Results 31 to 40 of about 9,595 (203)

Synthesis and Characterization of Novel Pyridinium Salts of (E)-2-(Pyridin-4-ylmethylene)hydrazine-1-carboximidamide

Molbank
We report the synthesis and characterization of the novel pyridinium salts from (E)-2-(pyridin-4-ylmethylene)hydrazine-1-carboximidamide. The pyridinium salts were obtained via the reaction of guanylhydrazone derived from pyridine-4-carbaldehyde with ...
Fatemeh Ataie Alani, Fatemeh Ahmadian, Alireza Houshdar Tehrani, Salimeh Amidi   +3 more
doaj   +1 more source

Reaction of Picolinamides with Ketones Producing a New Type of Heterocyclic Salts with an Imidazolidin-4-One Ring

Molecules, 2023
Reactions of picolinamides with 1,3-propanesultone in methanol followed by the treatment with ketones led to a series of previously unknown chemical transformations, yielding first pyridinium salts (2a–f), with a protonated endocyclic nitrogen atom, and ...
Eugenia P. Kramarova, Dmitry N. Lyakhmun, Dmitry V. Tarasenko, Sophia S. Borisevich, Edward M. Khamitov, Alfia R. Yusupova, Alexander A. Korlyukov, Alexander R. Romanenko, Tatiana A. Shmigol, Sergey Yu. Bylikin, Yuri I. Baukov, Vadim V. Negrebetsky   +11 more
doaj   +1 more source

Asymmetric Hydrogenation of 3‐Substituted Pyridinium Salts

Chemistry – A European Journal, 2016
AbstractThe use of an equivalent amount of an organic base leads to high enantiomeric excess in the asymmetric hydrogenation of N‐benzylated 3‐substituted pyridinium salts into the corresponding piperidines. Indeed, in the presence of Et3N, a Rh‐JosiPhos catalyst reduced a range of pyridinium salts with ee values up to 90 %.
M. Renom-Carrasco, GAJEWSKI, PIOTR, PIGNATARO, LUCA LUIGI, J. De Vries, U. Piarulli, C. Gennari, L. Lefort   +6 more
openaire   +4 more sources

Dynamic Fluorescence Modulation via Light‐Driven Competitive Protonation

Advanced Optical Materials, EarlyView.
A two‐component molecular system demonstrates reversible, light‐driven fluorescence write–erase cycling and thermal imaging. Illumination of a merocyanine photoacid transfers a proton to a highly efficient fluorescent pyridinium dye, switching its emission color; thermal relaxation reverses the process in the dark.
Serena X. Liu, Moritz E. Kleybolte, Colin van Dyck, Sergey I. Vagin, Preeti Gahtori, Antonio Scarpati, Razieh Firouzihaji, Diogo A. Galico, Ulrich S. Schubert, Julianne Gibbs, Alkiviathes Meldrum   +10 more
wiley   +1 more source

Crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κN)manganate(II) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κN)manganate(II)

Acta Crystallographica Section E: Crystallographic Communications, 2018
The crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands,
Tristan Neumann, Inke Jess, Christian Näther   +2 more
doaj   +1 more source

Multidimensional and Multifunctional Laser‐Induced Graphene (LIG) for Point‐of‐Care and Wearable Biosensing, Theranostics, and Bioactive Interfaces Toward Personalized Healthcare and Regenerative Medicine

Advanced Science, EarlyView.
Multidimensional laser‐induced graphene (LIG) spanning from 0D to 3D architectures is comprehensively reviewed for multifunctional biomedical platforms, including biosensing, theranostics, and bioactive interface applications, which highlights its potentials for point‐of‐care diagnostics, wearable health monitoring, smart drug delivery, and tissue ...
Li Zhang, Yurou Yuan, Xiaohong Ding, Wing Cheung Mak   +3 more
wiley   +1 more source

From optically pure pyridinium salts to some new dihydro-2H-oxazolo[3,2-a]pyridines

Results in Chemistry, 2023
Treatment of 2,4,6-triphenylpiridinium salts, bearing a chiral β-hydroxy alkyl N-substituent with diluted aqueous sodium hydroxide afforded four new dihydrooxazolo[3,2a]pyridines,as an almost equimolar mixture of diastereomers.
R.G. Moura, P.R. Batista, L.C. Ducati, J. Gruber, L.F. Yamaguchi, L. Marzorati   +5 more
doaj   +1 more source

Reversible Exfoliation‐Aggregation Dynamics in Ionic COFs for Tunable Interfacial Catalysis

Advanced Science, EarlyView.
A unique ionic covalent organic framework (I‐4) exhibits unprecedented concentration‐dependent dynamic behavior in water, undergoing reversible transitions between aggregation and exfoliation. This enables fully controllable, bidirectional modulation of its particle size and surface micro‐environment.
Jilu Yang, Xiaofei Zhang, Yue Li, Yuping Cao, Zhaowei Jia, Bo Li, Haitao Feng, Xiaoqiang Cui, Wenwu Qin   +8 more
wiley   +1 more source

Organic–inorganic hybrid mixed-halide ZnII and CdII tetrahalometallates with the 2-methylimidazo[1,5-a]pyridinium cation

Acta Crystallographica Section E: Crystallographic Communications, 2022
Three isomorphous 0-D hybrid salts, namely, 2-methylimidazo[1,5-a]pyridinium trichloridoiodidozincate(II), (C8H9N2)2[ZnCl3.19I0.81] or [L]2[ZnCl3.19I0.81], (I), 2-methylimidazo[1,5-a]pyridinium dibromidodichloridocadmate(II), (C8H9N2)2[CdBr2.42Cl1.58] or
Olga Yu. Vassilyeva, Elena A. Buvaylo, Vladimir N. Kokozay, Brian W. Skelton   +3 more
doaj   +1 more source

L-Aspartic acid pyridinium salts: In silico, synthesis and adjuvant vs antibiotic antibacterial evaluation

Results in Chemistry
In the present study, a new series of chiral L-aspartic acid pyridinium salts have been designed, guided by molecular docking as antiemetics via TrySR or DNA GryB inhibitors, as well as an adjuvant to chloramphenicol via CAT-III inhibitor to continue ...
Jessica R. Gutiérrez Cano, I. Paulina Morales-Sandoval, Dino Gnecco, Alan Carrasco-Carballo, Joel L. Terán   +4 more
doaj   +1 more source