Results 71 to 80 of about 19,048 (288)

Development of phosphine oxide and arsine oxide organocatalysis

open access: yes, 2018
In the field of organic chemistry, phosphine oxides and arsine oxides have generally been viewed as undesirable nuisances since their major origin is the reaction by-products or result from undesired oxidation of a phosphine or arsine catalyst or ligand.
劳智奇, Lao, Zhiqi
core   +1 more source

3D Printed Omniphobic Slippery Liquid Infused Porous Surfaces for Low Surface Tension Repellency

open access: yesAdvanced Materials Technologies, EarlyView.
A 3D printing strategy fabricates omniphobic slippery liquid‐infused porous structures with lubricant reservoirs and interconnected microchannels. A post‐printing surface treatment modifies the porous surface to ensure compatibility with the infused fluorinated lubricant.
Noa Trink, Shlomo Magdassi
wiley   +1 more source

Mapping surface-modified titania nanoparticles with implications for activity and facet control

open access: yesNature Communications, 2017
Metal oxide nanocrystals can be grown with different facets exposed to give variations in reactivity, but the chemical state of these surfaces is not clear.
Yung-Kang Peng   +7 more
doaj   +1 more source

Enantioselective Coupling of Dienes and Phosphine Oxides [PDF]

open access: yesJournal of the American Chemical Society, 2018
We report a Pd-catalyzed intermolecular hydrophosphinylation of 1,3-dienes to afford chiral allylic phosphine oxides. Commodity dienes and air stable phosphine oxides couple to generate organophosphorus building blocks with high enantio- and regiocontrol. This method constitutes the first asymmetric hydrophosphinylation of dienes.
Shao-Zhen Nie   +2 more
openaire   +4 more sources

Naphthyridine‐Based Donor–Acceptor Boron Difluoride Complexes Targeting Red Emission in Organic Light‐Emitting Diodes

open access: yesAdvanced Optical Materials, EarlyView.
Four donor–acceptor boron difluoride complexes based on triphenylamine donor and a naphthyridine acceptor units were synthesized, studied, and applied as OLED emitters. They exhibit pronounced intramolecular charge transfer character, balanced charge transport properties, and tunable emission. Near‐unity PLQYs are achieved for selected compounds, while
Omar Lahna   +8 more
wiley   +1 more source

Zinc Exposure Causes Disulfidptosis to Induce Miscarriage by Up‐Regulating GATA1/METTL1/SLC7A11 Axis

open access: yesAdvanced Science, EarlyView.
Zn exposure up‐regulates GATA1, promoting GATA1‐mediated METTL1 and SLC7A11 transcription. It also enhances METTL1‐mediated m7G modification on SLC7A11 mRNA, increasing SLC7A11 mRNA stability. Ultimately, Zn exposure up‐regulates SLC7A11 at both transcriptional and post‐transcriptional levels, causing disulfidptosis. Knockdown of murine Slc7a11, Gata1,
Wenxin Huang   +16 more
wiley   +1 more source

The functionalisation of wool by tris(hydroxymethyl)phosphine for metal ion recovery

open access: yes, 2009
Tris(hydroxymethyl)phosphine (THP) was prepared by the addition of a stoichiometric amount of base to tetrakis(hydroxymethyl)phosphonium chloride (THPC).
Addison, Simon James
core  

Evaluation of bifunctional chiral phosphine oxide catalysts for the asymmetric hydrosilylation of ketimines [PDF]

open access: yes, 2019
A series of bifunctional phosphine oxides have been prepared and evaluated as catalysts for the trichlorosilane mediated asymmetric hydrosilylation of ketimines. bis-Phosphine oxides, hydroxy-phosphine oxides, and biaryl phosphine oxides all demonstrated
Warner, C.J.A., Jones, S., Berry, S.S.
core   +1 more source

Quantitative Mass Spectrometry‐Based Biodistribution of Monoclonal Antibodies: An Alternative to Radio‐Biodistribution

open access: yesAdvanced Science, EarlyView.
Monoclonal antibodies are powerful anticancer therapeutics targeting tumor‐associated antigens. Mass spectrometry enables precise and accurate quantification of mAbs in tumor plasma and healthy organs. Unlike ligand binding assay and radioactivity, mass spectrometry does not suffer from matrix effects and labelling artefacts while facilitating method ...
Domenico Ravazza   +9 more
wiley   +1 more source

Recent trends in bonding and structure of metal derivatives of phosphine chalcogenides

open access: yesDiscover Chemistry
In this review, the bonding and structures of coordination compounds of phosphine chalcogenides (P = E, E = O, S, Se, Te) with several transition and non-transition elements, reported during the period from 1990 to 2023, are described.
Tarlok Singh Lobana
doaj   +1 more source

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