Results 131 to 140 of about 8,250 (257)

Electrochemical Degradation of Perfluoroalkyl Sulfonates via Sulfonate to Carboxylate Conversion

Angewandte Chemie, Volume 138, Issue 7, 9 February 2026.
We demonstrate a novel approach for the degradation of perfluoroalkyl sulfonic acids (PFSAs) involving a controlled, electromediated, sulfonate‐to‐carboxylate headgroup conversion. We apply this method to shorter chain PFSAs and provide key mechanistic insights that contribute to a broader understanding of the molecular pathways underlying pollutant ...
Stella A. Fors, Richard J. Monsky, Emily R. Mahoney, Christian A. Malapit, William R. Dichtel   +4 more
wiley   +2 more sources

Hydrogen-bonding environment suppresses thermally activated delayed fluorescence. [PDF]

Chem Sci
Puhan SS, Dash L, Roy P.
europepmc   +1 more source

The Formation of Covalent Linkages in Lignocellulosic Biomass via the Oxocarbenium Intermediate

ChemPhysChem, Volume 27, Issue 4, 25 February 2026.
Density functional theory models show that the hydrated and acidic hemicellulose matrix in lignocellulosic biomass can generate oxocarbenium ions. These reactive intermediates can participate in the stable formation of glycosidic lignin‐carbohydrate covalent linkages, promoting recalcitrance in plant biomass.
Eduardo Romero‐Montalvo, Samir H. Mushrif   +1 more
wiley   +1 more source

REACTION OF TRIALKYL PHOSPHITES AND a-HALOKETONES IN APROTIC MEDIA (PERKOW-ARBUZOV REACTION) AND IN PROTIC SOLVENTS

, 1988
L. Tőke, Imre Petneházy, György Keglevich, Gy. Szakál   +3 more
openalex   +1 more source

An Unorthodox Enolate–Triggered Radical Relay Directs the Chemo Upgrading of Levulinic Acid Into Citramalic Acid

ChemSusChem, Volume 19, Issue 4, 25 February 2026.
Unorthodox Thermodynamic Enolate Coupled with a Radical Pathway A transition‐metal‐free oxidation of biomass‐derived levulinic acid to citramalic acid is achieved through an unorthodox enolate in combination with a radical pathway using potassium tert‐butoxide (KOtBu) and molecular oxygen (O2).
Geun Ho Kim, Young Kwang Han, Tae Woo Lee, Eun Jeong Yoo, Jung Woon Yang   +4 more
wiley   +1 more source

Density functional theory insights into the solvent effect on the binding energies of Cd²⁺ in functionalized MOFs. [PDF]

RSC Adv
Hoa VT.
europepmc   +1 more source

Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

Advanced Synthesis &Catalysis, Volume 368, Issue 4, 17 February 2026.
The combination of azole compounds and oxiranes exhibits carbenoid reactivity at elevated temperatures, as demonstrated by the successful benzoin condensation of aromatic aldehydes. Using this catalytic system to polymerize bifunctional aldehyde/oxirane monomers yields thermosets with glass transition temperatures above 100°C.
Matthias R. Steiner, Johanna M. Uher, Jürgen Lindner, Cordula M. Zeiler, Christian Slugovc   +4 more
wiley   +1 more source

<i>In Silico</i> Perspective on Avobenzone, Octisalate, Octocrylene, Homosalate, and Bemotrizinol as Organic UV Filters Using DFT, TD-DFT, and Molecular Dynamics. [PDF]

ACS Omega
Rigoni ME, de Lazaro SR, de Lara LS.
europepmc   +1 more source

Facile Separation of Acetic Acid from 1-Ethyl-3-methylimidazolium Acetate Ionic Liquid with the Aid of a Protic Solvent [PDF]

Naoki Wada, Takahiro Hara, Kenji Takahashi   +2 more
openalex   +1 more source

Dual‐State Photophysical Modulation via Bifurcated Hydrogen Bonding in a U‐Shaped Dipyridophenazine‐Cored Donor‐π‐Acceptor‐π‐Donor Fluorophore

Chemistry – A European Journal, Volume 32, Issue 7, 16 February 2026.
A donor–π–acceptor–π–donor (D–π–A–π–D) fluorophore bearing a U‐shaped dipyridophenazine core forms bifurcated hydrogen bonds with neutral donors such as sulfonamides or water. This interaction modulates both ground and excited states, enabling red‐shifted emission and enhanced photoluminescence in solution and solid state.
Kimiya Takei, Shunsuke Kobashi, Divya, Norimitsu Tohnai, Satoshi Minakata, Yoichi Kobayashi, Piotr de Silva, Youhei Takeda   +7 more
wiley   +1 more source