Results 91 to 100 of about 19,048 (288)
Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
Angewandte Chemie, EarlyView.Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera +2 more
wiley +2 more sources
Versatile PEG-derivatized phosphine oxide ligands for water-dispersible metal oxide nanocrystals
, 2007 We report the simple synthesis of poly( ethylene glycol) (PEG)-derivatized phosphine oxide ligands for water-dispersible metal oxide nanocrystals ...
Park, Yong Il +6 more
core +1 more source
Adaptive Coordination Engineering for Efficient and Robust H2 Release
Advanced Science, EarlyView.β‐H elimination is a pivotal but challenging step in homogeneous formic acid dehydrogenation reactions due to strict hydride‐metal matching. By using a rationally designed Pd1Ag2 bimetallic system with adaptive Pd1‐Ag2/L2 coordination and formate bridges, it enables boosted formic acid dehydrogenation under ambient air (7.7 times higher than a Pd ...
Xiaolin Jiang +8 more
wiley +1 more source
A Neutral “Masked” Diborene and Its Reactivity Toward Metal‐Free Pyridine Homocoupling
Angewandte Chemie, EarlyView.An unprecedented neutral “masked” diborene, formed via intramolecular arene dearomatization of an N‐heterocyclic imine‐supported free diborene, can be photochemically released to regenerate the highly reactive triplet diborene intermediate. Computational analysis elucidates the bonding situation of the hitherto elusive free diborene species, and the ...
Ke Li +4 more
wiley +2 more sources
Unusual phosphine oxidation: new triazolopyridyl-quinolyl phosphine oxide fluorescent dyes
RSC Advances, 2015 3-(2-Pyridyl)-[1,2,3]triazolo[1,5-a]quinolylphosphines suffer an unusual phosphine oxidation due to their special geometry that allows a σ-donation of the nitrogen (N1) lone pair to phosphorus.
Ballesteros-Garrido, Rafael +5 more
openaire +2 more sources
Donor Extended Blue TADF Dendrimer for High‐Performance Solution‐Processed OLEDs
Advanced Science, EarlyView.A dendronized MR‐TADF emitter, DOBNA‐SpAc‐DCz, was designed to improve solubility, hole transport, and exciton dynamics for solution‐processed OLEDs. Incorporation of ter(tert‐butylcarbazole) dendrons decreases ΔEST and accelerates RISC, yielding short delayed lifetimes (∼2 µs).
Mahni Fatahi +4 more
wiley +1 more source
A Nonbenzenoid Nanographene Horse Saddle With Four Pentagon–Octagon Pairs
Angewandte Chemie, EarlyView.Horse‐saddle molecule: We report herein the design and synthesis of an unprecedented saddle‐shaped non‐benzenoid Nanographene featuring a fused four‐pair pentagon–octagon core. The horse‐saddle structure of HN1 is determined by single‐crystal X‐ray diffraction.
Qiang Huang +11 more
wiley +2 more sources
Phosphine Oxide Polymer for Water-Soluble Nanoparticles
, 2016 A phosphine oxide polymer was developed using bis(dichlorophosphino)ethane and poly(ethylene glycol). This polymer system was used to transfer various nanoparticles from organic solvents to water, retaining their physical properties and ...
Alan Jasanoff (1334172) +4 more
core +1 more source
Advanced Science, EarlyView.An ultrasound‐activatable piezoelectric hydrogel reprograms chondrocyte mitochondrial epigenetics via the mTOR/GATD3A axis, clearing damaged mitochondria and alleviating osteoarthritis progression in both mouse models and human cartilage explants. ABSTRACT The avascular nature of cartilage hinders drug delivery for osteoarthritis (OA) therapy.
Hui Zheng +9 more
wiley +1 more source
Angewandte Chemie, EarlyView.Multiphotochromic switching is controlled by silicon valency in a diarylethene‐based molecular architecture. Lewis base coordination gates electronic communication between the photochromic units, thereby enabling selective access to distinct switching states.
Lennart Stoess +2 more
wiley +2 more sources