Results 41 to 50 of about 66,875 (309)
Nickel and vanadyl porphyrins belong to the so-called fossil geo- or sedimentary porphyrins. They occur in different types of organic matter-rich sediments but mostly occur in crude oils and their source rocks, oil shales, coals, and oil sands.
Robert Stasiuk, Renata Matlakowska
doaj +1 more source
Electroactive Metal–Organic Frameworks for Electrocatalysis
Electrocatalysis is crucial in sustainable energy conversion as it enables efficient chemical transformations. The review discusses how metal–organic frameworks can revolutionize this field by offering tailorable structures and active site tunability, enabling efficient and selective electrocatalytic processes.
Irena Senkovska +7 more
wiley +1 more source
Synthesis and properties of cationic derivaties of meso-tetra(4-pyridyl)porphyrin
Synthesis of amphyphilic cationic meso-pyridilsubstituted porphyrins bearing long chain alkyl groups is described. An improved methods of preparation of tetra- and mono-alkylsubstituted meso-pyridil porphyrins are proposed.
N. V. Novikov +5 more
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Lignin has recently attracted the attention of the scientific community, as a suitable raw material for biomedical applications. In this work, acetylated lignin was used to encapsulate five different porphyrins, aiming to preserve their photophysical ...
Nidia Maldonado-Carmona +6 more
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Band Alignment in In‐Oxo Metal Porphyrin SURMOF Heterojunctions
Porphyrin core metalation in indium‑oxo SURMOFs enables systematic tuning of band edge positions without altering the crystal structure. First‑principles calculations reveal type‑I and type‑II heterostructures as well as multi‑junction energy cascades, establishing a modular strategy for exciton funneling and charge separation in optoelectronic ...
Puja Singhvi, Nina Vankova, Thomas Heine
wiley +1 more source
Azolium‐Porphyrin Electrosynthesis
AbstractElectrochemical oxidation of Zn(II) 2,7,12,17‐tetra‐tert‐butylporphyrin in the presence of a series of azole derivatives (1‐methylimidazole, 1‐vinyl‐1H‐imidazole, 2‐(1H‐imidazol‐1‐yl)pyridine, 1‐methylbenzimidazole, 1‐methyl‐1H‐1,2,4‐triazole, and benzothiazole) affords the corresponding meso‐substituted azolium‐porphyrins in very mild ...
Akhssas, Fatima +11 more
openaire +4 more sources
A previously unreported coordination motif stabilising single Fe atoms by indigo chelation and pyridyl coordination on Au(111) has been revealed. By using planar tritopic pyridyl linkers (TPyB), extended 2D porous networks of indigo3(TPyB)2Fe6 form. These networks can be crystalline or vitreous and offer an environment where individual coordination ...
Hongxiang Xu +9 more
wiley +1 more source
Entropy analysis of nickel(II) porphyrins network via curve fitting techniques
Nickel(II) porphyrins typically adopt a square planar coordination geometry, with the nickel atom located at the center of the porphyrin ring and the coordinating atoms arranged in a square plane.
Muhammad Talha Farooq +2 more
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Photoswitching Conduction in Framework Materials
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez +4 more
wiley +1 more source
Synthesis and properties amphiphilic meso-arylsubstituted porphyrins
Synthesis of amphiphilic meso-arylsubstituted porphyrins with hydrophobic long chain groups and with terminal carboxylic and hydroxylic groups via dipyrrolylmethanes and with the use of monopyrrolic condensation is described.
I. N. Fedulova +5 more
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