Results 51 to 60 of about 2,055 (188)
European Journal of Inorganic Chemistry, Volume 28, Issue 28, October 11, 2025.Variable coordination of peroxide: The reaction of the Cu(I) complex‐based on the BPMPD ligand with O2 at low temperatures initially led to a μ‐1,2 peroxo species (Cu2O2). By addition of an acid (lutidinium triflate), this species can be reversibly converted into a μ‐1,1‐hydroperoxo complex, which is monitored using UV/Vis spectroscopy and X‐ray ...
Alexander Stüber +10 more
wiley +1 more source
Preparation and nucleophilic substitution of hexafluorophthalazine [PDF]
, 1970 Not ...
Reilly, Ian Stephen
core +1 more source
Hybrid Diagonal Approximation in Time‐Dependent Auxiliary Density Functional Theory
Journal of Computational Chemistry, Volume 46, Issue 23, September 5, 2025.Our work demonstrates that time‐dependent auxiliary density functional theory (TD‐ADFT) in combination with the hybrid diagonal approximation (HDA) for global and range‐separated hybrid functionals is a promising approach for low‐order scaling electronic excitation energy calculations.
Kevin O. Pérez‐Becerra +4 more
wiley +1 more source
Boron–Boron Single Bonds Mimicking Transition Metals
European Journal of Inorganic Chemistry, Volume 28, Issue 23, August 26, 2025.Through careful design of the substituents, ambiphilic cationic diboranes are formed through substituent elimination from stable nucleophilic diboranes. The ambiphilic reactivity could be used to coordinate and selectively reduce organic substrates in the diborane coordination sphere.
Hans‐Jörg Himmel
wiley +1 more source
Chemistry – A European Journal, Volume 31, Issue 37, July 2, 2025.Access to various copper‐oxygen intermediates: Depending on the reaction conditions, different copper‐oxygen intermediates can be obtained with our new dinuclear complex. Whereas low‐temperature oxygenation leads to a μ‐1,1 hydroperoxo complex, oxygenation at room temperature generates a “green species” that looks like a mono μ‐oxo complex but rather ...
Alexander Stüber +11 more
wiley +1 more source
Advances in Mechanochemical Methods for One‐Pot Multistep Organic Synthesis
Chemistry – A European Journal, Volume 31, Issue 34, June 17, 2025.This review highlights recent advances in mechanochemical methods for multistep organic synthesis, focusing on sequential one‐pot approaches performed by grinding or ball milling. The presented transformations are discussed in terms of efficiency, applicability, and sustainability, assessing both the challenges and potential of solvent‐free one‐pot ...
Nina Biedermann, Michael Schnürch
wiley +1 more source
Syntheses in the Pyridazine Series. XXXII. Some Investigations on Polynuclear Systems Containing a Pyridazine Ring [PDF]
, 1969 Some 5,6-dihydrobenzo[f]phthalazines have been aromatized to II and the structures of a number of nitro derivatives prepared from several polynuclear systems (III, IV, V) , have been ...
A. Krbavčič +3 more
core +3 more sources
The first example of an intramolecular westphal reaction. Synthesis of a new aza-quinolizinium type system [PDF]
, 1999 The first example of an intramolecular Westphal condensation is described. To test the utility of this reaction, new benz(f)azino[2,1-a]phthalazinium salts have been prepared from appropriate dicarbonyl precursors.The authors wish to thank the Comisión ...
Burgos García, Carolina +4 more
core +2 more sources
Bisboron chemistry in small molecule activation and the synthesis of novel BN aromatics [PDF]
, 2016 The research on small molecules such as CO2, H2 and NH3BH3 receives currently a lot of attention. For instance, CO2 is largely produced from industrial process and transportation, which leads to serious environmental issues.
Lu, Zhenpin
core +1 more source
One-pot synthesis and negative ion mass spectrometric investigation of a densely functionalized cinnoline, 3-amino-5,7,8-trichloro-6-hydroxycinnoline-4-carbonitrile [PDF]
Known densely substituted 3-amino-5,7,8-trichloro-6-hydroxycinnoline-4-carbonitrile was synthesized using a new synthetic protocol involving chloranil and malonitrile via quinone methide formation.
Dempster, NM +9 more
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