Tuning 2,3-Bis(arylimino)butane-nickel Precatalysts for High-Molecular-Weight Polyethylene Elastomers [PDF]
The catalytic performance of α-diiminonickel complexes is highly sensitive to structural modifications in their ligand frameworks. In this study, a series of unsymmetrical 2,3-bis(arylimino)butane-nickel complexes featuring ortho-2,6-dibenzhydryl groups ...
Dongzhi Zhu +5 more
doaj +2 more sources
Controlled Copolymerization of Ethylene and Biosourced Comonomers Using Dibenzobarrelene-Based α-Diimine Nickel Catalyst [PDF]
The development of earth-abundant nickel-based catalysts is currently one of the greatest challenges for the straightforward synthesis of functionalized polyolefins.
Handou Zheng +6 more
doaj +2 more sources
Cyano-functionalized polyethylenes from ethylene/acrylamide copolymerization [PDF]
Synthesizing functionalized polyethylenes via ethylene coordination copolymerization with fundamental low-cost vinyl polar monomers provides a very attractive approach.
Shu-Yang Yu +10 more
doaj +2 more sources
Finely-Tuned Bis(imino)pyridylcobalt Complexes Enhance Ethylene Polymerization: The Role of Bulky and Halogen Substituents [PDF]
The bis(imino)pyridylcobalt complexes have been finely tuned through using the aniline derivative bearing a meta-chloro substituent, besides its ortho- and para-di(4-fluorophenyl)methyl and ortho-methyl substituents for the series of 2-[1-(3-chloro-4,6 ...
Elizabeth Ogbe +5 more
doaj +2 more sources
Diverse functional polyethylenes by catalytic amination [PDF]
Nicodemo R Ciccia +2 more
exaly +2 more sources
Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion [PDF]
Polyolefins are the most widely produced type of plastics owing to their low production cost and favorable properties. Their polymer backbone consists solely of inert C-C bonds, making them resistant and durable materials.
Robin Lemmens +3 more
doaj +2 more sources
Conversion of Polyethylenes into Fungal Secondary Metabolites [PDF]
Christian Rabot +2 more
exaly +2 more sources
Ethylene Polymerization through Neutral Nickel Complexes Bearing Cyclic Imides
The catalyst synthesis of salicylaldimine Ni(II) complexes with bulky imide moieties, ethylene polymerization, and characterization of synthesized polyethylenes are described in this paper.
Hassan Arabi +2 more
doaj +1 more source
Unveiling the Effects of Thermal Aging on the Oxidative Stability of Biobased Low-Density Polyethylenes [PDF]
Joanna Aniśko-Michalak +5 more
doaj +2 more sources
ortho/para-Chlorinated α‑Diimine Nickel Precatalysts Resulting Polyethylenes with Improved Mechanical Properties and Controlled Crystallinity [PDF]
Aoqian Xi +7 more
doaj +2 more sources

