ReOx/TiO2: An Efficient Catalyst for the Production of Butanediols From Erythritol in Water
A nonnoble metal heterogeneous catalyst, ReOx/TiO2, has been used for the successful valorization of erythritol into biosourced butanediols. The TiO2 support influences the formation of the various supported Re species, whose repartition has an impact on the catalytic phenomena.
Theresa Al Bayeh +6 more
wiley +1 more source
Unprecedented Formation of a Formally Cu(III) Trifluoromethyl Hydroxide Tetramer. [PDF]
Motornov V, Limberg N.
europepmc +1 more source
Electrophilic Iodination of Heterocyclic Compounds. Recent Advances 2008–2025: Part II
Electrophilic iodination using molecular iodine and iodide sources represents an efficient approach for accessing valuable iodinated organic compounds. This review highlights recent advances in the iodination of heterocyclic compounds from 2008 to 2025, emphasizing the role of heteroaryl iodides as important synthetic intermediates for biologically ...
Njomza Ajvazi, Stojan Stavber
wiley +1 more source
Roles of π‑Conjugation and Intermolecular Interactions in Molecular Raman, Fluorescence, and Lifetime Spectroscopy. [PDF]
Yu Q +6 more
europepmc +1 more source
Emerging Trends in Organic Photoreactions Utilizing Disulfides
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar +3 more
wiley +1 more source
Evolution of Methods for the Oxidation of Primary Alcohols to Carboxylic Acids: From Metal Oxides to Biocatalysis. [PDF]
Spang J, Mascia F, Kroutil W.
europepmc +1 more source
A practical and scalable route to C1 and C2 lysine homologs has been developed using Hofmann degradation of N‐protected L‐asparagine and L‐glutamine as the key step. These short‐tether scaffolds enable efficient synthesis of diverse Fmoc‐protected noncanonical amino acids (ncAAs) bearing donor, acceptor, redox‐active, and fluorescent residues.
Adelaide R. Mashweu +7 more
wiley +1 more source
Heterobenzyl Chlorides as Linchpins for C-H Arylation via Sequential C-H Chlorination/Cross-Electrophile Coupling. [PDF]
Floreancig JT +6 more
europepmc +1 more source
Exploring Diverse Glycone Preferences of Aspergillus rutinosidases
Rutinosidases from Aspergillus niger (AnRut) and A. oryzae (AoRut) catalyze hydrolysis and transglycosylation with non‐natural glycosides as donors, enabling glycosylation of alcoholic and phenolic acceptors. AnRut exhibits broad glycone promiscuity, while AoRut has a narrower substrate scope.
Jitka Brouzdová +9 more
wiley +1 more source

