Pyridinium Salts of Dehydrated Lanthanide Polychlorides [PDF]
The reaction of lanthanide (Ln) chloride hydrates ([Ln(H2O)n(Cl)3]) with pyridine (py) yielded a set of dehydrated pyridinium (py-H) Ln-polychloride salts. These species were crystallographically characterized as [[py-H-py][py-H]2[LnCl6]] (Ln-6; Ln = La,
Roger E. Cramer +2 more
doaj +4 more sources
Synthesis and Antimicrobial Activity of Some Pyridinium Salts [PDF]
Some substituted benzylidenehydrazinylpyridinium derivatives bearing benzyl, ethylphenyl and propylphenyl groups on the pyridinium nitrogen were synthesized and screened for possible antibacterial and antifungal activities against Staphylococcus aureus ...
Vildan Alptüzün +2 more
exaly +6 more sources
Regioselective and site-divergent synthesis of tetrahydropyridines by controlled reductive-oxidative dearomative hydroarylation of pyridinium salts [PDF]
Tetrahydropyridine skeletons serve as ubiquitous structural motifs which are predominant in natural products, bioactive and drug molecules. Thus, the development of efficient and general synthetic methods for the synthesis of tetrahydropyridine ...
Xing-Fu Wei +4 more
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Antitumour Effects of Selected Pyridinium Salts on Sensitive Leukaemia HL60 Cells and Their Multidrug Resistant Topoisomerase II-Defective HL60/MX2 Counterparts [PDF]
Multidrug resistance (MDR), having a multifactorial nature, is one of the major clinical problems causing the failure of anticancer therapy. The aim of this study was to examine the antitumour effects of selected pyridinium salts, 1-methyl-3 ...
Jolanta Tarasiuk +2 more
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Rapid Electrophilic Cysteine Arylation with Pyridinium Salts. [PDF]
Here, we present a series of fluorinated cationic reagents that enable rapid arylation of cysteine under mild conditions compatible with proteins and peptides. The highly polarized C-F bond and attractive nucleophile-electrophile Coulombic interactions substantially accelerate cysteine arylation, leading to unusually high rate constants on the order of
Lipka BM +9 more
europepmc +4 more sources
A metal-free approach for the synthesis of amides/esters with pyridinium salts of phenacyl bromides via oxidative C–C bond cleavage [PDF]
An efficient, simple, and metal-free synthetic approach for the N- and O-benzoylation of various amines/benzyl alcohols with pyridinium salts of phenacyl bromides is demonstrated to generate the corresponding amides and esters.
Kesari Lakshmi Manasa +3 more
doaj +2 more sources
Synthesis, Characterization, and Computational Modeling of N-(1-Ethoxyvinyl)pyridinium Triflates, an Unusual Class of Pyridinium Salts [PDF]
N-Substituted pyridinium salts constitute one of the most valuable reagent classes in organic synthesis, due to their versatility and ease of use. Herein we report a preliminary synthesis and detailed structural analysis of several N-(1-ethoxyvinyl ...
Jonathan D. Shapiro +8 more
doaj +2 more sources
One‐Step Aqueous Synthesis of Glycosyl Pyridinium Salts, Electrochemical Study, and Assessment of Utility as Precursors of Glycosyl Radicals Using Photoredox Catalysis [PDF]
A single step method for the production of unprotected glycosyl pyridinium salts has been developed involving treatment of the unprotected sugar with a pyridine, triethylamine, and either 2‐chloro‐1,3‐dimethylimidazolinium chloride (DMC) or 2‐chloro‐1,3 ...
Daniel Chong +2 more
doaj +2 more sources
Quaternary Pyridinium Salts: A Review
Cationic surfactants are being used in various applications industrially and domestically for a long time. Pyridinium salts come under the category of cationic surfactants. These are unsaturated heterocyclic compounds having different functional groups present either on pyridine ring or at nitrogen atom.
Parag, Madaan, Vinod K, Tyagi
exaly +4 more sources
Preparation and Characterization of Polyphenol-Functionalized Chitooligosaccharide Pyridinium Salts with Antioxidant Activity [PDF]
As a kind of eco-friendly material with wide application prospects, chitooligosaccharide (COS) has attracted increasing attention because of its unique bioactivities.
Zhen Qi +3 more
doaj +2 more sources

