Tuning 2,3-Bis(arylimino)butane-nickel Precatalysts for High-Molecular-Weight Polyethylene Elastomers [PDF]
MoleculesThe catalytic performance of α-diiminonickel complexes is highly sensitive to structural modifications in their ligand frameworks. In this study, a series of unsymmetrical 2,3-bis(arylimino)butane-nickel complexes featuring ortho-2,6-dibenzhydryl groups ...
Dongzhi Zhu +5 more
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Controlled Copolymerization of Ethylene and Biosourced Comonomers Using Dibenzobarrelene-Based α-Diimine Nickel Catalyst [PDF]
MoleculesThe development of earth-abundant nickel-based catalysts is currently one of the greatest challenges for the straightforward synthesis of functionalized polyolefins.
Handou Zheng +6 more
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Cyano-functionalized polyethylenes from ethylene/acrylamide copolymerization [PDF]
Nature CommunicationsSynthesizing functionalized polyethylenes via ethylene coordination copolymerization with fundamental low-cost vinyl polar monomers provides a very attractive approach.
Shu-Yang Yu +10 more
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Finely-Tuned Bis(imino)pyridylcobalt Complexes Enhance Ethylene Polymerization: The Role of Bulky and Halogen Substituents [PDF]
MoleculesThe bis(imino)pyridylcobalt complexes have been finely tuned through using the aniline derivative bearing a meta-chloro substituent, besides its ortho- and para-di(4-fluorophenyl)methyl and ortho-methyl substituents for the series of 2-[1-(3-chloro-4,6 ...
Elizabeth Ogbe +5 more
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Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion [PDF]
Nature CommunicationsPolyolefins are the most widely produced type of plastics owing to their low production cost and favorable properties. Their polymer backbone consists solely of inert C-C bonds, making them resistant and durable materials.
Robin Lemmens +3 more
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Ethylene Polymerization through Neutral Nickel Complexes Bearing Cyclic Imides
Advances in Polymer Technology, 2022 The catalyst synthesis of salicylaldimine Ni(II) complexes with bulky imide moieties, ethylene polymerization, and characterization of synthesized polyethylenes are described in this paper.
Hassan Arabi +2 more
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Macromol, 2021 Nickel-based ethylene polymerization catalysts have unique features, being able to produce macromolecules with a variable content of branches, resulting in polymers ranging from semicrystalline plastics to elastomers to hyperbranched amorphous waxes and ...
Ilaria D’Auria +2 more
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Macromol, 2022 Polyethylenes (PE) are the most commonly occurring ingredients for post-consumer recyclates (PCR). The structure–property relationships of different types of model PE-based blends are established using multiple thermo-rheological analyses.
Girish Galgali +2 more
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Radio-Oxidation of Electric Cabled Models: Ageing Evaluation at the Atomic Scale
Energies, 2022 The functionality of electric cables, being the safety components of plants, has to be ensured. In nuclear power plants, when they are in the reactor building, these cables can suffer γ irradiation even in normal operating conditions.
Muriel Ferry, Frederic Miserque
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Polymerization of Ethylene Catalyzed by Vanadium(III) Complexes
Orbital: The Electronic Journal of Chemistry, 2017 Thirty five complexes of 1,2- bis(benzimidazole, benzothiazole and benzoxazole)benzene, 1,2-bis(benzimidazole, benzothiazole and benzoxazole)-4-methyl-benzene, 1,2-bis (benzimidazole, benzothiazole and benzoxazole)4-bromobenzene, 1, 2-bis ...
Hamdi Ali Elagab
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