Results 91 to 100 of about 22,717 (244)

Impact of climate‐induced compositional shifts of ethanol and acidity on aroma release and perception in red wine: a case study on γ‐nonalactone and massoia lactone

open access: yesJournal of the Science of Food and Agriculture, Volume 106, Issue 14, Page 8679-8689, November 2026.
Abstract BACKGROUND Climate change‐driven warming is increasing wine ethanol, promoting an atypical convergence between pH and titratable acidity (TA), and favouring the accumulation of specific wine volatiles: γ‐nonalactone (γ‐C9) and massoia lactone (MLac).
Roberto Salvatore Di Fede   +3 more
wiley   +1 more source

Novel Tunable CuX2-Mediated Cyclization Reaction of Cyclopropylideneacetic Acids and Esters for the Facile Synthesis of 4-Halomethyl-2(5H)-furanones and 4-Halo-5,6-dihydro-2H-pyran-2-ones

open access: yes, 2016
A mixture of cyclopropylideneacetic acids (or esters) and CuBr2 (or CuI/I2) in aqueous acetonitrile afforded 4-substituted 2(5H)-furanones or 3,4-substituted 5,6-dihydro-2H-pyran-2-ones in moderate to good yields.
Xian Huang (820390)   +1 more
core   +1 more source

2-Amino-5-oxo-4-(thiophen-2-yl)-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile

open access: yesIUCrData
The crystal structure of the title compound, C14H12N2O2S, reveals two symmetrically independent molecules within the asymmetric unit. Each molecule contains a chromenone core attached to a 2-thiophene ring, cyano, and amino groups.
Carren Nyapola   +3 more
doaj   +1 more source

5-Amino-7-(3-chlorophenyl)-3,7-dihydro-2H-thieno[3,2-b]pyran-6-carbonitrile 1,1-dioxide

open access: yesActa Crystallographica Section E, 2010
The title compound, C14H11ClN2O3S, with fused thiophene and pyran rings, was synthesized via the condensation of dihydrothiophen-3(2H)-one 1,1-dioxide and 2-(3-chlorobenzylidene)malononitrile catalysed by triethylamine in ethanol.
Shi-De Shen   +4 more
doaj   +1 more source

Plasmepsins as Antimalarial Drug Targets—Then, Now, and the Future

open access: yesMedicinal Research Reviews, Volume 46, Issue 6, Page 1574-1602, November 2026.
ABSTRACT Malaria is a devastating disease caused by Plasmodium parasites. Plasmodium parasites express ten cathepsin D‐like aspartyl proteases, called plasmepsins (PMs). These PMs have diverse roles fulfill diverse functions throughout the parasite's lifecycle, though several exhibit functional redundancies. Among them, PMV, PMIV, and PMX are essential
Brad E. Sleebs
wiley   +1 more source

The Natural Product Esculetin as an Efficient Photoacid for the Visible‐Light‐Mediated Acetalization/Ketalization Reaction

open access: yesChemSusChem, Volume 19, Issue 19, 14 October 2026.
Esculetin: an efficient photoacid catalyzing acetalization/ketalization reactions. The development of photochemical protocols for the production of fine chemicals and industrially interesting products, employing sustainable catalysts under mild conditions, is of high interest.
Maria A. Theodoropoulou   +6 more
wiley   +1 more source

Design and Synthesis of Novel 4‑Hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one Derivatives for Use as Herbicides and Evaluation of Their Mode of Action

open access: yes, 2019
In order to develop a novel herbicide containing the β-triketone motif, a series of 4-hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one derivatives were designed and synthesized.
Kang Lei (2823794)   +8 more
core   +1 more source

9-(4-Formylphenyl)-3,3,6,6-tetramethyl-3,4,5,6,7,9-hexahydro-1H-xanthene-1,8(2H)-dione

open access: yesIUCrData, 2018
In the title compound, C24H26O4, the central 4H-pyran ring adopts a flattened boat conformation, with the mean and maximum deviations of the ring being 0.0582 (6) and 0.1012 (3) Å, respectively.
R. Kalaivanan   +2 more
doaj   +1 more source

Synthesis of Naphthoquinones by Pd‐Catalyzed Heck–Matsuda Arylation of Lapachol

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 38, 13 October 2026.
Direct Heck–Matsuda arylation of lapachol enables the efficient synthesis of diverse naphthoquinones under homogeneous and heterogeneous palladium catalysis. The methodology features broad substrate scope, gram‐scale applicability, and provides a practical platform for quinone diversification.
Breno U. de Abreu   +13 more
wiley   +1 more source

Synthesis of Optically Active 2-Alkoxy-2H-pyran-3(6H)-ones. Their Use as Dienophiles in Diels−Alder Cycloadditions

open access: yes, 2016
Optically active 2-alkoxy-2H-pyran-3(6H)-ones (4a−d) were synthesized in one step by the tin(IV) chloride-promoted glycosylation and rearrangement of the 2-acetoxy-3,4-di-O-acetyl-d-xylal (3) prepared from d-xylose (1).
Christian A. Iriarte Capaccio (3029214)   +1 more
core   +1 more source

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