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Dawn of photoredox catalysis. [PDF]
Proc Jpn Acad Ser B Phys Biol SciPhotoredox catalysis, which facilitates organic transformations under visible-light irradiation, including sunlight, has garnered considerable attention as a cornerstone of green chemistry.
Akita M.
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Molecular Rubies in Photoredox Catalysis
Frontiers in Chemistry, 2022 The molecular ruby [Cr(tpe)2]3+ and the tris(bipyridine) chromium(III) complex [Cr(dmcbpy)3]3+ as well as the tris(bipyrazine)ruthenium(II) complex [Ru(bpz)3]2+ were employed in the visible light-induced radical cation [4+2] cycloaddition (tpe = 1,1,1 ...
Steven Sittel +2 more
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Organic synthesis using photoredox catalysis [PDF]
Beilstein Journal of Organic Chemistry, 2014 Natural photosynthesis is a remarkable chemical machinery that enables our life on earth and delivers a constant stream of oxygen and organic biomass. We should acknowledge this fact with humbleness, especially because we have not been able yet to mimic this process in a reliable way even after decades of intense research.
Axel G. Griesbeck
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Cooperative Photoredox and Asymmetric Catalysis
CHIMIA, 2016 Chemical processes combining visible-light-activated redox catalysis with asymmetric catalysis are reviewed, including enamine catalysis in the presence or absence of an additional photoredox sensitizer, phase transfer catalysis exploiting an in
Haohua Huo, Eric Meggersa
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Chemistry glows green with photoredox catalysis [PDF]
Nature Communications, 2020 Can organic chemistry mimic nature in efficiency and sustainability? Not yet, but recent developments in photoredox catalysis animated the synthetic chemistry field, providing greener opportunities for industry and academia.
Giacomo E. M. Crisenza, Paolo Melchiorre
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Cooperative Photoredox Catalysis Under Confinement. [PDF]
ChemistryAbstractPhotoredox catalysis has emerged as a potent means to conduct synthetic chemistry. Leveraging light to achieve challenging organic transformations has led to many developments, both of fundamental and industrial nature. Despite their potency, photoredox processes are inherently diffusion controlled, which can limit their ability to enable both ...
Gaikwad S, Bhattacharjee A, Elacqua E.
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Photoredox Catalysis for Polymerization Reactions
CHIMIA, 2012 Photoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp).
Jacques Lalevée +7 more
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Excited Organic Radicals in Photoredox Catalysis. [PDF]
JACS AuMany important synthetic-oriented works have proposed excited organic radicals as photoactive species, yet mechanistic studies raised doubts about whether they can truly function as photocatalysts. This skepticism originates from the formation of (photo)redox-active degradation products and the picosecond decay of electronically excited radicals, which
Pfund B, Wenger OS.
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Interfacial Charge Transfer Regulates Photoredox Catalysis. [PDF]
ACS Cent SciPhotoredox catalytic processes offer the potential for precise chemical reactions using light and materials. The central determinant is identified as interfacial charge transfer, which simultaneously engenders distinctive behavior in the overall reaction.
Ye C, Zhang DS, Chen B, Tung CH, Wu LZ.
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