Results 261 to 270 of about 38,475 (330)

Syntheses and properties of phosphine-substituted ruthenium(ii) polypyridine complexes with nitrogen oxides

, 2015
Go Nakamura, Mio Kondo, Meredith Crisalli, Sze Koon Lee, Akane Shibata, Peter C. Ford, Shigeyuki Masaoka   +6 more
openalex   +2 more sources

Fluorenyl Cations: Synthesis and Reactivity

Chemistry – A European Journal, EarlyView.
This review covers the history of fluorenyl cations from Deno's first report in 1954 on the parent fluorenyl cation to the present. The parent cation and most derivatives have only been observed as a fleeting species by mass spectrometry, UV/Vis spectroscopy, IR spectroscopy, or NMR spectroscopy while recent developments led to isolable species ...
Kanika Vashisth, Sameera Ranasinghe, Ayesha Begum, Manjur O. Akram, Jason L. Dutton, Caleb D. Martin   +5 more
wiley   +1 more source

Asymmetric alkyl-alkyl coupling between electron-deficient and unactivated alkenes to access α-chiral phosphines by Ni catalysis. [PDF]

Sci Adv
Zou JY, Xing FL, Zi QX, Du HW, Chen M, Shu W.   +5 more
europepmc   +1 more source

Copper-catalyzed tandem phosphination–decarboxylation–oxidation of alkynyl acids with H-phosphine oxides: a facile synthesis of β-ketophosphine oxides

, 2015
Pengbo Zhang, Liangliang Zhang, Yuzhen Gao, Jian Xu, Hua Fang, Guo Tang, Yufen Zhao   +6 more
openalex   +2 more sources

Ruthenium-catalysed hydrogenation of esters using tripodal phosphine ligands

, 2011
Boardman, B, Hanton, MJ, Miller, P, Tin, S   +3 more
core   +1 more source

Nucleophilic Addition versus Migratory Insertion Pathways in the Gold‐Catalyzed Heck Reaction: A Computational Study

Chemistry – A European Journal, EarlyView.
The “gold‐catalyzed Heck reaction” could in principle proceed either via nucleophilic attack by triflate, or by migratory alkene insertion. This DFT study shows that nucleophilic attack is strongly preferred but ligand dependent. Abstract The initial reaction steps in the formation of Heck‐type arylated alkenes catalyzed by P^N chelated Au(III ...
Peter H. M. Budzelaar, Luca Rocchigiani, Manfred Bochmann   +2 more
wiley   +1 more source

New Click on the Block: Photocaged Hydroxylamine, an Addition to the Light‐Activatable Bioorthogonal Toolbox

Chemistry – A European Journal, EarlyView.
The retro‐Cope bioorthogonal reactivity of hydroxylamines was disabled transiently with a coumarin photolabile protecting group, which could be recovered upon removal of the protecting group by a short, 400 nm light illumination. Light‐controlled recovery of reactivity was demonstrated in bioorthogonal fluorescent labeling schemes of intracellular ...
Krisztina Németh, Flóra Horváth, Ágnes Szatmári, Evelin Albitz, Péter Kele, Gergely B. Cserép   +5 more
wiley   +1 more source

Difluoroenol phosphinates as difluoroenolate surrogates: synthesis and applications in defluorination and deoxygenative coupling. [PDF]

Chem Sci
Kurosawa MB, Shimoyama S, Tanaka H, Yamaguchi J.   +3 more
europepmc   +1 more source

Nitrile Hydroboration by Cooperative Iron Catalysis: An Experimental and Computational Study

Chemistry – A European Journal, EarlyView.
We describe the Fe‐catalyzed double hydroboration of nitriles using HBpin as the terminal reductant. Mechanistic studies, both experimental and computational, reveal a unique and unreported mechanistic pathway for iron‐catalyzed hydroboration where reductive elimination, rather than B─H bond activation is the rate‐ limiting step.
Laura A. Grose, Yi Zhang, Samuel Oultram, Ryan J. Schwamm, Sam. P. de Visser, Darren Willcox   +5 more
wiley   +1 more source

Cooperativity in the assembly of H-bonded duplexes of synthetic recognition-encoded melamine oligomers. [PDF]

Chem Sci
Dhiman M, Escobar L, Smith JT, Hunter CA.   +3 more
europepmc   +1 more source