Rapid photoassisted access to N,O,S-polyheterocycles with benzoazocine and hydroquinoline cores: intramolecular cycloadditions of photogenerated azaxylylenes. [PDF]
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The Groebke-Blackburn-Bienaymé reaction in its maturity: innovation and improvements since its 21st birthday (2019-2023). [PDF]
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Intramolecular carbenoid ylide forming reactions of 2-diazo-3-keto-4-phthalimidocarboxylic esters derived from methionine and cysteine. [PDF]
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Nucleophilic addition to 2,3-pyridyne and synthesis of benzonaphthyridinones. [PDF]
Fang Y, Larock RC.
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Tricyclic chemistry. Synthesis and chemistry of a novel polyheterocycle
Journal of Heterocyclic Chemistry, 1979AbstractThe photochemical reaction of 1 with acrylonitrile gave the cyclobutane adducts II and III, which on treatment with base afforded a novel polycyclic structure IV. Reduction of IV with LAH followed by Eschweiler‐Clarke methylation yielded the polyheterocyclic structure VI.
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