Results 191 to 200 of about 383,310 (333)

Hydrogels Under Superchaotropic Control: Polyoxometalate Stabilization and pH‐Responsive Crosslinking in Cellulose Ether Solutions

Angewandte Chemie, EarlyView.
Superchaotropic binding of Keggin polyoxometalates (POMs) to non‐ionic biopolymers like cellulose ethers (CEs) stabilizes otherwise hydrolytically unstable POMs in aqueous solution and allows conversion of pH‐nonresponsive polymers into pH‐responsive soft materials. The pH‐driven conversion from plenary to lacunary POMs switches superchaotropic binding
Vighnesh B. Lokare, Amina Ledinic, Nina Wehr, Max Hohenschutz   +3 more
wiley   +2 more sources

Targeting beta-2 adrenergic receptor attenuates schizophrenia-like behavioral effects induced by ketamine in mice: cAMP/PKA/BDNF-PEA-3 and RIM-1α signaling pathways involvement. [PDF]

Saudi Pharm J
Heikal MM, Mohamed AF, Rasheed NOA, El-Tanbouly DM, Nassar NN.   +4 more
europepmc   +1 more source

Phosphorylation of NF-kappa B p65 by PKA stimulates transcriptional activity by promoting a novel bivalent interaction with the coactivator CBP/p300.

Molecules and Cells, 1998
H. Zhong, Reinhard E. Voll, S. Ghosh
semanticscholar   +1 more source

Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6

Angewandte Chemie, EarlyView.
While electrophilic aromatic substitution is well‐established for carbon and silicon‐based electrophiles, it is extremely underdeveloped for germanium. Herein we report the first effective intermolecular Germa–Friedel–Crafts reaction. The process can be modified to enable selective synthesis of the mono‐ or the di‐aryl germane derivatives, ArGeCl3 and ...
Justyna Łosiewicz, Milan Kumar Bisai, Zachary A. Bub, Stuart A. Macgregor, Michael J. Ingleson   +4 more
wiley   +2 more sources

Atomic‐Scale Understanding of Selectivity Control in Nitrate Reduction on Cu(100) Under Acidic and Alkaline Conditions

Angewandte Chemie, EarlyView.
A combination of ab initio molecular dynamics simulations and density functional theory calculations clarifies the pH‐dependent origin of the selectivity of nitrate reduction on Cu(100). ABSTRACT We investigate the nitrate reduction reaction (NO3 RR) on the Cu(100) surface using grand‐canonical density functional theory (GC‐DFT) under constant ...
Ebrahim Tayyebi, Kai S. Exner
wiley   +2 more sources

Aldehyde–Olefin Couplings by Photoinduced Reduction of Electron‐Deficient Olefins with Hantzsch Ester Anions

Angewandte Chemie, EarlyView.
Single‐electron transfer‐mediated reductive carbonyl–olefin couplings are valuable carbon–carbon bond forming reactions. However, limitations persist for couplings of aliphatic aldehydes with electron‐deficient olefins. Here, we report a simple, photocatalyst‐free protocol that overcomes these limitations by using a Hantzsch ester anion as a ...
Zhihang Li, Adam Noble
wiley   +2 more sources

The Role of A-Kinase Anchoring Proteins for Inhibitory cAMP Signalling in Platelets. [PDF]

Cells
Barkey S, Smolenski A.
europepmc   +1 more source

Development of a pKa predictor (pKaLearn) by leveraging teaching experience to improve machine learning. [PDF]

Commun Chem
Genzling J, Luo Z, Weiser B, Moitessier N.   +3 more
europepmc   +1 more source

A redox sensor in protein kinase A regulatory subunit Iα regulates vasodilation and protects against hypertension. [PDF]

Redox Biol
Rudyk O, Braga A, Wheatcroft N, Bonzanni M, Prysyazhna O, Korneh MNA, Green HLH, Zhou Y, Zhang M, Gourine AV, Eaton P.   +10 more
europepmc   +1 more source

MYCN inhibits TrkC-mediated differentiation in neuroblastoma cells via disruption of the PKA signalling pathway. [PDF]

Cell Death Discov
Maher S, Roe A, Wynne K, Zhernovkov V, Halasz M.   +4 more
europepmc   +1 more source