Results 21 to 30 of about 6,093 (220)
Short Photoswitchable Antibacterial Peptides
AbstractThree photoswitchable tetrapeptides, based on a known synthetic antibacterial, were designed and synthesized to determine activity against Staphylococcus aureus. Each peptide contains an azobenzene photoswitch incorporated into either the N‐terminal side chain (1), C‐terminal side chain (2), or the C‐terminus (3) to allow reversible switching ...
Yuan Qi Yeoh +5 more
openaire +5 more sources
Azobenzene photocontrol of peptides and proteins [PDF]
The last few years have witnessed significant advances in the use of light as a stimulus to control biomolecular interactions. Great efforts have been devoted to the development of genetically encoded optobiological and small photochromic switches. Newly
Allemann, Rudolf, Mart, Robert
core +1 more source
Emission color tuning and white-light generation based on photochromic control of energy transfer reactions in polymer micelles [PDF]
We encapsulate a fluorescent donor molecule and a photochromic acceptor unit (photoswitch) in polymer micelles and show that the color of the emitted fluorescence is continuously changed from blue to yellow upon light-induced isomerization of the ...
Andréasson, Joakim +8 more
core +2 more sources
Azotriptycenes: Photoswitchable Molecular Brakes
AbstractThe control of molecular motions is a central topic of molecular machine research. Molecular brakes are fundamental building blocks towards such goal as they allow deliberately decelerating specific motions after an outside stimulus is applied. Here we present azotriptycenes as structural framework for light‐controlled molecular brakes.
Stockerl, Willibald J. +7 more
openaire +3 more sources
Nonlinear optical techniques as two-photon absorption (TPA) have raised relevant interest within the last years due to the capability to excite chromophores with photons of wavelength equal to only half of the corresponding one-photon absorption energy ...
Marco Marazzi +5 more
doaj +1 more source
Concentration dependence of thermal isomerization process of methyl orange in ethanol [PDF]
The thermal isomerization (TI) rates of methyl orange (MO) and 4-dimethylaminoazobenzene (DMAAB) in ethanol (EtOH) are measured. Usually TI rates of azobenzene dyes are known to be concentration independent.
KINOSHITA Eri +3 more
core +2 more sources
Dihydroazulene‐Azobenzene‐Dihydroazulene Triad Photoswitches [PDF]
AbstractPhotoswitch triads comprising two dihydroazulene (DHA) units in conjugation with a central trans‐azobenzene (AZB) unit were prepared in stepwise protocols starting from meta‐ and para‐disubstituted azobenzenes. The para‐connected triad had significantly altered optical properties and lacked the photoactivity of the separate photochromes.
Alvis Mengots +9 more
openaire +6 more sources
Coherent ultrafast torsional motion and isomerization of a biomimetic dipolar photoswitch [PDF]
Femtosecond fluorescence up-conversion, UV-Vis and IR transient absorption spectroscopy are used to study the photo-isomerization dynamics of a new type of zwitterionic photoswitch based on a N-alkylated indanylidene pyrroline Schiff base framework (ZW ...
Andrea Cannizzo +63 more
core +4 more sources
Rationally designed azobenzene photoswitches for efficient two-photon neuronal excitation
Two-photon absorption capacity of azobenzene photoswitches usually comes with a reduction in thermal stability. Here, the authors developed photoswitches with high two-photon sensitivity and enhanced cis isomer thermal lifetime for the control of ...
Gisela Cabré +13 more
doaj +1 more source
Orthogonal photoswitching in a multifunctional molecular system
While molecular photoswitches have proven useful in many fields, selective and reversible control over multiple switches is an unsolved challenge. Here, the authors report on a system consisting of two classes of photoswitches that can be addressed ...
Michael M. Lerch +4 more
doaj +1 more source

