Results 21 to 30 of about 16,017 (235)

2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate

open access: yesIUCrData, 2017
The cation of the title molecular salt, C12H9N4S+·ClO4−, is approximately planar, with the pyridine and pyridinium rings being inclined to the central thiadiazole ring by 6.51 (9) and 9.13 (9)°, respectively.
Abdelhakim Laachir   +4 more
doaj   +1 more source

4-(4-Nitrobenzyl)pyridinium 5-nitrosalicylate [PDF]

open access: yes, 2010
In the title salt, C12H11N2O2+·C7H4NO5−, the cations and anions interact through asymmetric cyclic pyridinium–carboxylate N—H...O,O′ hydrogen-bonding associations [graph set R12(4)], giving discrete ...
Urs D. Wermuth   +3 more
core   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate

open access: yesActa Crystallographica Section E, 2014
In the cation of the title salt, C10H10N3+·C6H2N3O7−, the pyridine and pyridinium rings are linked by an intramolecular N—H...N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°.
Kateryna A. Ohui   +2 more
doaj   +1 more source

Asymmetric Hydrogenation of 3‐Substituted Pyridinium Salts

open access: yesChemistry – A European Journal, 2016
AbstractThe use of an equivalent amount of an organic base leads to high enantiomeric excess in the asymmetric hydrogenation of N‐benzylated 3‐substituted pyridinium salts into the corresponding piperidines. Indeed, in the presence of Et3N, a Rh‐JosiPhos catalyst reduced a range of pyridinium salts with ee values up to 90 %.
M. Renom-Carrasco   +6 more
openaire   +4 more sources

Advances in BODIPY Derivatives for Antibacterial Phototherapy

open access: yesAngewandte Chemie, EarlyView.
This review systematically summarizes the design strategies and structure‐activity relationships of BODIPY‐based antibacterial phototherapy, covering molecular engineering of small‐molecule photosensitizers and nanoplatforms, bacterial targeting and carrier design, and discussing the challenges and future perspectives associated with clinical ...
Li Lv   +9 more
wiley   +2 more sources

4,4′-(o-Phenylenedioxydimethylene)dipyridinium dinitrate

open access: yesActa Crystallographica Section E, 2009
The cation of the salt, C18H18N2O22+·2NO3−, lies about a twofold rotation axis. The pyridinium ring is almost coplanar with the phenylene ring [dihedral angle between rings = 5.69 (9)°].
Ping Zou   +4 more
doaj   +1 more source

Crystal structure of (E)-3-{[2-(2,4-dichlorobenzylidene)hydrazin-1-yl]carbonyl}pyridinium chloride trihydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
In the title hydrated salt, C13H10Cl2N3O+·Cl−·3H2O, the organic cation exhibits a dihedral angle of 8.26 (14)° between the mean planes of the pyridinium and benzene rings, and dihedral angles of 8.70 (15) and 15.93 (5)° between the mean planes of the ...
J. Josephine Novina   +3 more
doaj   +1 more source

Pyridinium-catalyzed decarboxylative borylation of benzoyl peroxides

open access: yesGreen Synthesis and Catalysis, 2021
A pyridinium salt catalyzed radical borylation of benzoyl peroxides is reported herein. A range of benzoyl peroxides having different electronic properties were well compatible in this borylation reaction, delivering various arylboronates in good yields ...
Shuxian Zhu   +4 more
doaj   +1 more source

Tandem dinucleophilic cyclization of cyclohexane-1,3-diones with pyridinium salts

open access: yesBeilstein Journal of Organic Chemistry, 2013
The cyclization of cyclohexane-1,3-diones with various substituted pyridinium salts afforded functionalized 8-oxa-10-aza-tricyclo[7.3.1.02,7]trideca-2(7),11-dienes.
Mostafa Kiamehr   +7 more
doaj   +1 more source

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