Results 141 to 150 of about 51,028 (331)

Synthesis of elastomers for use with liquid fluorine Quarterly letter report, 1 Sep. - 30 Nov. 1968 [PDF]

open access: yes
Phosphines as initiators of polymerization of hexafluorobutyne-
Brown, H. C., Mukherjee, A. R.
core   +1 more source

Stereodivergent Access to Aliphatic Nitro Compounds Bearing Multi‐Contiguous Stereocenters via Sequential Catalysis

open access: yesAdvanced Science, EarlyView.
Herein, we report a highly efficient synthesis of aliphatic nitro compounds bearing multi‐contiguous stereocenters in good yields with excellent diastereo‐ and enantio‐selectivities by combining copper‐catalyzed asymmetric conjugate addition of dialkylzinc reagents to nitroalkenes with iridium‐catalyzed asymmetric allylic substitution reaction ...
Jia‐Hao Xie   +4 more
wiley   +1 more source

Ultrafast Dense Immobilization of Noble Metal Nanoparticles on Customizable Multifunctional Polymer Microspheres for Heterogeneous Catalysis and Multiplexed Biodetection

open access: yesAdvanced Science, EarlyView.
This work proposes a facile co‐assembly strategy to achieve highly uniform and dense immobilization of diverse noble metal nanoparticles onto metastable multifunctional (e.g., magnetic or fluorescent) polymer microspheres, enabling fabrication of complex hierarchical superstructures.
Jie Zhao   +12 more
wiley   +1 more source

Monolithic 3D Printing of Origami‐Inspired Soft Robotics from Sustainable Bio‐Based Resin

open access: yesAdvanced Science, EarlyView.
This work develops a photocurable, bio‐based resin from soybean oil for the monolithic fabrication of sustainable soft robots via Digital Light Processing. An origami‐inspired, vacuum‐actuated soft gripper is designed and fabricated, enabling reliable operation despite the material's lower elongation.
Ramin Montazeri   +6 more
wiley   +1 more source

Membrane‐Penetrating Molecular Device Based on a Triplex Containing Acyclic L‐Threoninol Nucleic Acid Functionalized with Cholesterol

open access: yesAngewandte Chemie, EarlyView.
A membrane‐penetrating molecular device composed of triplex containing cholesterol‐modified acyclic L‐threoninol nucleic acid (L‐aTNA) was achieved. This device is applied to a photo‐triggered signal transduction system functioning on giant unilamellar vesicles. Abstract Membrane‐penetrating molecular devices are valuable biological tools.
Kaifu Liu   +2 more
wiley   +2 more sources

Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update

open access: yesAdvanced Science, EarlyView.
This review explores recent advances in the past five years for non‐traditional RAFT polymerization, focusing on new activation strategies, sustainable depolymerization, and integration with automated and AI‐driven synthesis. Together, these innovations advance polymer chemistry and reveal how the pieces of the non‐traditional RAFT puzzle are steadily ...
Vianna F. Jafari   +10 more
wiley   +1 more source

Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin

open access: yesAngewandte Chemie, EarlyView.
Triply gated isomerization: In polar solvents, a phosphorus‐containing indirubin photoswitch undergoes visible‐light‐driven Z→E isomerization only when protonated, and reverts thermally via nucleophile‐catalyzed back‐isomerization. This three‐way control by light, acid, and nucleophile enables reversible photoisomerization.
Jacob Jan van der Wal   +8 more
wiley   +2 more sources

Cycloaurated GoId (III) complexes- Possible alternatives to cisplatin? [PDF]

open access: yes, 2009
The serendipitous discovery of the anti-tumour activity of cisplatin [cis-PtCI₂(NH₃)₂] in 1969 has led to increased interest in the development of new metal-based anti-cancer drugs.
Henderson, William, Kilpin, Kelly Joan
core   +1 more source

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