Results 31 to 40 of about 8,250 (257)

Salicylaldimine Ruthenium Alkylidene Complexes: Metathesis Catalysts Tuned for Protic Solvents [PDF]

open access: yesAdvanced Synthesis & Catalysis, 2007
AbstractTuning the electronic and steric environment of olefin metathesis catalysts with specialized ligands can adapt them to broader applications, including metathesis in aqueous solvents. Bidentate salicylaldimine ligands are known to stabilize ruthenium alkylidene complexes, as well as allow ring‐closing metathesis in protic media.
Joseph B, Binder   +2 more
openaire   +2 more sources

Epimerization of ergot alkaloids in feed

open access: yesHeliyon, 2020
Chronic intake of cereals contaminated with ergot alkaloids can cause ergotism and result in the loss of toes and fingers or even death. Today, due to common risk management practices, ergotism is rare as a human disease but remains a problem in ...
Claude Schummer   +3 more
doaj   +1 more source

Solvent Effect on Product Distribution in the Aerobic Autoxidation of 2-Ethylhexanal: Critical Role of Polarity

open access: yesFrontiers in Chemistry, 2022
In the aerobic oxidation of aldehydes to acids, how the solvent affect the reaction remains unclear. Herein, the solvent effect in the oxidation of 2-ethylhexanal (2-ETH) to 2-ethylhexanoic acid (2-ETA) was systematically investigated.
Zheng Wang   +7 more
doaj   +1 more source

Photoswitching Conduction in Framework Materials

open access: yesAdvanced Functional Materials, EarlyView.
This mini‐review summarizes recent advances in state‐of‐the‐art proton and electron conduction in framework materials that can be remotely and reversibly switched on and off by light. It discusses the various photoswitching conduction mechanisms and the strategies employed to enhance photoswitched conductivity.
Helmy Pacheco Hernandez   +4 more
wiley   +1 more source

Laser‐Induced Microfabrication of Carbon Nanostructure: Processing Mechanism and Application for Next‐Generation Battery Technology

open access: yesAdvanced Functional Materials, EarlyView.
The article reviews laser‐processed carbons from various precursors, processing mechanism and their application in advanced batteries. The laser process is chemical free, fast, and scalable, enabling improved battery performance and stability for Li, Na, and Zn battery technologies.
Sujit Deshmukh   +2 more
wiley   +1 more source

A linear solvation energy relationship study for the reactivity of 2-substituted cyclohex-1-enecarboxylic and 2-substituted benzoic acids with diazodiphenylmethane in aprotic and protic solvents [PDF]

open access: yesJournal of the Serbian Chemical Society, 2007
The rate constants for the reaction of 2-substituted cyclohex-1-enecarboxylic acids and the corresponding 2-substituted benzoic acids with diazodiphenylmethane were determined in various aprotic solvents at 30 ºC.
Nikolić Jasmina B.   +1 more
doaj   +3 more sources

Fully Bio‐Based Gelatin Organohydrogels via Enzymatic Crosslinking for Sustainable Soft Strain and Temperature Sensing

open access: yesAdvanced Functional Materials, EarlyView.
Enzymatically crosslinked gelatin‐based organohydrogels, fabricated through a fully bio‐based and scalable process, exhibit exceptional strain and temperature sensing capabilities with minimal interference from environmental humidity. These transparent, stretchable, and ionically conductive materials operate without synthetic fillers or dopants.
Pietro Tordi   +7 more
wiley   +1 more source

PTFE‐Activated Graphene Overcomes Dispersion Challenges for Scalable Solvent‐Free Fabrication of Ultra‐Thick, High‐Performance Cathodes in Lithium Metal Batteries

open access: yesAdvanced Functional Materials, EarlyView.
PTFE nanoparticle–anchored rGO (rGO@PTFE) for scalable solvent‐free fabrication of ultra‐thick, high‐density cathodes, achieving high conductivity (9.55 S cm−1), lithium transference (0.73), and improved wettability, is developed. The resulting cathode delivers 15.2 mAh cm−2 areal and 563 mAh cm−3 volumetric capacities, with full cells exhibiting 637 ...
Juhee Yoon   +7 more
wiley   +1 more source

The study of linear solvation energy relationship for the reactivity of carboxylic acids with diazodiphenylmethane in protic and aprotic solvents [PDF]

open access: yesJournal of the Serbian Chemical Society, 2009
Solvent effects on the reactivity of cycloalkenecarboxylic, cycloalkeneacetic, 2-substituted cyclohex-1-enecarboxylic, 2-substituted benzoic, 2-substituted cyclohex-1-eneacetic, 2-substituted phenylacetic, 2-phenylcyclohex-1-enecarboxylic, 2 ...
Ušćumlić Gordana S.   +1 more
doaj   +3 more sources

Where Most Frameworks Degrade: Flexible Bimetallic Phosphonate Crystals as pH‐Universal Supercapacitor Electrodes

open access: yesAdvanced Functional Materials, EarlyView.
Plastically flexible single crystals of the bimetallic phosphonate framework [Cu(2,2′‐bpy)VO(O3PC6H5)2] combine mechanical adaptability with robust pseudocapacitive charge storage. The material delivers about 140 Fg−1 at pH 4 and pH 10 and remains stable across pH 2‐12, enabling energy storage under comparatively mild electrolyte conditions.
Tim Müller   +11 more
wiley   +1 more source

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