesis: Copper(II) Quinoline-Fused Oxazolidines in Alcohol Dehydration. [PDF]
J Org ChemPanda A +3 more
europepmc +1 more source
A Non‐Antigenic Randomized Polyethylene Glycol/Poly(2‐Phenyl‐2‐Oxazine)‐Based Drug Delivery Platform
Macromolecular Rapid Communications, EarlyView.Randomized PEG (rPEG), a conceptually new PEG alternative, is combined with poly(2‐phenyl‐2‐oxazine) (PPheOzi) to establish an rPEG‐b‐PPheOzi‐b‐rPEG micellar drug delivery platform. The PPheOzi block enables high drug loadings, while competitive ELISA reveals a drastic reduction in anti‐PEG antibody affinity of rPEG in comparison to PEG.
Julian Schmidt +6 more
wiley +1 more source
Photosensitized diradical rearrangement of alkenyl oxime ethers towards amino-featured oxiranes: reaction, mechanism, and structural prediction. [PDF]
Chem SciLiu TM +6 more
europepmc +1 more source
Macromolecular Rapid Communications, EarlyView.Micellar systems based on biodegradable aliphatic polycarbonates and acid‐responsive triggers enhance drug solubility, stability, and tumor‐selective release. This review covers micelles with acid‐cleavable drug linkages and those that disassemble via acid‐sensitive functionalities.
Adrian V. Hauck, Lutz Nuhn
wiley +1 more source
3,3'-Linked BINOL macrocycles: optimized synthesis of crown ethers featuring one or two BINOL units. [PDF]
Beilstein J Org ChemKheirjou S +4 more
europepmc +1 more source