Results 61 to 70 of about 2,082 (291)

Bipolar Covalent Organic Frameworks Crafting Core–Shell Heterostructured Cathode for High–Performance Lithium–Organic Batteries

open access: yesAdvanced Science, EarlyView.
A bipolar CNT@COF core–shell heterostructure cathode constructed via synergistic molecular and microstructural engineering enables rapid electron/ion transport and efficient utilization of electroactive groups for high–performance lithium–organic batteries. ABSTRACT Covalent organic frameworks (COFs) with tunable molecular structures and ordered porous
Yalong Jiang   +6 more
wiley   +1 more source

Tailoring Multifunctional Carbon Dots via Precursor Stoichiometry: Switching Between Solid‐State Fluorescence and Broadband Absorption Through Aggregation Control

open access: yesAdvanced Science, EarlyView.
Precursor stoichiometry programs the surface chemistry of carbon dots, directing their self‐assembly into distinct aggregation modes. Aldehyde‐enriched surfaces form ordered, hydrogen‐bonded assemblies that enable bright red solid‐state fluorescence, whereas amine‐rich surfaces promote compact π–π stacked aggregates with broadband visible‐light ...
Gaixia Yang   +8 more
wiley   +1 more source

DBU-Based Ionic-Liquid-Catalyzed Carbonylation of o‑Phenylenediamines with CO2 to 2‑Benzimidazolones under Solvent-Free Conditions

open access: yes, 2016
Herein, a new route was presented to synthesize 2-benzimidazolones via the carbonylation of o-phenylenediamines with CO2 catalyzed by 1,8-diaza­bicyclo­[5.4.0]­undec-7-ene (DBU)-based ionic liquids under solvent-free conditions. DBU acetate ([DBUH]­[OAc])
Jilei Xu (1915465)   +6 more
core   +1 more source

Mechanistic Understanding of Protein–MOF Integration Through Surfactant‐Driven Interfacial Design

open access: yesAdvanced Science, EarlyView.
This study reveals how surfactant‐driven interfacial design governs the assembly and stability of protein@MOF composites. Using lipid‐based nonionic surfactants, we modulate protein–MOF interactions to improve encapsulation efficiency, MOF crystallization, and catalytic performance.
Ehsan Rashidniyaghi   +4 more
wiley   +1 more source

Electrosynthesis of benzimidazole-fused quinazolinones via a cascade addition-desulfurization-cyclization process

open access: yesTetrahedron Green Chem
The electrosynthesis of benzimidazole-fused quinazolinones from N-substituted o-phenylenediamines and isothiocyanates via a cascade addition-desulfurization-cyclization process was introduced. This electrochemical approach utilizes the mild and efficient
Khuyen Thu Nguyen   +2 more
doaj   +1 more source

Nanomaterials for Allergy Diagnosis and Treatment: Advances, Opportunities and Translational Challenges

open access: yesAdvanced Science, EarlyView.
Nanomaterials offer dual applications in allergy management. For diagnosis, nanomaterials enhance analytical sensitivity and improve detection in specific IgE and functional assays such as the basophil activation test (BAT). For allergen‐specific immunotherapy, nanomaterials enable allergen masking and controlled release, and effectively modulate the ...
Madiha Habib   +8 more
wiley   +1 more source

Regioselective Radical Arene Amination for the Concise Synthesis of ortho-Phenylenediamines

open access: yes, 2021
The formation of arene C-N bonds directly from C-H bonds is of great importance and there has been rapid recent de-velopment of methods for achieving this through radical mechanisms, often involving reactive N-centered radicals.

core   +1 more source

A Hydrogen Sulfide–Releasing Dynamic Hydrogel Modulates Coordinated Neurovascular, Immune, and Angiogenic Responses for Scar‐Suppressed Diabetic Wound Repair

open access: yesAdvanced Science, EarlyView.
ROS‐Responsive H2S Hydrogel (HAPPF) Coordinated Regeneration for High‐Quality Diabetic Wound Repair.A self‐regulating dynamic hydrogel is developed to deliver a fluorogenic H2S donor in response to excessive ROS. Released H2S acts as a master regulator to resolve chronic inflammation (M2 polarization), restore VEGF‐driven angiogenesis, and rebalance ...
Xuyang Ning   +7 more
wiley   +1 more source

Copper-catalyzed aerobic oxidative coupling of o-phenylenediamines with 2-aryl/heteroarylethylamines: direct access to construct quinoxalines

open access: yes, 2017
A versatile method for synthesis of quinoxalines by Cu-catalyzed oxidative coupling of o-phenylenediamines with 2-arylethylamines is presented.
Kovuru Gopalaiah   +5 more
core   +1 more source

Freestanding Bamboo‐Like Nitrogen‐Doped Carbon Nanofibers/PANI Dual‐Conductive Cathodes via Interfacial Engineering for High‐Performance Lithium–Sulfur Batteries

open access: yesAdvanced Science, EarlyView.
Bamboo‐like nitrogen‐doped carbon fibers (BNCFs) were synthesized via a vapor‐liquid‐solid catalytic growth method and further integrated with polyaniline to fabricate a freestanding BNCFs/S/PANI cathode. The PANI coating and BNCFs framework synergistically establish an interconnected conductive network with abundant nitrogen‐active sites, thereby ...
Jie Yang   +5 more
wiley   +1 more source

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