Results 61 to 70 of about 236,012 (388)

MnI‐Functionalized Covalent Organic Framework as Efficient Electrocatalyst for CO2 Reduction in a Catholyte‐Free Zero‐Gap Electrolyzer

open access: yesAdvanced Functional Materials, EarlyView.
This work demonstrates the successful integration of a phenanthroline‐based 2D COF with MnI catalytic sites into a catholyte‐free membrane‐electrode‐assembly cell for CO2 electroreduction. The crystalline COF actively suppresses Mn⁰–Mn⁰ dimerization, achieving a turnover frequency of 617 h⁻¹ at 2.8 V (full‐cell potential), and enabling stable operation.
Laura Spies   +8 more
wiley   +1 more source

The effect of porphyrins on normal and transformed mouse cell lines in the presence of visible light

open access: yesBrazilian Journal of Medical and Biological Research, 2001
Photodynamic therapy consists of the uptake of a photosensitizing dye, often a porphyrin, by tumor tissue and subsequent irradiation of the tumor with visible light of an appropriate wavelength matched to the absorption spectrum of the photosensitizing ...
S.P.S Tita, J.R. Perussi
doaj   +1 more source

Interactions Between Spermine-Derivatized Tentacle Porphyrins And The Human Telomeric DNA G-Quadruplex [PDF]

open access: yes, 2018
G-rich DNA sequences have the potential to fold into non-canonical G-Quadruplex (GQ) structures implicated in aging and human diseases, notably cancers.
Chen, Jessica, , \u2717   +5 more
core   +1 more source

Amplified singlet oxygen generation in metallated-porphyrin doped conjugated polymer nanoparticles [PDF]

open access: yes, 2018
We report on the mechanism and efficiencies of singlet oxygen O2(1Δg) generation of nanoparticles (NP) of the conjugated polymer (CP) poly(9,9-dioctylfluorene-alt-benzothiadiazole) (F8BT) doped with platinum octaethylporphyrin (PtOEP) suspended in water.
Chesta, Carlos Alberto   +7 more
core   +2 more sources

Porphyrin photosensitizers in photodynamic therapy and its applications

open access: yesOncoTarget, 2017
In 1841, the extraction of hematoporphyrin from dried blood by removing iron marked the birth of the photosensitizer. The last twenty years has witnessed extensive research in the application of photodynamic therapy (PDT) in tumor-bearing (or other ...
Jiayuan Kou, D. Dou, Liming Yang
semanticscholar   +1 more source

Flexibility and Dynamicity Enhances and Controls Supramolecular Self‐Assembly of Zinc(II) Metallogels

open access: yesAdvanced Functional Materials, EarlyView.
Zinc(II) coordination complexes with tunable aryloxy‐imine ligands exhibit controllable supramolecular self‐assembly into hierarchical fibrous structures. Coordination‐driven stacking, not π–π interactions, enables gelation, dynamic assembly/disassembly, and enhanced nanomechanical properties.
Merlin R. Stühler   +10 more
wiley   +1 more source

Self-assembled micro and nano rod-shaped porphyrin@Bi12O17Cl2 composite as an efficient photocatalyst for degradation of organic contaminants

open access: yesDiscover Nano, 2023
Bi12O17Cl2 is a potential photocatalyst in practical applications due to its excellent photostability, visible light activity, and competitive bandgap energy.
Osemeikhian Ogbeifun   +2 more
doaj   +1 more source

A low-bandgap dimeric porphyrin molecule for 10% efficiency solar cells with small photon energy loss [PDF]

open access: yes, 2018
Dimeric porphyrin molecules have great potential as donor materials for high performance bulk heterojunction organic solar cells (OSCs). Recently reported dimeric porphyrins bridged by ethynylenes showed power conversion efficiencies (PCEs) of more than ...
Cao, Y   +8 more
core  

Atomically Dispersed Copper Electrocatalysts with Proton‐feeding Centers for Efficient Ammonia Synthesis by Nitrate Electroreduction

open access: yesAdvanced Functional Materials, EarlyView.
Rationally‐designed advanced carbon‐based single‐atom catalysts with isolated CuN2O2 active sites anchored in N,O‐doped porous carbon facilitate water dissociation and nitrate reduction, accelerating proton supply for efficient electrosynthesis of ammonia.
Yan Li   +14 more
wiley   +1 more source

En Route to a Chiral Melanin: The Dynamic “From-Imprinted-to-Template” Supramolecular Role of Porphyrin Hetero-Aggregates During the Oxidative Polymerization of L-DOPA

open access: yesFrontiers in Chemistry, 2020
Chiral porphyrin hetero-aggregates, produced from meso-tetrakis(4-N-methylpyridyl) porphyrin H2T4 and copper(II) meso-tetrakis(4-sulfonatophenyl)porphyrin CuTPPS by an imprinting effect in the presence of L-3,4-dihydroxyphenylalanine (L-DOPA), are shown ...
Massimiliano Gaeta   +7 more
doaj   +1 more source

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