Results 41 to 50 of about 24,479 (307)

Zirconyl (IV) Nitrate as Efficient and Reusable Solid Lewis Acid Catalyst for the Synthesis of Benzimidazole Derivatives

open access: yesJournal of Chemistry, 2013
The present paper introduces a simple and efficient method for the synthesis of substituted benzimidazoles by heterocyclization of different o-phenylenediamines and substituted aromatic carboxylic acid/aldehyde in the presence of zirconyl nitrate as ...
Pratapsinha B. Gorepatil   +2 more
doaj   +1 more source

Simple, mild, and highly efficient synthesis of 2-substituted benzimidazoles and bis-benzimidazoles

open access: yesQuímica Nova, 2014
A new convenient method for preparation of 2-substituted benzimidazoles and bis-benzimidazoles is presented. In this method, o-phenylenediamines were condensed with bisulfite adducts of various aldehydes and di-aldehydes under neat conditions by ...
Bilge Eren, Yunus Bekdemir
doaj   +1 more source

Redox Potential Inversion by Ionic Hydrogen Bonding between Phenylenediamines and Pyridines

open access: yes, 2020
[[abstract]]In electrochemical oxidations, the second oxidation potential of phenylenediamines (PD) varies because of hydrogen-bonding formation for PD(+center dot) with pyridines.
Chiu, KY, 裘坤元 
core   +5 more sources

Base-catalyzed multicomponent access to quinoxalin-2-thiones from o -phenylenediamines, aryl ketones and sulfur

open access: yes, 2022
International audienceQuinoxalin-2-thiones were readily synthesized from o -phenylenediamines, ketones and sulfur. The reactions proceeded under simple and mild conditions with chromatography-free purification and were amenable to large-scale ...
Nguyen, Thanh Binh   +4 more
core   +1 more source

A Fast and Efficient Method for the Synthesis of 1,5-Benzodiazepine Derivatives Under Solvent-Free Conditions [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 2007
Silica sulfuric acid is found to catalyze efficiently the condensation of o-phenylenediamines with various linear and cyclic ketones to afford the corresponding 1,5-benzodiazepines in quantitative yields under solvent-free conditions at room ...
Ahmad Shaabani, Ali Maleki
doaj  

Electrochemical amination of para-chloroaniline

open access: yesУчёные записки Казанского университета: Серия Естественные науки, 2019
The process of cation-radical amination of para-chloroaniline using hydroxylamine and the Ti(IV)/Ti(III) mediator system was studied in aqueous solutions of 9–17 M H2SO4.
Yu.A. Lisitsyn
doaj   +1 more source

Determination of phenylenediamines in hair colors derivatizated with 5-(4, 6-dichlorotriazinyl) aminofluorescein via micellar electrokinetic chromatography

open access: yesJournal of Food and Drug Analysis, 2019
Phenylenediamines (PDs), which are reported to cause allergic dermatitis and possess genotoxicity and carcinogenicity, are the ingredients used in permanent hair dyes.
H. Ko   +3 more
semanticscholar   +1 more source

Synthesis of quinoxalines through iodine-catalyzed one-pot annulation of alkynes with o-phenylenediamines

open access: yes, 2018
The synthesis of N-heterocycles of quinoxalines has been developed by an efficient protocol of one-pot annulation of alkynes with o-phenylenediamines. A variety of quinoxalines were prepared in good to high yields in the presence of catalytic amount of ...
Zhe-Yao Hu (4925218)   +5 more
core   +1 more source

Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries

open access: yesAngewandte Chemie, EarlyView.
A proton‐switchable imine‐linked framework is developed to dynamically regulate interfacial iodine chemistry in aqueous Zn–I2 batteries, where reversible protonation/deprotonation switches the host affinity between iodide and polyiodide species. This state‐dependent regulation suppresses shuttle‐induced side reactions while preserving fast iodine redox
Feifei Wang   +14 more
wiley   +2 more sources

Illegally additives determination by thin layer chromatography

open access: yesMATEC Web of Conferences, 2016
To find out a simple TLC method, which could identify m-phenyenediamine and o-phenylenediamine in several colors of oxidation hair coloring products simultaneously. The colors includes black, yellow, brown and red. A small amount of the sample was placed
Liang Xin   +3 more
doaj   +1 more source

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