Results 61 to 70 of about 2,238,998 (236)

Phosphine-Catalyzed Intramolecular Cyclizations of α‑Nitroethyl­allenoates Forming (Z)‑Furanone Oximes

open access: yes, 2016
A novel and efficient phosphine-catalyzed intramolecular cyclization of α-nitroethyl­allenic esters is reported. This process appears to be practical for the stereoselective syntheses of (Z)-furan-2­(3H)-one oxime derivatives in excellent yields ...
Qing-Fa Zhou (1632868)   +3 more
core   +1 more source

Ultrasound‐Activatable Piezoelectric Hydrogel Reprograms Mitochondrial Epigenetics for Osteoarthritis Therapy via the mTOR/GATD3A Axis

open access: yesAdvanced Science, EarlyView.
An ultrasound‐activatable piezoelectric hydrogel reprograms chondrocyte mitochondrial epigenetics via the mTOR/GATD3A axis, clearing damaged mitochondria and alleviating osteoarthritis progression in both mouse models and human cartilage explants. ABSTRACT The avascular nature of cartilage hinders drug delivery for osteoarthritis (OA) therapy.
Hui Zheng   +9 more
wiley   +1 more source

Preliminary Study on the Differences in Hydrocarbons Between Phosphine-Susceptible and -Resistant Strains of Rhyzopertha dominica (Fabricius) and Tribolium castaneum (Herbst) Using Direct Immersion Solid-Phase Microextraction Coupled with GC-MS

open access: yesMolecules, 2020
Phosphine resistance is a worldwide issue threatening the grain industry. The cuticles of insects are covered with a layer of lipids, which protect insect bodies from the harmful effects of pesticides.
Ihab Alnajim   +5 more
doaj   +1 more source

Mitochondrial modulation of phosphine toxicity and resistance in Caenorhabditis elegans

open access: yes, 2008
Phosphine is a fumigant used to protect stored commodities from infestation by pest insects, though high-level phosphine resistance in many insect species threatens the continued use of the fumigant.
Zuryn, S   +4 more
core   +1 more source

Probing Electrocatalyst Design for Product Selectivity in CO2 Reduction

open access: yesAdvanced Science, EarlyView.
Selective CO2 electroreduction is controlled by catalyst structure, dynamic surface reconstruction, adsorbate interactions, and reaction microenvironment. This review summarizes Cu‐ and non‐Cu‐based catalysts, single‐atom and molecular systems, degradation pathways, and operando/computational strategies for steering CO2RR toward hydrocarbons ...
Suvodeep Sen   +5 more
wiley   +1 more source

Nanovesicles With Mechanically Induced Adjuvanticity for Robust Melanoma Vaccination Toward Tumor‐Associated Macrophages

open access: yesAdvanced Science, EarlyView.
Rigidity‐tunable nanovesicle (P‐Pm) with mechanically induced adjuvanticity toward tumor‐associated macrophages (TAMs) was designed to engineer R848/gp100 antigen ‐loaded nanovaccine (P@Rg‐Pm), which achieved outstanding anti‐tumor outcomes in both therapeutic and preventive model of B16‐F10 melanoma.
Bangyue Luo, Liyan Qiu
wiley   +1 more source

Synthesis and applications of Palladium complexes Part I. The synthesis, single crystal structures and liquid crystalline phase behavior of Alkoxy substituted Tolans. Part II. Palladium-Complexes of Thioureas and phosphine sulfides [PDF]

open access: yes, 2008
Three series of alkoxy substituted tolans p-X-C(_6)H(_4)-C≡C-C(_6)H(_4)-p-OC(_n)H(_2n+1) [X = H (series 1), CH(_3) (series 2), OCH(_3) (series 3)] with varying chain length were synthesized by Pd/Cu-catalysed Sonogashira cross-coupling reactions of ...
Wongkhan, Kittiya
core  

Phosphine-Stabilized Arsenium Salts:  Water-Stable, Labile, Coordination Complexes

open access: yes, 2016
A series of air- and water-stable tertiary phosphine-stabilized arsenium salts of the type R3P→AsR2+PF6- has been isolated. In the crystal structures of two chiral triarylphosphine complexes of prochiral methylphenylarsenium hexafluorophosphate, the ...
Anthony C. Willis (735858)   +3 more
core   +1 more source

Phosphine-Protected Atomically Precise Silver–Gold Alloy Nanoclusters and Their Luminescent Superstructures

open access: yes, 2022
Superstructures made by assemblies of metal nanoclusters (NCs) have gained interest due to their atomic precision and exciting photophysical properties.
Madhuri Jash (4527178)   +17 more
core   +1 more source

Phosphine-Catalyzed Asymmetric Cycloaddition Reaction of Diazenes: Enantioselective Synthesis of Chiral Dihydropyrazoles

open access: yes, 2019
Although carbon–carbon, carbon–nitrogen, and carbon–oxygen double bonds or their combinations have extensively been applied in phosphine-catalyzed asymmetric cycloaddition, a nitrogen–nitrogen double bond has never been investigated in chiral phosphine ...
Bo Wang   +13 more
core   +1 more source

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