Results 1 to 10 of about 19,048 (288)

Disulfide Competition for Phosphine Gold(I) Thiolates: Phosphine Oxide Formation vs. Thiolate Disulfide Exchange

Inorganics, 2015
Phosphine gold(I) thiolate complexes react with aromatic disulfides via two pathways: either thiolate–disulfide exchange or a pathway that leads to formation of phosphine oxide.
Gamage S. P. Garusinghe, S. Max Bessey, Mostapha Aghamoosa, Meaghan McKinnon, Alice E. Bruce, Mitchell R. M. Bruce   +5 more
doaj   +4 more sources

A visible-light activated secondary phosphine oxide ligand enabling Pd-catalyzed radical cross-couplings [PDF]

Nature Communications, 2022
Ligand design is key for improving the performance in light-enabled catalytic processes. Here, the authors report the synthesis of a visible-light–activated secondary phosphine oxide ligand and apply it to Pd-catalyzed radical cross-coupling reactions.
Takahito Kuribara, Masaya Nakajima, Tetsuhiro Nemoto   +2 more
doaj   +2 more sources

Phosphine Oxide Indenoquinoline Derivatives: Synthesis and Biological Evaluation as Topoisomerase I Inhibitors and Antiproliferative Agents [PDF]

Molecules
The synthesis of phosphorous indenoquinolines and their biological evaluation as topoisomerase 1 (TOP1) inhibitors and antiproliferative agents were performed.
Alba Rodriguez-Paniagua, Cinzia Tesauro, Birgitta R. Knudsen, Maria Fuertes, Concepción Alonso   +4 more
doaj   +2 more sources

5-Cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinane, its phosphine oxide, and its [NiCl2L2] complex [PDF]

Acta Crystallographica Section E: Crystallographic Communications
The crystal structures of 5-cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinane, C21H27N2P, and its oxidized phosphine oxide, 5-cyclohexyl-1,3-diphenyl-1,3,5-diazaphosphinan-5-one, C21H27N2OP, have primitive monoclinic symmetry (both in space group P21/m) at ...
David Esjornson, Denise Anderson, Jessica Vo, Jeanette A. Krause, Timothy J. Hubin, Allen G. Oliver   +5 more
doaj   +2 more sources

Controlled CO labilization of tungsten carbonyl precursors for the low-temperature synthesis of tungsten diselenide nanocrystals

Frontiers in Nanotechnology, 2022
We report a low-temperature colloidal synthesis of WSe2 nanocrystals from tungsten hexacarbonyl and diphenyl diselenide in trioctylphosphine oxide (TOPO).
Jessica Q. Geisenhoff, Hang Yin, Natacha Oget, Haeun Chang, Linfeng Chen, Alina M. Schimpf   +5 more
doaj   +1 more source

Ortho-Phosphinoarenesulfonamide-Mediated Staudinger Reduction of Aryl and Alkyl Azides

Molecules, 2022
Conventional Staudinger reductions of organic azides are sluggish with aryl or bulky aliphatic azides. In addition, Staudinger reduction usually requires a large excess of water to promote the decomposition of the aza-ylide intermediate into phosphine ...
Xingzhuo Li, Zhenguo Wang, Wenjun Luo, Zixu Wang, Keshu Yin, Le Li   +5 more
doaj   +1 more source

Phosphineoxide-Chelated Europium(III) Nanoparticles for Ceftriaxone Detection

Nanomaterials, 2023
The present work demonstrates the optimization of the ligand structure in the series of bis(phosphine oxide) and β-ketophosphine oxide representatives for efficient coordination of Tb3+ and Eu3+ ions with the formation of the complexes exhibiting high ...
Rustem Zairov, Alexey Dovzhenko, Natalia Terekhova, Timur Kornev, Ying Zhou, Zeai Huang, Dmitry Tatarinov, Guliya Nizameeva, Robert R. Fayzullin, Aidar T. Gubaidullin, Taliya Salikhova, Francesco Enrichi, Vladimir F. Mironov, Asiya Mustafina   +13 more
doaj   +1 more source

Surface Passivation with Selected Phosphine Oxide Molecules for Efficient Pure‐Blue Mixed‐Halide Perovskite Quantum Dot Light‐Emitting Diodes

Advanced Materials Interfaces, 2023
Passivation of defects in halide perovskite using phosphine oxide or alkyl‐phosphonate has recently obtained a few remarkable achievements. However, effective application of phosphine oxide or alky‐phosphonate in passivating perovskite quantum dots (QDs)
Fang Chen, Dingshuo Zhang, Qiaopeng Cui, Xingliang Dai, Peiqing Cai, Zhizhen Ye, Haiping He   +6 more
doaj   +1 more source

A synthetic methodology for the preparation of a water-soluble quaternized amino phosphine oxide ligand

Results in Chemistry, 2022
After several unsuccessful attempts to synthesize quaternized aniline-derived phosphanes, we succeeded to develop a synthetic methodology for the preparation of a water-soluble amino phosphine oxide ligand containing a quaternary ammonium ion by ...
Ioannis D. Kostas, Georgia Antonopoulou, Polydoros-Chrysovalantis Ioannou, Eleftherios Ferentinos, Panayotis Kyritsis   +4 more
doaj   +1 more source

Organophosphorus catalytic reaction based on reduction of phosphine oxide

Green Synthesis and Catalysis, 2023
The special electronic configuration of phosphorus atoms endows organophosphorus reagents with unique chemical properties, which enable them to be used to catalyze various organic reactions, such as the Wittig reaction, Staudinger reaction, Appel ...
Mengyu Pei, Anqi Tian, Qingqing Yang, Nianyu Huang, Long Wang, Dongsheng Li   +5 more
doaj   +1 more source