Results 41 to 50 of about 358,569 (255)

N-Heterocyclic carbene-catalyzed deaminative cross-coupling of aldehydes with Katritzky pyridinium salts. [PDF]

open access: yesChem Sci, 2020
By employing an N-heterocyclic carbene (NHC) catalyst, we developed a versatile catalytic system that enables deaminative cross-coupling reactions of aldehydes with redox-active pyridinium salts.
Kim I, Im H, Lee H, Hong S.
europepmc   +2 more sources

On the photochemical reaction of pyridinium salts with nucleophiles [PDF]

open access: yesPhotochemical & Photobiological Sciences, 2021
AbstractDFT calculations on the photochemical reaction of 1-n–N-butylpyridinium salt in water with hydroxide anion is in agreement with a singlet state process where the S2 state at λ = 253 nm can be converted into a Dewar isomer (2-butyl-2-azabicyclo[2.2.0]hexa-2,5-dien-2-yl cation).
openaire   +4 more sources

Passivating Lead Halide Perovskites Using Pyridinium Salts with Superhalogen Atoms

open access: yes, 2022
Passivating lead halide perovskites using pyridinium salts has attracted enormous attention, but the excellent surface passivation of the halide perovskites has not been achieved by using only a pyridinium salt until now.
Dongjie Zhu (8897999)   +3 more
core   +2 more sources

Catalytic Photochemical Enantioselective α-Alkylation with Pyridinium Salts

open access: yes, 2022
We have developed a chiral amine catalyzed enantioselective α-alkylation of aldehydes with amino acid derived pyridinium salts as alkylating reagents. The reaction proceeds in the presence of visible light (390 nm) and in the absence of a photocatalyst ...
Santhivardhana Reddy, Yetra   +2 more
core   +1 more source

Novel Coumarin–Pyridine Hybrids as Potent Multi-Target Directed Ligands Aiming at Symptoms of Alzheimer’s Disease

open access: yesFrontiers in Chemistry, 2022
Graphical AbstractA novel series of 3-phenyl-coumarin derivatives containing pyridinium salts was prepared, indicating significant inhibitory activity against AChE and BuChE as well as precious neuroprotective and anti-Aβ aggregation effects.
Elaheh Babaei   +14 more
doaj   +1 more source

Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl-Alkyl Cross-Couplings. [PDF]

open access: yesJ Am Chem Soc, 2019
A Negishi cross-coupling of alkyl pyridinium salts and alkylzinc halides has been developed. This is the first example of alkyl–alkyl bond formation via cross-coupling of an alkyl amine derivative with an unactivated alkyl group, and allows both primary ...
Plunkett S   +3 more
europepmc   +2 more sources

Sulfinates from Amines: A Radical Approach to Alkyl Sulfonyl Derivatives via Donor-Acceptor Activation of Pyridinium Salts.

open access: yesOrganic Letters, 2021
Synthetically versatile alkyl sulfinates can be prepared from readily available amines, using Katritzky pyridinium salt intermediates. In a catalyst-free procedure, primary, secondary, and benzylic alkyl radicals are generated by photoinduced or ...
Jonathan A. Andrews   +4 more
semanticscholar   +1 more source

Investigation of the Pyridinium Ylide—Alkyne Cycloaddition as a Fluorogenic Coupling Reaction

open access: yesMolecules, 2016
The cycloaddition of pyridinium ylides with alkynes was investigated under mild conditions. A series of 13 pyridinium salts was prepared by alkylation of 4-substituted pyridines.
Simon Bonte   +4 more
doaj   +1 more source

Catalytic reactions of pyridinium and iminium ions

open access: yes, 2022
Watson, Mary P.The dissertation focuses on transition metal catalysis of cationic species to make C-C bonds. ☐ Chapter 1 describes a nickel-catalyzed Suzuki-Miyaura cross-coupling of benzylic pyridinium salts. The pyridinium salts act as electrophiles in
Guan, Weiye
core   +1 more source

4,4′,4″-(Benzene-1,3,5-triyltris(ethyne-2,1-diyl))tris(1-methylpyridin-1-ium) Iodide

open access: yesMolbank, 2023
Despite having been known for a long time, quaternary 4,4′-bipyridinium salts, or viologens, are still a highly inspiring class of compounds, thanks to their peculiar redox and charge transfer properties.
Lorenza Romagnoli   +2 more
doaj   +1 more source

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