Results 191 to 200 of about 17,511 (250)
The Graphical Abstract summarizes the key concepts of this review, covering supramolecular assembly strategies, CPP material integration, multicolor emission, information encryption, and flexible optoelectronic applications. ABSTRACT Circularly polarized luminescence (CPL) and room‐temperature phosphorescence (RTP) materials are crucial for advanced ...
Wei Zhang +6 more
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One-Pot Bioisosteric Replacement of Alkyl Carboxylic Acids via Organic Photoredox Catalysis. [PDF]
Haney BA +3 more
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Enantioselective C(sp<sup>3</sup>)-H bond functionalization enabled by Cp <sup><i>x</i></sup> M(iii) catalysis (M = Co, Rh, Ir). [PDF]
Mou SB +5 more
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Azide‐to‐Diazo Transformation Facilitated by Michael Addition via Phosphazide Formation
A new type of Michael addition based on azide‐to‐diazo conversion is disclosed. This unusual transformation proceeds via 1,4‐addition accompanied by N─N bond cleavage of phosphazide intermediates under practical conditions. The high versatility of the resulting Michael adducts enables the synthesis of a wide variety of organonitrogen compounds ...
Tomoki Mano +3 more
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Discovery of 7-(Pyridin-3-yl)thieno[3,2-<i>b</i>]pyridine-5-carboxamides as Negative Allosteric Modulators of Metabotropic Glutamate Receptor Subtype 5. [PDF]
Henderson SH +21 more
europepmc +1 more source
Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu +3 more
wiley +1 more source
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HYDROGEN BONDING OF PYRIDINE-CARBOXYLIC ACIDS IN SOLIDS
Chemistry Letters, 1973Abstract The nature of the hydrogen bonds in pyridine-carboxylic acids is studied theoretically. There is an interesting relationship between O···N and N···H distances in the systems. The relation can be reasonably explained by the consideration of the charge transfer interactions.
Fusao Takusagawa +2 more
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Pyridine-Based Cavitands for Acid and Carboxylate Recognition
Molecular Crystals and Liquid Crystals, 2006The design, syntheses and binding capabilities of two novel cavitand-based receptors are described. Receptor 1, contains a cyclic array of pyridine moieties in its appendages and was synthesized in a single step from the known tetrol: refluxing tetrol with 2-bromomethyl 6-hydroxymethylpyridine under basic conditions. Receptor 2 was obtained by stirring
Nicola Edwards +3 more
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The Journal of Physical Chemistry A, 2016
The rotational spectra of four isotopologues of the 1:1 complex between formic acid and pyridine show that the two units are linked together through a "classical" (OH···N) and a weak (CH···O) hydrogen bond. The molecular system appears quite rigid and no effects of the internal motions have been observed in the spectrum.
Spada, Lorenzo +3 more
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The rotational spectra of four isotopologues of the 1:1 complex between formic acid and pyridine show that the two units are linked together through a "classical" (OH···N) and a weak (CH···O) hydrogen bond. The molecular system appears quite rigid and no effects of the internal motions have been observed in the spectrum.
Spada, Lorenzo +3 more
openaire +3 more sources
Thermochemistry of aqueous pyridine-3-carboxylic acid (nicotinic acid)
The Journal of Chemical Thermodynamics, 2011Abstract The molar enthalpy of solution of solid nicotinic acid (NA) at T = 298.15 K, to give an aqueous solution of molality m = 3.748 · 10−3 mol · kg−1, was determined as Δ sol H m = (19,927 ± 48) J · mol−1, by solution calorimetry.
Elsa M. Gonçalves +2 more
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