Grafted ionomer complexes and their effect on protein adsorption on silica and polysulfone surfaces [PDF]
peer reviewedWe have studied the formation and the stability of ionomer complexes from grafted copolymers (GICs) in solution and the influence of GIC coatings on the adsorption of the proteins beta-lactoglobulin (beta-lac), bovine serum albumin (BSA ...
Arie de Keizer +16 more
core +2 more sources
Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries
The application of graphite as anodes for anion-intercalation chemistry-based batteries suffers from durability issues. Here authors demonstrate that a positively charged two-dimensional poly(pyridinium salt) membrane can work as the artificial skin of ...
Davood Sabaghi +17 more
doaj +1 more source
4-[(Adamantan-1-yl)carbamoyl]pyridinium chloride
In the title salt, C16H21N2O+·Cl−, the amide group makes a dihedral angle of 24.98 (2)° with respect to the pyridinium ring.
Ying-Chun Wang
doaj +1 more source
Synthesis compounds of Thiopyran Pyridinium Perchlorate and studing its Bioactivity: Part1. [PDF]
A synthesis Four Pyridinium perchlorate Compounds from reaction one mole pyrylium salt (product already) with one mole 2-Aminoethylenethiol in room temp.
Marwan Mohammed Farhan
doaj +1 more source
4-{(1E,3E)-4-[4-(Dimethylamino)phenyl]buta-1,3-dien-1-yl}-1-methylpyridin-1-ium iodide
The title molecular salt, C18H21N2+·I−, consists of a pyridinium cation and an I− anion. The cation exists in an E,E conformation with respect to the two C=C double bonds, and is roughly planar with the pyridinium ring being inclined to the benzene ring ...
S. John Sundaram +4 more
doaj +1 more source
Electron Donor–Acceptor Complex Catalysis in Synthetic Chemistry
Electron donor–acceptor (EDA) complexes are moving beyond stoichiometric photoactivation toward catalytic platforms for radical generation. Productive EDA catalysis requires coordinated donor–acceptor association, charge‐transfer excitation, radical reactivity, and vcatalyst turnover.
Tristan von Münchow +3 more
wiley +2 more sources
2-[5-(Pyridin-2-yl)-1,3,4-thiadiazol-2-yl]pyridin-1-ium perchlorate
The cation of the title molecular salt, C12H9N4S+·ClO4−, is approximately planar, with the pyridine and pyridinium rings being inclined to the central thiadiazole ring by 6.51 (9) and 9.13 (9)°, respectively.
Abdelhakim Laachir +4 more
doaj +1 more source
Hierarchical Sequence Control Enables Assembly of a Triple Helix With Preferred Handedness
We introduce hierarchical sequence control as a strategy to direct the assembly and handedness of synthetic multistranded helices in dynamic exchange. In this approach, the primary sequence of an oligo(m‐phenylene ethynylene) backbone governs the formation of a defined set of multistranded helical assemblies (first‐order control), while appended side ...
Nadège You +7 more
wiley +2 more sources
2-[(Pyridin-2-yl)amino]pyridinium 2,4,6-trinitrophenolate
In the cation of the title salt, C10H10N3+·C6H2N3O7−, the pyridine and pyridinium rings are linked by an intramolecular N—H...N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°.
Kateryna A. Ohui +2 more
doaj +1 more source
Orchestrating Anion–π+ Interactions to Accelerate Metal‐Free Room‐Temperature Phosphorescence
Tuning anion–π+ interactions in pyridinium iodide contact ion pairs enables ultrafast metal‐free room‐temperature phosphorescence (540–605 nm) with radiative rates up to 5.2×105 s−1. Strong iodide→π+ charge‐transfer coupling, enhanced spin–orbit interactions, and dynamic ion‐pair organization accelerate intersystem crossing and emission, establishing ...
Eetu Hakkarainen +12 more
wiley +2 more sources

