The title compound (systematic name: pyridinium 4-methylbenzenesulfonate), C5H6N+·C7H7O3S−, is the pyridinium salt of para-toluenesulfonic acid. In the crystal, classical N—H...O hydrogen bonds as well as C—H...O contacts connect the cationic and anionic
Eric Cyriel Hosten, Richard Betz
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Tandem dinucleophilic cyclization of cyclohexane-1,3-diones with pyridinium salts
The cyclization of cyclohexane-1,3-diones with various substituted pyridinium salts afforded functionalized 8-oxa-10-aza-tricyclo[7.3.1.02,7]trideca-2(7),11-dienes.
Mostafa Kiamehr +7 more
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The asymmetric unit of the title salt, (C12H11BrN)2[Ni(C4N2S2)2], consists of one 1-(4-bromobenzyl)pyridinium cation and one half of a complex [Ni(mnt)2]2− (mnt2− is the maleonitriledithiolate dianion).
Dong Zeng +2 more
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Synthesis of Pyridinium Amphiphiles Used for Transfection and Some Characteristics of Amphiphile/DNA Complex Formation [PDF]
Pyridinium amphiphiles have found practical use for the delivery of DNA into cells. Starting from 4-methylpyridine, a general synthesis has been devised for the production of pyridinium amphiphiles which allows variation in both the hydrophobic part and ...
Bosgraaf, Bouke, +10 more
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Catalytic Photochemical Enantioselective α-Alkylation with Pyridinium Salts
We have developed a chiral amine catalyzed enantioselective α-alkylation of aldehydes with amino acid derived pyridinium salts as alkylating reagents. The reaction proceeds in the presence of visible light (390 nm) and in the absence of a photocatalyst via a light activated charge-transfer complex.
Santhivardhana Reddy Yetra +2 more
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Tetrapyridinium μ-oxido-di-μ-sulfato-bis[chloridodioxidomolybdate(VI)]
The title salt, (C5H6N)4[Mo2Cl2O5(SO4)2], comprises four pyridinium cations for each [(MoClO2)2(μ-O)(μ-SO4)2]4− anionic unit. The asymmetric unit consists of three aggregates of the empirical formula.
José A. Fernandes +8 more
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Syntheses and Properties of Two-Dimensional, Dicationic Nonlinear Optical Chromophores Based on Pyrazinyl Cores [PDF]
Six new dicationic 2D nonlinear optical (NLO) chromophores with pyrazinyl-pyridinium electron acceptors have been synthesized by nucleophilic substitutions of 2,6-dichloropyrazine with pyridyl derivatives. These compounds have been characterized as their
Asselberghs, Inge +7 more
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Bis(4,4′-bipyridin-1-ium) cis-bis(1,2-dicyano-2-sulfidoethene-1-sulfinato-κ2S,S′)platinate(2−)
Crystals of the sulfinate-containing platinate salt, (C10H9N2)2[Pt(C4N2O2S2)2], were obtained from a solution of [Pt(4,4′-bpy)2(mnt)] after a long period with minimal light (4,4′-bpy is 4,4′-bipyridine and mnt is maleonitriledithiolate). In the crystals,
Claire E. Welton +2 more
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Tailoring the Properties of Functional Materials With N‐Oxides
The properties of materials bearing N‐oxide groups are often dominated by the polar N+─O− bond. It provides hydrophilicity, selective ion‐binding, electric conductivity, or antifouling properties. Many of the underlying mechanisms have only recently been discovered, and the interest in N‐oxide materials is rapidly growing.
Timo Friedrich +5 more
wiley +1 more source
2-({[(Pyridin-1-ium-2-ylmethyl)carbamoyl]formamido}methyl)pyridin-1-ium bis(3,5-dicarboxybenzoate): crystal structure and Hirshfeld surface analysis [PDF]
The asymmetric unit of the title salt, C14H16N4O22+·2C9H5O6−, comprises half a dication, being located about a centre of inversion, and one anion, in a general position.
Jotani, Mukesh M. +3 more
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