Results 61 to 70 of about 5,692 (237)

From:E to Z and back again: Reversible photoisomerisation of an isolated charge-tagged azobenzene [PDF]

open access: yes, 2018
Substituted azobenzenes serve as chromophores and actuators in a wide range of molecular photoswitches. Here, tandem ion mobility spectrometry coupled with laser excitation is used to investigate the photoisomerisation of selected E and Z isomers of the ...
Adamson   +40 more
core   +2 more sources

Photon Avalanching Nanoparticles: The Next Generation of Upconverting Nanomaterials?

open access: yesAdvanced Functional Materials, EarlyView.
This Perspective outlines the mechanistic foundations that enable photon‐avalanche (PA) behavior in lanthanide nanomaterials and contrasts them with emerging application spaces and forward‐looking design strategies. By bridging threshold engineering, energy‐transfer dynamics, and materials engineering, we provide a coherent roadmap for advancing the ...
Kimoon Lee   +7 more
wiley   +1 more source

Recent Advances of Azobenzene-Based Photoresponsive Molecular Switches for Protein-Targeted Photopharmacology

open access: yesMolecules
Azobenzene derivatives constitute a prototypical class of photoresponsive molecular switches with broad utility in synthetic chemistry and biomedical research, owing to their distinctive physicochemical properties.
Jingyu Jiang, Xinrui Yuan, Lei Hu
doaj   +1 more source

Vibrational Spectroscopy of Phytochromes

open access: yesBiomolecules, 2023
Phytochromes are biological photoswitches that translate light into physiological functions. Spectroscopic techniques are essential tools for molecular research into these photoreceptors.
Peter Hildebrandt
doaj   +1 more source

Charge-transfer dynamics in azobenzene alkanethiolate self-assembled monolayers on gold [PDF]

open access: yes, 2016
We have studied the charge transfer dynamics in azobenzene-functionalized alkanethiolate self-assembled monolayers. We compare the core-hole clock technique, i.e., resonant vs. non-resonant contributions in the azobenzene autoionization of the C1s-pi∗
Brete, Daniel   +4 more
core   +1 more source

Design of a Photoswitchable Cadherin [PDF]

open access: yesJournal of the American Chemical Society, 2013
There is a growing interest in engineering proteins whose function can be controlled with the spatial and temporal precision of light. Here, we present a novel example of a functional light-triggered switch in the Ca-dependent cell-cell adhesion protein E-cadherin, created using a mechanism-based design strategy. We report an 18-fold change in apparent
Kortemme, Tanja   +3 more
openaire   +4 more sources

Light‐Programmable Interfaces: From Molecular Photoswitching to Adaptive Membrane Separations

open access: yesAdvanced Materials Interfaces, EarlyView.
This review advances an interface‐centered framework for light‐responsive membranes, linking molecular photoswitches (azobenzene (AZO), spiropyran (SP), diarylethene (DAE), donor–acceptor Stenhouse adducts (DASA), photoacid) to integration strategies in polymeric, porous, self‐assembled, and mixed‐matrix systems.
Liangliang Zhang   +6 more
wiley   +1 more source

Predicting photoactivity in dithienylethene crystalline solids

open access: yesIUCrJ, 2023
This commentary discusses the design of stimuli-responsive materials, specifically, light-responsive dithienylethene-based compounds. Recent progress in predicting photoactivity using a combination of theory and crystal structure landscape experiments is
Kristin M. Hutchins
doaj   +1 more source

Optical gating with organic building blocks : A quantitative model for the fluorescence modulation of photochromic perylene bisimide dithienylcyclopentene triads [PDF]

open access: yes, 2014
We investigated the capability of molecular triads, consisting of two strong fluorophores that were covalently linked to a photochromic molecule, for optical gating.
Bauer, Peter   +5 more
core   +1 more source

A Chiroptical Photoswitchable DNA Complex [PDF]

open access: yesThe Journal of Physical Chemistry B, 2011
The interesting structural, electronic, and optical properties of DNA provide fascinating opportunities for developing nanoscale smart materials by integrating DNA with opto-electronic components. In this article we demonstrate the electrostatic binding of an amine-terminated dithienylethene (DET) molecular switch to double-stranded synthetic ...
- Mammana   +4 more
openaire   +3 more sources

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