Results 141 to 150 of about 5,035 (240)

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

Chemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan, Vu Nguyen Tran, Thanh Vinh Nguyen   +2 more
wiley   +1 more source

The versatile synthesis and biological evaluation of all-alkyl biscationic quaternary phosphonium compounds: atom-economical and potent disinfectants. [PDF]

RSC Med Chem
McDonough D, Bezold EL, Wuest WM, Minbiole KPC.   +3 more
europepmc   +1 more source

Dynamic Reactivity: Reversible Reaction of a Phosphinine–Borane Adduct With Water and Double Hydrophosphination

Chemistry – A European Journal, EarlyView.
A phosphinine–borane Lewis pair shows a dynamic mode of water addition, revealing reversible and regioselective transformations that expand the reactivity of aromatic phosphorus heterocycles and open pathways to stimuli‐responsive systems for catalysis, small‐molecule activation, and functional materials.
Samantha Frank, Ádám Horváth, Júlia Boglárka Horváth, Chiara Interdonato, Moritz J. Ernst, Priya Kumar, Zoltán Benkő, Christian Müller   +7 more
wiley   +1 more source

Direct Editing of Cysteine to Electrophilic Alkyl Halides in Peptides. [PDF]

J Am Chem Soc
Honeycutt DS, Salgado-Bello W, Greenberg HS, McCarthy WK, Mrosla JM, Pallares B, Goldberg JM, Wang F.   +7 more
europepmc   +1 more source

Pd‐Catalyzed C─C Bond Borylation of Biphenylenes Leading to Tri‐Ortho‐Substituted Biaryls

Chemistry – A European Journal, EarlyView.
Palladium‐catalyzed ring‐opening C─C borylation of 1‐substituted biphenylenes yields a range of o,o,o′‐trisubstituted biaryls with two ortho‐boryl groups via selective cleavage of the least hindered C─C bond. The resulting diborylated products are readily amenable to sequential, site‐selective postfunctionalization.
Robyn V. Presland, Konstantin V. Luzyanin, Luke A. Wilkinson, Oliver L. Jacobs, Nathan R. Halcovitch, Alexey G. Sergeev   +5 more
wiley   +1 more source

Cobalt(0)-Catalyzed Isomerization of Allylamines Promoted by Monodentate Benzofuran Phosphines. [PDF]

J Am Chem Soc
Ahrens S, Kusy R, Spannenberg A, Vuong TH, Rabeah J, Russbueldt BME, Panten J, Jiao H, Junge K, Beller M.   +9 more
europepmc   +1 more source

Rational Design Strategies for Stimuli‐Responsive DNAzymes Using Modified and Artificial Nucleotides

Chemistry – A European Journal, EarlyView.
Activity control of RNA‐cleaving DNAzymes in response to external stimuli has attracted growing interest for applications in DNA‐based diagnostics, therapeutics, and dynamic DNA nanotechnology. This review summarizes rational design strategies for stimuli‐responsive DNAzymes using modified or artificial nucleotides, including split and caged DNAzymes ...
Yusuke Takezawa, Mitsuhiko Shionoya
wiley   +1 more source

Addition Reactions of Phosphorus‐Centered Radicals onto Olefins: Interplay Between Stability and Reactivity

Chemistry – A European Journal, EarlyView.
The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang, Julianna Oláh, Zoltán Benkő   +2 more
wiley   +1 more source

Enantioselectivity in Transition Metal Catalyzed Propargylic Substitution Reactions: A Theoretical Perspective

Chemistry – A European Journal, EarlyView.
Recent theoretical efforts to elucidate the origin of enantioselectivity in transition metal‐catalyzed propargylic substitution reactions are highlighted in this review. ABSTRACT In recent years, asymmetric catalytic propargylic substitution reactions have undergone remarkable development, enabling the construction of chiral carbon centers adjacent to ...
Ken Sakata, Yoshiaki Nishibayashi
wiley   +1 more source

One-pot synthesis of primary phosphines from white phosphorus.

Chem Commun (Camb)
Mende M, Cammarata J, Scott DJ, Wolf R.
europepmc   +1 more source