Solvent-free mechanochemical multicomponent preparation of 4H-pyrans catalyzed by Cu2(NH2-BDC)2(DABCO) metal-organic framework [PDF]
4H-pyrans have been prepared through a mechanochemical multicomponent reaction (MCR) of different aldehydes, malononitrile, and various 1,3-dicarbonyl compounds, catalyzed by an amine-functionalized metal-organic framework (MOF) Cu2(NH2-BDC)2(DABCO) as a
Zahra Akhlaghi +4 more
doaj +2 more sources
Zr-MOF-glutaraldehyde-Adn@Fe3O4 nanocomposite: as a new adsorbent for removal of methylene blue and heterogeneous nanocatalyst for the synthesis of tetrahydrobenzo[b]pyran derivatives [PDF]
In this research, a magnetic hybrid material (Zr-MOF-glutaraldehyde-Adn@Fe3O4) consisting of UiO-66-NH2 as a stable and unique metal-organic framework, and Fe3O4 nanoparticles was synthesized.
Fatemeh Yazdiamiri +3 more
doaj +2 more sources
Metal-organic framework catalysed multicomponent reactions towards the synthesis of Pyrans [PDF]
Metal-Organic Frameworks (MOFs) gaining increasing interest in heterogeneous catalysis owing to their advantageous properties such as superior porosity, high surface area, ample catalytic sites.
Subrahmanya Ishwar Bhat, Chinmay Bhat
doaj +2 more sources
Facile Assembly of Structurally Diverse 2H-Pyrans Enabled by Chloropalladation-Initiated Carboetherification of Alkenes [PDF]
3,6-Dihydro-2H-pyran heterocyclic framework is one of the currently developed heterocyclic building blocks in both pharmaceutical chemistry and organic synthesis, but with significant challenges.
Fanghua Mao +5 more
doaj +2 more sources
Entry to new spiroheterocycles via tandem Rh(II)-catalyzed O–H insertion/base-promoted cyclization involving diazoarylidene succinimides [PDF]
A facile approach to novel medicinally relevant spiro heterocyclic scaffolds (namely furan-2(5H)-ones, tetrahydrofurans and pyrans spiro-conjugated with the succinimide ring) has been developed.
Alexander Yanovich +4 more
doaj +2 more sources
Alcohol-Directed Carboamination of Conjugated Enynes. [PDF]
The first general three‐component intermolecular Pd‐catalyzed carboamination of conjugated enynes enables the coupling of anilines and aryl triflates to produce functionalized allenic amines, utilizing a native alcohol directing group to control regioselectivity.
Solé-Àvila H +3 more
europepmc +3 more sources
Pyrans are one of the most significant skeletons of oxygen-containing heterocyclic molecules, which exhibit a broad spectrum of medicinal applications and are constituents of diverse natural product analogues.
Suresh Maddila +2 more
doaj +1 more source
Starch-derived magnetic nanoparticles (Fe3O4@C-SO3H): Synthesis, Characterization and Its application on the preparation of dihydropyrano[c]chromenes, 2‑Amino-3-cyano‑4H‑pyrans and 2-amino-4H-chromenes derivatives [PDF]
In this study, a novel biomass and Starch-derived carbonaceous solid acid catalyst (Fe3O4@C-SO3H) that has superparamagnetism with high acid density was successfully prepared for the first time by incomplete hydrothermal carbonization of Starch followed ...
Fatemeh Khorsi Damghani +2 more
doaj +1 more source
Innovating Electrosynthesis From Metal Electrodeposition to Organic Chemistry: Deep Eutectic Solvents as Efficient and Sustainable Media. [PDF]
This review analyzes deep eutectic solvents (DESs) as efficient media for both organic and inorganic electrosynthesis. The improvements in terms of synthetic opportunities and sustainability are discussed, by exploring the multiple roles of DESs as solvents, electrolytes, and promoters, enabling effective and selective electrosynthesis under mild and ...
Margarita C +6 more
europepmc +2 more sources
Developing green and sustainable principles in catalytic systems using natural materials is becoming a suitable strategy to reduce the possible pollutant with high-risk agents.
Eskandar Kolvari +4 more
doaj +1 more source

